Hostname: page-component-76fb5796d-wq484 Total loading time: 0 Render date: 2024-04-26T01:40:35.610Z Has data issue: false hasContentIssue false
  • English
  • Français

An isotropic glass phase in Al-Fe-Si formed by a first order transition

Published online by Cambridge University Press:  01 February 2011

John W. Cahn  and
Leonid A. Bendersky
John W. Cahn
Affiliation:
Materials Science and Engineering Laboratory, National Institute of Standards and Technology, Gaithersburg, MD 20899, USA
Leonid A. Bendersky
Affiliation:
Materials Science and Engineering Laboratory, National Institute of Standards and Technology, Gaithersburg, MD 20899, USA
Get access

Abstract

We present evidence of the nucleation and growth of a metallic glass phase from the melt, as if by a first-order transition. Microstructures of a number of rapidly solidified Al-Fe-Si alloys demonstrate that this glassy phase, which we term q-glass, is not a kinetically frozen liquid. It is the first phase to form from the melt as isolated nuclei that grow and deplete the melt of iron and silicon. From the nucleation behavior and the compositional partitioning, we infer an interface between the q-glass and the melt, and that, in a narrow composition range, the q-glass has a lower energy and entropy (is more ordered) than a conventional glass.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 806: Symposium MM – Amorphous and Nanocrystalline Metals , 2003 , MM2.7
Copyright
Copyright © Materials Research Society 2004

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1. Bendersky, L.A., Biancaniello, F.S. and Schaefer, R.J., J. Mater. Res., 2, 427 (1987).Google Scholar
2. Bendersky, L.A., Kaufman, M.J., Boettinger, W.J. and Biancaniello, F.S., Mat. Sci. Eng., 98, 213 (1988).Google Scholar
3. Angell, A., Sol. State Sci. 2, 791 (2000).Google Scholar
4. Inoue, A., Prog. Mater. Sci., 43, 365 (1998).Google Scholar
5. Cahn, J. W., J. Am. Ceram. Soc., 52, 118 (1969).Google Scholar
6. Suzuki, R.O., Komatsu, Y., Kobayashi, K.F. and Shingu, P.H., J. Mater. Sci., 18, 1195 (1983).Google Scholar
7. Dubois, J.M., Dehghan, K., Janot, C., Chieux, P. and Chenal, B., J. Phys., 46, Colloq. C8–461 (1985).Google Scholar
8. Legresy, J.M., Audier, M., Simon, J.P. and Guyot, P., Acta Metall., 34, 1759 (1986).Google Scholar
9. Liu, Z. K. and Chang, Y. A., Metall. Mater. Trans., 30, 1081 (1999).Google Scholar
10. Rept. of Ad Interim Commission on Aperiodic Crystals, Acta Cryst. A 48, 928 (1992).Google Scholar
11. Senechal, M., Quasicrystals and Geometry, Cambridge Univ. Press, New York (1995). Chapt 7.Google Scholar
12. Orimo, S. and Fujii, H., Appl. Phys., A 72, 167 (2001), figure 12.Google Scholar
13. Kirchheimer, R., private communication.Google Scholar