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Assembly of Metal-Anion Arrays within Dion-Jacobson-Type Perovskite Hosts

Published online by Cambridge University Press:  18 March 2011

Thomas A. Kodenkandath ,
Marilena L. Viciu ,
Xiao Zhang ,
Jessica A. Sims ,
Erin W. Gilbert ,
François-Xavier Augrain ,
Jean-Noël Chotard ,
Gabriel A. Caruntu ,
Leonard Spinu  and
Weilie L. Zhou
...Show all authors
Thomas A. Kodenkandath
Affiliation:
Current address American Superconductor, Westborough, MA 01581
Marilena L. Viciu
Affiliation:
Department of Chemistry and the Advanced Materials Research Institute, University of New Orleans, New Orleans, LA 70148-2820
Xiao Zhang
Affiliation:
Department of Chemistry and the Advanced Materials Research Institute, University of New Orleans, New Orleans, LA 70148-2820
Jessica A. Sims
Affiliation:
Department of Chemistry and the Advanced Materials Research Institute, University of New Orleans, New Orleans, LA 70148-2820
Erin W. Gilbert
Affiliation:
Department of Chemistry and the Advanced Materials Research Institute, University of New Orleans, New Orleans, LA 70148-2820
François-Xavier Augrain
Affiliation:
Department of Chemistry and the Advanced Materials Research Institute, University of New Orleans, New Orleans, LA 70148-2820
Jean-Noël Chotard
Affiliation:
Department of Chemistry and the Advanced Materials Research Institute, University of New Orleans, New Orleans, LA 70148-2820
Gabriel A. Caruntu
Affiliation:
Department of Chemistry and the Advanced Materials Research Institute, University of New Orleans, New Orleans, LA 70148-2820
Leonard Spinu
Affiliation:
Department of Chemistry and the Advanced Materials Research Institute, University of New Orleans, New Orleans, LA 70148-2820
Weilie L. Zhou
Affiliation:
Department of Chemistry and the Advanced Materials Research Institute, University of New Orleans, New Orleans, LA 70148-2820
John B. Wiley
Affiliation:
To whom correspondence should be addressedjwiley@uno.edu
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Abstract

The construction of metal-anion arrays within Dion-Jacobson-type (DJ) perovskites was studied. A variety of hosts readily react with CuCl2 to produce compounds of the form (CuCl)[A'n-1(M,M')nO3n+1] (A' = alkaline earth, rare earth or Bi; M/M' = Nb, Ta, and/orTi; n = 2, 3). In contrast, CuBr2 only reacts with some of these hosts; this difference relative to the chloride may simply be a size effect. The formation of metal-anion arrays with other transition metals has also been examined. (FeCl)LaNb2O7 can be readily prepared from FeCl2, while reactions with FeBr2and NiCl2 under similar reaction conditions result in compounds of the formM0.5LaNb2O7 (M = Fe, Ni). The reductive intercalation of lithium and sodium into (CuCl)LaNb2O7 was also examined and was found to produce new compounds that have a large layer expansion.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 658: Symposium GG – Solid-State Chemistry of Inorganic Materials III , 2000 , GG5.8
Copyright
Copyright © Materials Research Society 2001

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References

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