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Electrical and Electrochemical Properties of Nanocomposite Thin Films Formed by Exchange-Precipitation Route from Nanocrystals and Organic Cross-Linkers

  • Frank L. Leibowitz (a1), Wenxia Zheng (a1), Mathew M. Maye (a1), Nam K. Ly (a1) and Chuan-Jian Zhong (a2)...


The structural, electrical and electrochemical properties of nanoparticle thin films derived by a one-step exchange-crosslinking-precipitation route were characterized by microscopic, spectroscopic and electrochemical techniques. Thiolate-encapsulated gold nanocrystals of 2-nm and 5-nm core sizes and alkyldithiol crosslinkers were studied as a model system. The mixing of the two components in solutions allowed sequential exchanging, crosslinking and precipitation of dithiol-crosslinked nanocrystal thin films. The films were specularly reflecting and electronically continuous, and have potential applications in catalysis and molecular recognition.



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