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Catalytic Materials by Design from Hybrid Organic-Inorganics

Published online by Cambridge University Press:  10 February 2011

Joël ,
J.E. Moreau  and
Michel Wong Chi Man
Joël
Affiliation:
UPRESA 5076, Laboratorie de Chimie Organométallique, Ecole Nationale Supérieure de Chimie, 8, rue de l'Ecole Normale, 34296 Montpellier Cedex 05, FRANCE.
J.E. Moreau
Affiliation:
UPRESA 5076, Laboratorie de Chimie Organométallique, Ecole Nationale Supérieure de Chimie, 8, rue de l'Ecole Normale, 34296 Montpellier Cedex 05, FRANCE.
Michel Wong Chi Man
Affiliation:
UPRESA 5076, Laboratorie de Chimie Organométallique, Ecole Nationale Supérieure de Chimie, 8, rue de l'Ecole Normale, 34296 Montpellier Cedex 05, FRANCE.
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Abstract

The sol-gel processing of appropriated molecular precursors easily leads to a variety of hybrid organic-inorganic materials with intrinsic properties. This approach is increasingly becoming an interesting way to prepare heterogeneous catalysts. The paper will focus on the use of hybrids for the preparation of selective catalytic materials. Two examples of the use of hybrid polysilsesquioxanes polymers will be given. i) The tailoring of the pore structure of silicas, under mild reaction conditions, based on the temporary introduction of different organic substructures in the hybrid network of polysilsesquioxane gels will be discussed. ii) Also the preparation of new chiral hybrid supports for enantioselective catalysis will be presented.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 519: Symposium O – Organic/Inorganic Hybrid Materials , 1998 , 41
Copyright
Copyright © Materials Research Society 1998

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