Hostname: page-component-848d4c4894-4rdrl Total loading time: 0 Render date: 2024-07-05T10:46:14.233Z Has data issue: false hasContentIssue false

Characterization of Boron Carbide Films Formed by PECVD

Published online by Cambridge University Press:  25 February 2011

John Mazurowski
Affiliation:
Department of Physics, Syracuse University, Syracuse, NY. GE Electronics Laboratory, Syracuse, NY.
Sunwoo Lee
Affiliation:
Department of Physics, Syracuse University, Syracuse, NY.
G. Ramseyer
Affiliation:
GE Electronics Laboratory, Syracuse, NY.
P. A. Dowben
Affiliation:
Department of Physics, Syracuse University, Syracuse, NY.
Get access

Abstract

Boron carbide films have been fabricated from pentaborane (B5H9) and methane using plasma enhanced chemical vapor deposition (PECVD). Availability of high quality specimens has facilitated analysis of electronic and optical properties. We have undertaken measurements of photoluminescence spectra and infra-red band-edge absorption. Results show that the bandgap is strongly influenced by the ratio of boron to carbon. There is evidence for the existence of shallow trapping levels.

Type
Research Article
Copyright
Copyright © Materials Research Society 1992

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1. Ploog, Klaus, J. Crystal Growth 24/25, 197204 (1974).Google Scholar
2. Jansson, U., Calisson, J. -O., Stridii, B., Soderberg, S., and Olsson, M., Thin Solid Films 172, 8193 (1989).Google Scholar
3. Kevill, D. N., Rissmann, T. J., Brewe, D., and Wood, C., J. Crystal Growth 74, 210216 (1986).CrossRefGoogle Scholar
4. Cholet, V., Herbin, R., and Vandenbulcke, L., Thin Solid Films 188, 143155 (1990).Google Scholar
5. Mazurowski, J., Baral-Tosh, S., Ramseyer, G., Spencer, J.T., Kim, Yoon-Gi, and Dowben, P.A. in Plasma Processing and Synthesis of Materials, edited by Apelian, D. and Szekely, J. (Mater. Res. Soc. Proc. 190, Pittsburgh, PA 1991) pp. 101106.Google Scholar
6. Cody, G. D., Abeles, B., Wronski, C.R., Brooks, B., and Lanford, W. A., J. Non-Crystalline Solids 35/ 36, 463468 (1980).Google Scholar
7. Taue, J., in Optical Properties of Solids, edited by Abeles, F. (North Holland, Amsterdam, 1972), pp. 279313.Google Scholar
8. Aselage, T. L. and Emin, D. in Boron Rich Solids, edited by Emin, D., Aselage, T. L., Switendick, A. C., Morosin, B., and Beckel, C. L. (American Institute of Physics, New York, 1991) pp. 177185.Google Scholar
9. Emin, D. in Boron Rich Solids, edited by Emin, D., Aselage, T. L., Switendick, A. C., Morosin, B., and Beckel, C. L. (American Institute of Physics, New York, 1991) pp. 6576.Google Scholar
10. Bandyopadhyay, A. K., Beuneu, F., Zuppiroli, L., and Beauvy, M., J. Phys. Chem. Solids 45(2), 207214 (1984).Google Scholar
11. Mazurowski, J., (in preparation).Google Scholar
12. Jansson, U. and Calisson, J. -O., Thin Solid Films 124, 101107 (1985).Google Scholar
13. Samsonov, G. W. and Sinelkova, G. W., Ukr. Fiz. Zh. 6, 687 (1961).Google Scholar