Hostname: page-component-848d4c4894-pftt2 Total loading time: 0 Render date: 2024-05-25T06:13:55.726Z Has data issue: false hasContentIssue false
  • English
  • Français

Chemical and Physical Properties of Soluble Part of Emeraldine: Comparison with Insoluble Emeraldine

Published online by Cambridge University Press:  25 February 2011

R. Laversanne  and
P. Vaca
R. Laversanne
Affiliation:
Centre de Recherche Paul Pascal, CNRS, Château Brivazac, F-33600 Pessac, FRANCE
P. Vaca
Affiliation:
Laboratoire CPMOH, Université de Bordeaux I, F-33405 Talence, FRANCE
Get access

Abstract

A preliminary physical study of the soluble part of emeraldine is presented. The electrical and magnetic properties of this low weight material are very similar of those of the pristine emeraldine salt. These results emphazise the possible role of short chain species in the conduction mechanism of polyaniline. In order to clarify this point, previous magnetic investigations on insoluble emeraldine salts are revisited. It appears that the fit of the magnetic susceptibility temperature dependence of polyaniline with a Curie law plus a Pauli term might not be justified at low temperature. A T−α law with a ≈ 0.75 gives a better fit suggesting a behavior similar to the one found in Random Exchange Heisenberg Antiferromagnetic Chain (REHAC)

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 173: Symposium Q – Advanced Organic Solid State Materials , 1989 , 323
Copyright
Copyright © Materials Research Society 1990

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1. de Surville, R., Josefowicz, M., Yu, L.T., Périchon, J. and Buvet, R.,Electrochim. Acta, 13, 1451 (1968).CrossRefGoogle Scholar
2. MacDiarmid, A.G., Chiang, J.C., Halpem, M., Huang, W.S., Mu, S.L., Somasiri, N.L.D., Wu, W. and Yaniger, S.I., Mol. Cryst. Liq. Cryst., 121 173 (1985)Google Scholar
3. Genies, E.M. and Tsintavis, C., J. Electroanal. Chem., 200, 127 (1986)CrossRefGoogle Scholar
4. Chiang, J.C. and MacDiarmid, A.G., Synth. Metal., 13, 193 (1986)Google Scholar
5. For a recent review, see Proceedings of the International Conference on Science and Technology of Synthetic Metals (ICSM '88) Santa Fe, NM, USA June 26-July 2,1988, in Synth. Metal., 29, E141-E457 (1989).Google Scholar
6. Epstein, A.J., Ginder, J.M., Zuo, F., Bigelow, R.W., Woo, H.S., Tanner, D.B., Richter, A.F., Huang, W.S. and MacDiarmid, A.G., Synth. Metal., 18, 303 (1987).CrossRefGoogle Scholar
7. Ginder, J.M., Richter, A.F., MacDiarmid, A.G. and Epstein, A.J., Solid State Comm., 63, 97 (1987).Google Scholar
8. Zuo, F., Angelopoulos, M., MacDiarmid, A.G. and Epstein, A.J., Phys. Rev. B, 36, 3475 (1987).Google Scholar
9. Javadi, H.H.S., Cromack, K.R., MacDiarmid, A.G. and Epstein, A.J., Phys. Rev. B, 39, 3579 (1987).Google Scholar
10. Wudl, F., Angus, R.O. Jr, Lu, F.L., Allemand, P.M., Vachon, D.J., Nowak, M., Liu, Z.X. and Heeger, A.J., J. Amer. Chem. Soc, 109, 3677 (1987)Google Scholar
11. Monkman, A.P., Bloor, D., Stevens, G.C., Stevens, J.C.H. and Wilson, P., Proceedings of the International Conference on Science and Technology of Synthetic Metals (ICSM '88) Santa Fe, NM, USA June 26-July 2, 1988, in Synth. Metal., 29, E277 (1989).CrossRefGoogle Scholar
12. Nechstein, M., Genoud, F., Menardo, C., Mizoguchi, K., Travers, J.P. and Villeret, B., ibid, pE211.Google Scholar
13. Fite, C., Cao, Y. and Heeger, A.J., Solid State Comm., 70, 245 (1989)Google Scholar
14. MacDiarmid, A.G., Chiang, J.C., Richter, A.F., Somasiri, N.L.D. and Epstein, A.J. in Conducting Polymers, edited by Alcacer, L. (D. Reidel Publishing Co., The Netherlands, 1987), p. 105.Google Scholar
15. Ray, A., Asturias, G.E., Kershner, D.L., Richter, A.F., MacDiarmid, A.G. and Epstein, A.J., Proceedings of the International Conference on Science and Technology of Synthetic Metals (ICSM '88) Santa Fe, NM, USA June 26-July 2,1988, in Synth. Metal., 29, E141 (1989).Google Scholar
16. Jozefowicz, M.E., Laversanne, R., Javadi, H.H.S., Epstein, A.J., Pouget, J.P., Tang, X. and MacDiarmid, A.G., Phys. Rev. B, 39, 12958 (1987).Google Scholar
17. LU, F.L., Wudl, F., Nowak, M. and Heeger, A.J., J. Amer. Chem. Soc, 108, 8311 (1986)CrossRefGoogle Scholar
18. MacDiarmid, A.G., Asturias, G.E., Kershner, D.L., Manohar, S.K., Ray, A., Scherr, E.M., Sun, Y., Tang, X. and Epstein, A.J., Polymer Preprints, 30, 147 (1989)Google Scholar
19. Javadi, H.H.S., Laversanne, R., Epstein, A.J., Kohli, R.K., Scherr, E.M. and MacDiarmid, A.G., Proceedings of the International Conference on Science and Technology of Synthetic Metals (ICSM '88) Santa Fe, NM, USA June 26-July 2,1988, in Synth. Metal., 29, E439 (1989)CrossRefGoogle Scholar
20. Inoue, M., Navarro, R.E. and Inoue, M.B., Synth. Metal, 30 (1989)Google Scholar
21. Li, S., Dong, H. and Cao, Y., Proceedings of the International Conference on Science and Technology of Synthetic Metals (ICSM '88) Santa Fe, NM, USA June 26-July 2,1988, in Synth. Metal., 29, E329 (1989).Google Scholar
22. Mizoguchi, K., Nechstein, M., Travers, J.P. and Menardo, C., ibid, p E417Google Scholar
23. Bulaevskii, L.N., Zvarykina, A.V., Karimov, Y.S., Lyubovskii, R.B. and Shchegolev, I.F., Sov. phys. JETP, 35, 384 (1972)Google Scholar
Theodorou, G. and Cohen, M.H., Phys. Rev. B, 16, 4104 (1977)CrossRefGoogle Scholar
Tippie, L.C. and Clark, W.G., ibid, 23, 5854 (1981)CrossRefGoogle Scholar