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CO2 Chemisorption on Li5AlO4: Effects of Sodium and Potassium Carbonate Addition

Published online by Cambridge University Press:  01 October 2015

M. Teresa Flores-Martínez
Affiliation:
Instituto de Investigaciones en Materiales, Universidad Nacional Autónoma de México, Circuito Exterior s/n, Ciudad Universitaria, Del. Coyoacán, CP 04510, México D.F, México.
Heriberto Pfeiffer
Affiliation:
Instituto de Investigaciones en Materiales, Universidad Nacional Autónoma de México, Circuito Exterior s/n, Ciudad Universitaria, Del. Coyoacán, CP 04510, México D.F, México.
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Abstract

In this work, Na- and K-doped β-Li5AlO4 samples were synthesized, characterized and analyzed thermogravimetrically (dynamically and isothermally), under different CO2 conditions. Additionally, chemisorption/desorption cycles were performed for the best chemical compositions and thermal conditions determined. While the CO2 chemisorption of the Na- and K-doped β-Li5AlO4 samples was improved at high temperatures (450 -700 °C), the opposite effect was observed at lower temperatures as well as in the presence of water vapor.

Type
Articles
Copyright
Copyright © Materials Research Society 2015 

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References

REFERENCES

D´Alessandro, D.M., Smit, B. and Long, J.R., Angew. Chem. Int. Ed. 49, 2 (2010).Google Scholar
Qiang, W., Luo, J., Zhong, Z. and Borgna, A., Energy Environ. Sci. 4, 42 (2011).Google Scholar
Choi, S., Drese, J.H. and Jones, C.W., ChemSusChem 2, 796 (2009).CrossRefGoogle Scholar
Ávalos-Rendón, T., Lara, V.H. and Pfeiffer, H., Ind. Eng. Chem. Res. 51, 2622 (2012).CrossRefGoogle Scholar
Ávalos-Rendón, T and Pfeiffer, H., Ener. Fuels 26, 3110 (2012).CrossRefGoogle Scholar
Olivares-Marín, M., Drage, T. and Maroto-Valer, M., Int. J. Greenhouse Gas Control 4, 623 (2010).CrossRefGoogle Scholar
Seggiani, M., Puccini, M. and Vitolo, S., Int. J. Greenhouse Gas Control 5, 741 (2011).CrossRefGoogle Scholar
Sing, K.S.W., Everett, D.H., Haul, R.A.W., Moscou, L., Pierotti, R.A., Rouquerol, J. and Siemieniewska, T., Pure & Appl. Chem. 57, 603 (1985).CrossRefGoogle Scholar