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Ti - Substituted Mesoporous Molecular Sieves for Catalytic Oxidation of Large Aromatic Compounds Prepared by Neutral Templating Route

Published online by Cambridge University Press:  28 February 2011

Thomas J. Pinnavaia ,
Peter T. Tanev ,
Jialiang Wang  and
Wenzhong Zhang
Thomas J. Pinnavaia
Affiliation:
Department of Chemistry and Center for Fundamental Materials Research, Michigan State University, East Lansing, MI 48824
Peter T. Tanev
Affiliation:
Department of Chemistry and Center for Fundamental Materials Research, Michigan State University, East Lansing, MI 48824
Jialiang Wang
Affiliation:
Department of Chemistry and Center for Fundamental Materials Research, Michigan State University, East Lansing, MI 48824
Wenzhong Zhang
Affiliation:
Department of Chemistry and Center for Fundamental Materials Research, Michigan State University, East Lansing, MI 48824
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Abstract

A new synthesis route to open framework mesostructures based on H-bonding and self-assembly between neutral primary amine surfactants (S°) and neutral inorganic precursors (I°) has been used to prepare hexagonal mesoporous silicas containing site isolated titanium centers. These new titanosilicates, designated Ti-HMS, exhibit exceptional catalytic reactivity for the oxidation of substrates too large to access the pore structure of conventional titanosilicates, such as titanium silicalite, TS-1. The catalytic properties of Ti-HMS materials for the peroxide oxidation of 2,6- di- tert-butylphenol are compared with those of microporous TS-1 and a mesoporous Ti-MCM-41 analog prepared by an electrostatic templating mechanism using a liquid crystal quaternary ammonium cationic surfactant.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 371: Symposium W1 – Advances in Porous Materials , 1994 , 53
Copyright
Copyright © Materials Research Society 1995

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References

References and Notes

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