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An Organotin Oxo-Carboxylate Cluster Functionalized by Triethoxysilyl Groups

Published online by Cambridge University Press:  01 February 2011

François O. Ribot ,
Delphine Minoux  and
Clément Sanchez
François O. Ribot
Affiliation:
Chimie de la Matière Condensée (UMR CNRS 7574) - Université Pierre et Marie Curie 75252 Paris, FRANCE
Delphine Minoux
Affiliation:
Chimie de la Matière Condensée (UMR CNRS 7574) - Université Pierre et Marie Curie 75252 Paris, FRANCE
Clément Sanchez
Affiliation:
Chimie de la Matière Condensée (UMR CNRS 7574) - Université Pierre et Marie Curie 75252 Paris, FRANCE
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Abstract

The organotin oxo-carboxylate cluster {BuSnO(O2CC6H4-4-NH2)}6 (1), which exhibits a hexagonal prismatic oxo-core, was synthesized from BuSnO (OH) and p-aminobenzoic acid. Its peripheral functionalization with triethoxysilyl moieties was achieved through the reaction with 3-isocyanatopropyltriethoxysilane (ICPTES) which preserves the oxo-carboxylate framework and yields {BuSnO[O2CC6H4-4-NHC (O)NH (CH2)3Si (OEt)3]}6 (2). Both compounds were characterized by multinuclear NMR (119Sn, 1H, 13C, 29Si).

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 628: Symposium CC – Hybrid Organic/Inorganic Materials , 2000 , CC2.2
Copyright
Copyright © Materials Research Society 2000

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References

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