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Comparison Between the Sol-Gel Processes of Zirconia and those of Alumina

Published online by Cambridge University Press:  25 February 2011

Alain C. Pierre
Affiliation:
Laboratoire de Chimie du Solide, Université de Bordeaux I, 351 cours de la Libération, 33405 Talence cedex, France.
Donald R. Uhlmann
Affiliation:
Department of Materials Sciences, University of Arizona, Tucson, AZ 85721, USA.
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Abstract

Zirconia gels have been synthesized from zirconium butoxide in excess water with HNO3. The structure and characteristics of the gels have been studied as a function of the acid content, and the transformation during heat treatment has been followed up to 1150°C.

From the results of a previous similar study on aluminum hydroxide gels, a comparison is made between the sol-gel processes of zirconia and those of alumina. A discussion of the differences of the aqueous media chemistry of Al and Zr, and gelation mechanisms, is presented.

Type
Research Article
Copyright
Copyright © Materials Research Society 1988

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References

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