Hostname: page-component-848d4c4894-m9kch Total loading time: 0 Render date: 2024-05-01T21:20:14.200Z Has data issue: false hasContentIssue false
  • English
  • Français

Diffuse Reflectance and Absorption Characteriation of a Plasmonic Back Reflector for Application in Thin Film Si Solar Cells

Published online by Cambridge University Press:  10 May 2012

R.S.A. Sesuraj ,
T. L. Temple  and
D.M. Bagnall
R.S.A. Sesuraj*
Affiliation:
Nano Research Group, Electronics and Computer Science, Faculty of Physical and Applied Sciences, University of Southampton, SO17 1BJ, United Kingdom.
T. L. Temple
Affiliation:
Nano Research Group, Electronics and Computer Science, Faculty of Physical and Applied Sciences, University of Southampton, SO17 1BJ, United Kingdom.
D.M. Bagnall
Affiliation:
Nano Research Group, Electronics and Computer Science, Faculty of Physical and Applied Sciences, University of Southampton, SO17 1BJ, United Kingdom.
*
*Corresponding author. Email: rsas1v07@ecs.soton.ac.uk
Get access

Abstract

A plasmonic back reflector has been fabricated for light-trapping application in thin film Si photovoltaic devices. The back reflector comprises of a 2D array of self-organized Ag NPs separated from a planar Ag mirror by a ZnO layer deposited by atomic-layer deposition. The diffuse reflectance and parasitic absorption losses can be modulated by varying the ZnO thickness. A maximum diffuse reflectance peak value of 30% at 950 nm, with a bandwidth of 400nm, is observed for ∼100 nm diameter NPs at a distance of 50 nm from the Ag mirror. Finite-difference time-domain simulations of a 100nm Ag sphere near a mirror were used to understand the experimentally observed trends in diffuse reflectance and parasitic absorption, with distance from the mirror. Particles very close to the mirror can couple to delocalized surface plasmons or exhibit Fano resonance effects, thereby increasing parasitic absorption. Particles situated away from the mirror are influenced by driving-field effects due to the interaction of incident and reflected photons, which modulate the scattering cross-section.

Keywords

photovoltaicnanostructureAg
Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 1391: Symposium J – Photonic and Plasmonic Materials for Enhanced Photovoltaic Performance , 2012 , mrsf11-1391-j07-13
Copyright
Copyright © Materials Research Society 2012

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1. Springer, J., Poruba, A., Mullerova, L. and Vanecek, M., Journal of Applied Physics, 2004. 95. no.3. p1427-1429 Google Scholar
2. Lim, S. H., Mar, W., Matheu, P., Derkacs, D., and Yu, E. T., Journal of Applied Physics. 2009. 101. p104309–1-104309-7.Google Scholar
3. Temple, T. L., Mahanama, G. D. K, Reehal, H. S. and Bagnall, D. M., Solar Energy Materials and Solar Cells. 2009. 93. p1978–1985.Google Scholar
4. Pillai, S., Catchpole, K. R., Trupke, T., and Green, M. A., Journal of Applied Physics. 2009. 101. p093105–1-093105-8.Google Scholar
5. Beck, F. J., Polman, A., and Catchpole, K. R., Journal of Applied Physics. 2009. 105. p114310–6-114310-6Google Scholar
6. "FDTD Solutions Knowledge Base: Advanced method," Lumerical, [Online]. Available: http://docs.lumerical.com/en/fdtd/user_guide_absorption_2.html. (March 2012)Google Scholar
7. Soller, B.J. and Hall, D.G., Journal of Optical Society of America B, 2002. 19. no.10. p2438.Google Scholar
8. Mertz, J., Journal of the Optical Society of America B, 2000. 17, pp.1906-1913.Google Scholar
9. Johansson, P., Physical Review B, 64. 2001. pp. 165405–7-165403-11.Google Scholar
10. Zhang, S., Bao, K., Halas, N., Xu, H. and Nordlander, P., Nano Letters, 2011. 11. pp.1657-1658.Google Scholar