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Study of Glass Transition Based on the Fragmentation Model

Published online by Cambridge University Press:  21 February 2011

Y. Masaki ,
A. Kitagawa  and
M. Suzuki
Y. Masaki
Affiliation:
Department of Electrical and Computer Engineering, Kanazawa University, 2-40-20 Kodatsuno, Kanazawa 920, Japan, masaki@ect.kanazawa-u.ac.jp
A. Kitagawa
Affiliation:
Department of Electrical and Computer Engineering, Kanazawa University, 2-40-20 Kodatsuno, Kanazawa 920, Japan, masaki@ect.kanazawa-u.ac.jp
M. Suzuki
Affiliation:
Department of Electrical and Computer Engineering, Kanazawa University, 2-40-20 Kodatsuno, Kanazawa 920, Japan, masaki@ect.kanazawa-u.ac.jp
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Abstract

Glass transition phenomena for a fictive V2-VI3 compound have been described on the basis of fragmentation model in which glass materials begin to fragmentize at a certain temperature and the fragment size becomes small with increasing temperature. By a numerical calculation, the heating rate dependence of glass transition temperature was clearly presented, and fragment sizes at glass transition and melting temperature were estimated as 1.4μm and 20Å respectively. Further, thermodynamic aspects were discussed using the model and it was concluded that the glass transition is a sort of the first order transition.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 398: Symposium C – Thermodynamics and Kinetics of Phase Transformations , 1995 , 369
Copyright
Copyright © Materials Research Society 1998

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References

REFERENCES

1 Suzuki, M., Masaki, Y. and Kitagawa, A., to be published in Phys. Rev. B.Google Scholar
2 Masaki, Y., Suzuki, M. and Kitagawa, A., to be published in Thermochim. Acta.Google Scholar
3 Glazov, V. M., Chizhevskaya, S. N. and Glagoleva, N. N., Liquid Semiconductors. (Plenum Press, New York, 1969), pp.4–6.Google Scholar
4 Phillips, J. C., J. Non-Cryst. Solids, 34, 153 (1979).Google Scholar
5 Elliott, S. R., in Glasses and Amorphous Materials, edited by Zarzycki, J. (VCH Publications Inc., New York, 1991), Chap.7.Google Scholar
6 Elliott, S. R., Physics of Amorphous Materials. (Longman, Harlow, 1983), pp.110.Google Scholar
7 Zarzycki, J., Glasses and the Vitreous States (Cambridge University Press, Cambridge, 1991), pp.68.Google Scholar
8 Nakayama, K., Kojima, K., Takahashi, N., Masaki, Y., Kitagawa, A. and Suzuki, M., presented at the 1995 MRS Fall Meeting (this meeting), Boston, MA, 1995.Google Scholar