Hostname: page-component-848d4c4894-4rdrl Total loading time: 0 Render date: 2024-07-06T08:29:54.708Z Has data issue: false hasContentIssue false

Diffusion Cells for Integrating Temperature and Humidity Over Long Periods of Time

Published online by Cambridge University Press:  21 February 2011

Fred Trembour
Affiliation:
U.S. Geological Survey, D.F.C., M.S. 963, Box 25046, Denver, CO. 80225
Franklin L. Smith
Affiliation:
U.S. Geological Survey, D.F.C., M.S. 963, Box 25046, Denver, CO. 80225
Irving Friedman
Affiliation:
U.S. Geological Survey, D.F.C., M.S. 963, Box 25046, Denver, CO. 80225
Get access

Abstract

The rate of many processes, including the diffusion of water into rhyolitic volcanic glass (obsidian), as well as the racemization of amino acids is temperature dependent, and a knowledge of temperatures integrated over time periods of at least a year is necessary to quantify these processes. The construction and properties of simple devices consisting of small plastic containers that change weight at a rate that is a function of temperature and the activity of water will be described. The cells function because water diffuses through the plastic across a constant vapor-pressure gradient. This vapor-pressure gradient is maintained constant between the substances within the cell and the materials outside the cell. The plastic cells are usually filled with water and surrounded by a dehydrating agent, such as silica gel. A better arrangement is to fill the cell with a mixture of solid sodium chloride (NaCl) and a saturated solution of NaCl, and to surround the cell with pure water. A number of plastics have been investigated, including polycarbonate, polystyrene, tefzel, polyallomer, and methacrylate. The cells have been sealed by various methods including screw caps, room-temperature vulcanizing silicone rubber sealant, and rubber stoppers. The final design consists of a small cell made of a polycarbonate plastic centrifuge tube containing solid NaCl plus NaCl-saturated solution sealed with a rubber stopper and placed in a polypropylene tube containing pure water. Our aim has been to develop cells that are sufficiently sensitive to yield a precision of ±0.2°C when exposed for one year at temperatures that range from 0° to 40°, and that will fit into metal fittings that can be screwed into standard 3/4-inch plastic water pipe (approximately 1 inch outside diameter).

Type
Research Article
Copyright
Copyright © Materials Research Society 1988

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1 Ambrose, W., Advances in Obsidian Glass Studies edited by Taylor, R.E.(Noyes Press, New Jersey, 1978) pp110114 Google Scholar
2 Trembour, F.W., Friedman, I., Jurceka, F.J., Smith, F.L., J. Atmos. & Ocean Tech. 3, 186190 (1986)Google Scholar