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The Defect Chemistry of Pyrochlore Solid Solutions of the Type R2(ZrxTil-x)2O7 with R=Gd, Y
Published online by Cambridge University Press: 28 February 2011
Abstract
Two pyrochlore solid solutions, Gd2(ZrxTi1-x)2O7 and Y2(ZrxTil-x)2O7, were investigated to clarify the relationships between composition, structural disorder and ionic and electronic transport. A defect chemical model was developed based on the results of electrical and x-ray diffraction measurements. Frenkel, reduction and bandgap energies were derived.
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