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Chemical Interactions at Metal-Polymer Interfaces

  • P. O. Hahn (a1), G. W. Rubloff (a1), J. W. Bartha (a1), F. Legoues (a1), R. Tromp (a1) and P. S. Ho (a1)...

Abstract

This paper summarizes recent studies on metal-polymer interfaces for Cu, Ni and Cr on a high temperature polymer, polyimide. First some surface and bulk chemical properties of polyimide are described briefly, as measured with surface spectroscopies and verified by theoretical molecular orbital calculations. Then the chemical bonding and reactivity of the three interfaces are described and discussed in light of experimental observations of electronic structure, composition and interface morphology. The chemical trend of increasing reactivity of the interface is illustrated by comparing results from Cu to Cr.

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1. Duke, C.B., Int. Journal of Quantum Chemistry, Quantum Chemistry Symposium, 13, (John Wiley, N.Y.), 267(1979).
2. Duke, C.B., Salaneck, W.R., Fabish, T.J., Ritsko, J.J., Thomas, H.R., and Paton, A., Phys. Rev. B1518, 5717 (1978).
3. Fabish, T.J., CRC Critical Reviews in Solid State and Material Science, 383, (1979).
4. Wilson, A.M., Thin Solid Films 83, 145 (1981).
5. Duke, C.B., Bigelow, R.W., Dilks, A., Paton, A., Salaneck, W.R., and Thomas, H.R., Chem. Phys. Letters 83, 255 (1981).
6. Ford, W.K., Duke, C.B., and Paton, A., J. Chem. Phys. 78, 4734 (1983).
7. Winters, H. “Plasma etching” Review papers.
8. Winters, H. “RIE” Review papers
9. Srinivasah, R., J. Vac. Sci. Technol. B 1 (4) Oct.-Dec., 1983.
10. Burkstrand, J.M., J. Vac. Sci. Technol. 16, 363 (1979).
11. Burkstrand, J.M., J. Appl. Phys. 52, 4795 (1981).
12. Batich, C.D. and Wendt, R.C., Photon, Electron, and Ion Probes of Polymer Structure and Properties, ACS Symposium Series 162, (American Chemical Society, Washington, D.C., 1981), p. 221.
13. Clark, D.T., CRC Critical Reviews in Solid State and Material Science, 1 (1978).
14. Leary, H.J. and Campbell, jD. S., Photon, Electron, and Iron Probes of Polymer Structure and Properties, ACS Symposium Series 162, (American Chemical Society, Washington, D.C., 1981), p. 419.
15. Briggs, D., J. Vac. Sci. Technol. (in press).
16. Hahn, P.O., Rubloff, G.W., Clabes, J.G. and Ho, P.S., Phys. Rev. Let., in preparation.
17. Buchwalter, P.L. and Baise, A.I., Polyimides, Synthesis, Characterization and Applications, Vol.1, ed. by Mittal, K.L. (Plenum Press, N.Y., 1983) in press.
18. Hahn, P.O., Rubloff, G.W., and Ho, P.S., J. Vac. Sci. Technol. (in press).
19. Clark, D.T. et. al. J. of Electron spec. and Rel. Phen. 8 (1976) 51.
20. Silverman, D., et al to be published. Surfa. Sci., 78, (1978) 439458.
21. Gewinner, G., Peruchetti, J.C., Jaegie, A., and Kalt, A.,
22. Tromp, R.M., LeGoues, F. and Ho, P.S. to be published.
23. Legoues, F.K., Hahn, P.O., Bartha, J.W. and Ho, P.S. to be published.

Chemical Interactions at Metal-Polymer Interfaces

  • P. O. Hahn (a1), G. W. Rubloff (a1), J. W. Bartha (a1), F. Legoues (a1), R. Tromp (a1) and P. S. Ho (a1)...

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