- Cited by 21
Techer, Isabelle Advocat, Thierry Lancelot, Joël and Liotard, Jean-Michel 2000. Basaltic glass: alteration mechanisms and analogy with nuclear waste glasses. Journal of Nuclear Materials, Vol. 282, Issue. 1, p. 40.
Abraitis, P.K. McGrail, B.P. Trivedi, D.P. Livens, F.R. and Vaughan, D.J. 2000. Single-pass flow-through experiments on a simulated waste glass in alkaline media at 40°C.. Journal of Nuclear Materials, Vol. 280, Issue. 2, p. 196.
Jégou, C. Gin, S. and Larché, F. 2000. Alteration kinetics of a simplified nuclear glass in an aqueous medium: effects of solution chemistry and of protective gel properties on diminishing the alteration rate. Journal of Nuclear Materials, Vol. 280, Issue. 2, p. 216.
Techer, Isabelle Advocat, Thierry Lancelot, Joël and Liotard, Jean-Michel 2001. Dissolution kinetics of basaltic glasses: control by solution chemistry and protective effect of the alteration film. Chemical Geology, Vol. 176, Issue. 1-4, p. 235.
McGrail, B.P. Bacon, D.H. Icenhower, J.P. Mann, F.M. Puigh, R.J. Schaef, H.T. and Mattigod, S.V. 2001. Near-field performance assessment for a low-activity waste glass disposal system: laboratory testing to modeling results. Journal of Nuclear Materials, Vol. 298, Issue. 1-2, p. 95.
Gin, S Jollivet, P Mestre, J.P Jullien, M and Pozo, C 2001. French SON 68 nuclear glass alteration mechanisms on contact with clay media. Applied Geochemistry, Vol. 16, Issue. 7-8, p. 861.
Bois, L Barré, N Guittet, M.J Guillopé, S Trocellier, P Gautier-Soyer, M Verdier, P and Laurent, Y 2002. Aqueous corrosion of lanthanum aluminosilicate glasses: influence of inorganic anions. Journal of Nuclear Materials, Vol. 300, Issue. 2-3, p. 141.
Wolff-Boenisch, Domenik Gislason, Sigurdur R. Oelkers, Eric H. and Putnis, Christine V. 2004. The dissolution rates of natural glasses as a function of their composition at pH 4 and 10.6, and temperatures from 25 to 74°C. Geochimica et Cosmochimica Acta, Vol. 68, Issue. 23, p. 4843.
Rogers, Jennifer Roberts and Bennett, Philip C 2004. Mineral stimulation of subsurface microorganisms: release of limiting nutrients from silicates. Chemical Geology, Vol. 203, Issue. 1-2, p. 91.
Icenhower, Jonathan P. Samson, S. Lüttge, A. and McGrail, B. P. 2004. Towards a consistent rate law: glass corrosion kinetics near saturation. Geological Society, London, Special Publications, Vol. 236, Issue. 1, p. 579.
Wellman, D.M. Icenhower, J.P. and Weber, W.J. 2005. Elemental dissolution study of Pu-bearing borosilicate glasses. Journal of Nuclear Materials, Vol. 340, Issue. 2-3, p. 149.
Djanarthany, S. and Trocellier, P. 2007. IBA and SIMS coupling to study glass alteration mechanisms. Journal of Non-Crystalline Solids, Vol. 353, Issue. 52-54, p. 4830.
Minet, Y. Bonin, B. Gin, S. and Frugier, P. 2010. Analytic implementation of the GRAAL model: Application to a R7T7-type glass package in a geological disposal environment. Journal of Nuclear Materials, Vol. 404, Issue. 3, p. 178.
Neeway, J. Abdelouas, A. Grambow, B. and Schumacher, S. 2011. Dissolution mechanism of the SON68 reference nuclear waste glass: New data in dynamic system in silica saturation conditions. Journal of Nuclear Materials, Vol. 415, Issue. 1, p. 31.
Jollivet, P. Gin, S. and Schumacher, S. 2012. Forward dissolution rate of silicate glasses of nuclear interest in clay-equilibrated groundwater. Chemical Geology, Vol. 330-331, Issue. , p. 207.
Aloy, A. S. Trofimenko, A. V. Kol’tsova, T. I. and Nikandrova, M. V. 2012. Formation of surface layers in leaching of borosilicate glasses incorporating different amounts of simulated HLW. Radiochemistry, Vol. 54, Issue. 3, p. 291.
Kerisit, Sebastien and Pierce, Eric M. 2012. Monte Carlo simulations of the dissolution of borosilicate glasses in near-equilibrium conditions. Journal of Non-Crystalline Solids, Vol. 358, Issue. 10, p. 1324.
