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Chemical Route to Aluminosilicate Gels, Glasses and Ceramics

Published online by Cambridge University Press:  28 February 2011

J. C. Pouxviel
Affiliation:
Groupe de Chimie du Solide, Laboratoire de Physique de la Matière Condensée, Ecole Polytechnique, 91128 Palaiseau Cédex, France Also at Saint-Gobain Recherche, 38 Quai Lucien-Lefranc, 93304 Aubervilliers, France
J. P. Boilot
Affiliation:
Groupe de Chimie du Solide, Laboratoire de Physique de la Matière Condensée, Ecole Polytechnique, 91128 Palaiseau Cédex, France
A. Dauger
Affiliation:
E.N.S.C.I., 47-73 Avenue A. Thomas, 87065 Limoges Cédex, France
L. Huber
Affiliation:
Laboratoire de Chimie de Coordination, Université de Nice, Parc Valrose, 06034 Nice Cédex, France.
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Abstract

Chemically ultra-homogeneous gels have been prepared, in the SiO2-Al2O3 system, using new metal-organic precursors with Al-O-Si linkages. By thermal treatment at 900°C, transparent monolithic gels lead to aluminosilicate glasses and above 1000°C, to optically transparent glass-ceramics (for instance by homogeneous crystallization of mullite in an amorphous silica matrix).

Type
Articles
Copyright
Copyright © Materials Research Society 1986

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References

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