Hostname: page-component-68945f75b7-z8dg2 Total loading time: 0 Render date: 2024-08-06T09:04:02.223Z Has data issue: false hasContentIssue false

Control of the Formation of Zn1-xMgxO Films by Zinc Sulfate Concentration

Published online by Cambridge University Press:  20 March 2013

Hiroki Ishizaki
Affiliation:
Department of Electronic System Engineering, Tokyo University of Science Suwa, 5000-1 Toyohira, Chino-shi, Nagano 391-0292, Japan
Seishiro Ito
Affiliation:
Faculty of Science and Engineering, Kinki University, 4-1 Kowakae 3-chome, Higashiosaka, Osaka 577-8502, Japan
Get access

Abstract

Magnesium doped ZnO films were electrochemically grown on the NESA conductive glass substrate from the magnesium nitrate aqueous solution with zinc sulfate, kept at 323K and the cathodic potential of -0.9V vs. Ag/AgCl. The Mg/(Mg+Zn) atomic ratio of Zn1-xMgxO films increased with the decrease in the zinc sulfate concentration. The optical band gap energy of these Zn1-xMgxO films decreased with increasing content of zinc sulfate. Thus, the optical band gap energy and Mg/(Mg+Zn) atomic ratio of Zn1-xMgxO films would depend on the zinc sulfate concentration.

Type
Articles
Copyright
Copyright © Materials Research Society 2013 

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

Erfurth, F., Husmann, B., Scholl, A., Reinert, F., Grimm, A., Lauermann, I., Bar, M., Niesen, Th., Palm, J., Visbeck, S., Weinhardt, L., and Umbach, E., Appl. Phys. Lett., 95, 122104 (2009)CrossRefGoogle Scholar
Matsubara, K., Tampo, H., Shibata, H., Yamada, A., Fons, P., Iwata, K. and Niki, S., Appl. Phys. Lett., 85, 1374 (2004)CrossRefGoogle Scholar
Izumi, F. and Ikeda, T., Mater. Sci. Forum, 198, 321 (2000)Google Scholar
Pourbaix, M., “Atlas of electrochemical Equilibria in Aqueous Solution”, p.139, Pergamon Press, Paris, (1966)Google Scholar
Pourbaix, M., “Atlas of electrochemical Equilibria in Aqueous Solution”, p.406, Pergamon Press, Paris, (1966)Google Scholar
Chastain, J., “Handbook of X-ray Photoelectron Spectroscopy”, p.52, Perkin-Elmer Corporation Physical Electronics Division, America (1992)Google Scholar
Chastain, J., “Handbook of X-ray Photoelectron Spectroscopy”, p.88, Perkin-Elmer Corporation Physical Electronics Division, America (1992)Google Scholar
Dona, J. M., J. Electrochem. Soc., 141, 205 (1994)CrossRefGoogle Scholar