Hostname: page-component-8448b6f56d-dnltx Total loading time: 0 Render date: 2024-04-19T00:02:00.913Z Has data issue: false hasContentIssue false

An extended Cahn-Hilliard model for interfaces with cubic anisotropy

Published online by Cambridge University Press:  17 March 2011

T.A. Abinandanan
Affiliation:
Department of Metallurgy, Indian Institute of Science, Bangalore 560 012, India Institut für Physik, Universitäat Augsburg, Universitäatstr. 1, D-86159 Augsburg, Germany
F. Haider
Affiliation:
Institut für Physik, Universitäat Augsburg, Universitäatstr. 1, D-86159 Augsburg, Germany
Get access

Abstract

For studying systems with a cubic anisotropy in interfacial energy σ, we extend the CahnHilliard model by including in it a fourth rank term, which leads to an additional linear term in the evolution equation for the composition field. It also leads to an orientation-dependent effective fourth rank coeficient γ(hkl) in the governing equation for the one-dimensional composition profile across a planar interface. The main effect of a non-negative γ(hkl) is to increase both σ and interfacial width w, each of which, upon suitable scaling, is related to γ(hkl) through a universal scaling function. The anisotropy in the interfacial energy can be large enough to give rise to corners in the Wulff shapes in two dimensions. In particles of finite sizes, the corners get rounded, and their shapes tend towards the Wulff shape with increasing particle size. In the study of unmixing of concentrated alloys, the anisotropy nt only leads to non-spherical particle shapes, but also to strongly elongated morphologies.

Type
Research Article
Copyright
Copyright © Materials Research Society 2002

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

[1 ] Cahn, J.W. and Hilliard, J.E., J.Chem.Phys., 28, 258, (1958).Google Scholar
[2 ] Cahn, J.W., Acta Metall., 9, 795, (1961).Google Scholar
[3 ] Abinandanan, T.A. and Haider, F., phil. mag. A, 81, 2457, (2001)Google Scholar
[4 ] Herring, C., in Structure and Properties of Solid Surfaces, edited by Gomer, R. and Smith, C.S. (University of Chicago, Chicago, 1952).Google Scholar