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Controlled Cleavage of Fully-Condensed Silsesquioxane Frameworks: A Revolutionary New Method for Manufacturing Precursors to Hybrid Inorganic/Organic Materials

  • Frank J. Feher (a1) and Daravong Soulivong (a1)

Abstract

The reaction of readily available Cy8Si8O12 (3) with triflic acid (TfOH) can produce two different ditriflates derived from controlled cleavage of Si-O-Si linkages. These ditriflates can be subsequently hydrolyzed to four different incompletely condensed silsesquioxanes, which are attractive precursors to hybrid inorganic/organic materials.

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Controlled Cleavage of Fully-Condensed Silsesquioxane Frameworks: A Revolutionary New Method for Manufacturing Precursors to Hybrid Inorganic/Organic Materials

  • Frank J. Feher (a1) and Daravong Soulivong (a1)

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