Gin, Stéphane Jollivet, Patrick Fournier, Maxime Berthon, Claude Wang, Zhaoying Mitroshkov, Alexandre Zhu, Zihua and Ryan, Joseph V. 2015. The fate of silicon during glass corrosion under alkaline conditions: A mechanistic and kinetic study with the International Simple Glass. Geochimica et Cosmochimica Acta, Vol. 151, Issue. , p. 68.
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Rahman, Shaily Tamborski, Joseph J. Charette, Matthew A. and Cochran, J. Kirk 2019. Dissolved silica in the subterranean estuary and the impact of submarine groundwater discharge on the global marine silica budget. Marine Chemistry, Vol. 208, Issue. , p. 29.
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The objective of this work was to develop a more representative mathematical formulation of the alteration kinetics of the borosilicate SON68 glass by combining three approaches: (1) Compare extensive prior experimental static leaching results for SON68 glass with the first-order kinetic law in which silica is the predominant element, (2) Assess the exact role of dissolved silica on the alteration rate under conditions near and far from saturation, by means of dynamic leach tests and, (3) Compare the new data with the general kinetic law for silicates in which the reaction affinity, catalysis and inhibition are the three influencing factors.
Hide All1 Pederson, L.R., Buckwalter, C.Q. and McVay, G.L., “The Effect of Surface Area to Solution Volume on Waste Glass Leaching”, in Sci. Basis for Nuclear Waste Management, vol. VI. (1983).2 Wallace, R. and Wicks, G., “Leaching Chemistry of Defense Borosilicate Glass”, in Sci. Basis for Nuclear Waste Management, vol. VI (1983).3 Grambow, B., “A General Rate Equation for Nuclear Waste Glass Corrosion”, in Sci. Basis for Nuclear Waste Management, vol. VIII (1985).4 Freude, E., Grambow, B., Luitze, W., Rabe, H. and Ewing, R.C., “Borosilicate Glass Alteration”, in Sci. Basis for Nuclear Waste Management, vol. VIII (1985).5 Grambow, B. and Strachan, D., A Comparison of Performance of Nuclear Waste Glass by Modeling. PNL 6698, Richland. WA (1988).6 Advocat, T., Crovisier, J.L., Fritz, B. and Vernaz, E., “Thermokinetic Model of Borosilicate Glass Dissolution”, in Sci. Basis for Nuclear Waste Management, vol. XIII (1990).7 Inagaki, I. and Furuya, H., “Corrosion Behavior of a Powered Simulated Nuclear Waste Glass under Anoxic Condition”, in Sci. Basis for Nuclear Waste Management, vol. XVIII (1995).8 Bourcier, B., Knauss, K. and Merzbacher, C., “A Kinetic Model for Borosilicate Glass Dissolution”. Proc. 6th inter. Symp. Water-Rock Interactions, Malvern, UK, AA (1989).9 Gin, S., “Control of SON68 Nuclear Glass Alteration Kinetics under Saturation Conditions”, in Sci. Basis for Nuclear Waste Management, vol. XIX (1996).10 Daux, V., Guy, C., Advocat, T., Crovisier, J. L., Stille, P.. “Kinetics aspects of basaltic glass dissolution at 90'C : röle of aqueous silicon and aluminum”. Chemical Geology (under Press).11 Vernaz, E., Advocat, T., Dussossoy, J. L.. “Effects of the SA/V ratio on the long-term corrosion kinetics of SON68 glass”, Nuclear Waste Management III, Ceramic Trans. 9, 175–185, (1990).12 Lasaga, A., “Rate Law of Chemical Reactions. Kinetics of Geochemical Processes”, Min. Soc. Amer., Reviews in Mineralogy, vol. 8, p. 1–68 (1981).13 Aagaard, P. and Helgeson, H., “Thermodynamic and Kinetic Constraints on Reaction Rates among Minerals and Aqueous Solutions”, Amer. J. Sci., vol. 282, p. 237–285 (1982).14 Nagy, K.L., Blum, A. and Lasaga, A., “Dissolution and Precipitation Kinetics of Kaolinite at 80°C and pH3: Dependence on Solution Saturation State”, Amer. J. of Sci. No 291 (1991).15 Paul, A., “Chemical Durability of Glasses: A Thermodynamic Approach”, J. of Mater. Sci., vol. 12 (1977).16 Jantzen, C. and Plodinec, M., “Thermodynamic Model of Natural, Medieval and Nuclear Waste Glass Durability”, Journ. of Non Cryst. Solids 67 (1984).
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