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Aluminum/Copper Nanocomposites Fabricated by The Jet Vapor Depositiontm Process

Published online by Cambridge University Press:  15 February 2011

Rebecca L. Lankey
Affiliation:
Department of Materials Science and Engineering, School of Engineering, Thornton Hall, University of Virginia, Charlottesville, VA 22903-2442
L.M. Hsiung
Affiliation:
Department of Materials Science and Engineering, School of Engineering, Thornton Hall, University of Virginia, Charlottesville, VA 22903-2442
H.N.G. Wadley
Affiliation:
Department of Materials Science and Engineering, School of Engineering, Thornton Hall, University of Virginia, Charlottesville, VA 22903-2442
S.M. Karecki
Affiliation:
Jet Process Corporation, 24 Science Park, New Haven, CT 06511
D.T. Smith
Affiliation:
Ceramics Division, National Institute of Standards and Technology, Bldg. 223, Room A329, Gaithersburg, MD 20899
B.L. Halpern
Affiliation:
Jet Process Corporation, 24 Science Park, New Haven, CT 06511
J.J. Schmitt
Affiliation:
Jet Process Corporation, 24 Science Park, New Haven, CT 06511
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Abstract

Aluminum and copper nanolaminates have been fabricated at Jet Process Corporation using the novel, proprietary Jet Vapor DepositionTM (JVD)TM process. Laminates with a total thickness of 10 μm were made by depositing alternating layers ofapproximately equal thicknesses of copper and aluminum onto preheated silicon wafers at asubstrate temperature of ∼140 °C. The layer thicknesses were systematicallyvaried between 20 nm and 1 μm. The microstructure and properties of the laminates were investigated using transmission electron microscopy (TEM), scanning electron microscopy (SEM), and nanoindentation methods. TEM has shown that the laminates have a strong {111} texture. The hardness results show that above a critical layer thickness of approximately 50 nm, the yield strength of the composites varies inversely with thelayer thickness, while the strength of nanolaminates with layer thicknesses smaller than the critical thickness is better explained by the Koehler model. An alternative model recently proposed by Embury and Hirth fits the data equally well.

Type
Research Article
Copyright
Copyright © Materials Research Society 1995

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References

REFERENCES

1. Hsiung, L.M., Zhang, J.Z., McIntyre, D.C., Golz, J.W., Halpern, B.L., Schmitt, J.J., and Wadley, H.N.G., Scripta Metall. Mater. 29, 293 (1993).Google Scholar
2. Hsiung, L.M., Lankey, R.L., Wadley, H.N.G., Smith, D.T., Zhang, J.Z., Golz, J.W., Halpern, B.L. and Schmitt, J.J., in Proceedings of International Symposium on Novel Techniques in Synthesis and Processing of Advanced Materials, edited by Singh, J. and Copely, S.M. (TMS, Warrendale, 1995), in press.Google Scholar
3. Halpern, B.L., J. Colloid & Interface Sci. 86, 337 (1982).Google Scholar
4. Schmitt, J.J., U.S. Patent No. 4 788 082 (29 November 1988).Google Scholar
5. Halpern, B.L., Schmitt, J.J., Di, Y., Golz, J.W., Johnson, D.L., McAvoy, D.T., Wang, D. and Zhang, J.Z., Metal Finishing, 37 (December 1992).Google Scholar
6. Halpern, B.L. and Schmitt, J.J., in Handbook of Deposition Technologies for Films and Coatings, edited by Bunshah, R.F. (Noyes Publications, Park Ridge, New Jersey, 1994), p. 822.Google Scholar
7. Cohen, U., Koch, F.B. and Sard, R., J. Electrochem. Soc. 130, 1987 (1983).Google Scholar
8. Barnett, S.A., in Physics of Thin Films, edited by Francombe, M.H. and Vossen, J.L., 17 (1993), p. 1.Google Scholar
9. Embury, J.D. and Hirth, J.P., Acta Metall. 42, 2051 (1994).Google Scholar
10. Koehler, J.S., Phys. Rev. B 2, 547 (1970).Google Scholar
11. Lehoczky, S.L., J. Appl. Phys. 49, 5479 (1978).Google Scholar
12. Hull, D. and Bacon, D.J., Introduction to Dislocations, 3rd ed., (Pergamon Press, 1984).Google Scholar
13. Stoloff, N.S., in Alloy and Microstructural Design, edited by Tien, J.K. and Ansell, G.S. (Academic Press, New York, 1976), p. 65.Google Scholar
14. Thompson, E.R. and Lemkey, F.D., in Metal Matrix Composites, edited by Kreider, K.G. (Academic Press, New York, 1974), p. 539.Google Scholar
15. Springer, R.W. and Catlett, D.S., Thin Solid Films 54, 197 (1978).Google Scholar
16. Bickerdike, R.L., Clark, D., Easterbrook, J.N., Hughes, G., Mair, W.N., Partridge, P.G. and Ranson, H.C., Internat. J. Rapid Solidification 1, 305 (1984-1985).Google Scholar
17. Alpas, A.T., Embury, J.D., Hardwick, D.A. and Springer, R.W., J. Mater. Sci. 25, 1603 (1990).Google Scholar
18. Chou, T.C., Nieh, T.G., McAdams, S.D., Pharr, G.M. and Oliver, W.C., J. Mater. Res. 7, 2774 (1992).Google Scholar
19. Foecke, T. and Lashmore, D.S., Scripta Metall. Mater. 27, 651 (1992).Google Scholar
20. Oliver, W.C. and Pharr, G.M., J. Mater. Res. 7, 1564 (1992).Google Scholar