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Design and Syntheses of Poly(Norbornenyldecaborane) Precursors to Boron Carbide and Boron-Carbide/Silicon-Carbide Ceramics

  • Xiaolan Wei (a1), Daniel T. Welna (a2), Jared D. Bender (a2), Larry G. Sneddon (a1) and Harry R. Allcock (a2)...

Abstract

Poly(norbornenyldecaborane) (PND) was synthesized via ruthenium catalyzed ring opening metathesis polymerization and was found to be a good single-source polymeric boron carbide precursor. Polymer blends of PND and allylhydridopolycarbosilane (AHPCS) were also found to be excellent precursors to boron-carbide/silicon-carbide composite materials.

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Design and Syntheses of Poly(Norbornenyldecaborane) Precursors to Boron Carbide and Boron-Carbide/Silicon-Carbide Ceramics

  • Xiaolan Wei (a1), Daniel T. Welna (a2), Jared D. Bender (a2), Larry G. Sneddon (a1) and Harry R. Allcock (a2)...

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