Skip to main content Accessibility help
×
Home
Hostname: page-component-559fc8cf4f-55wx7 Total loading time: 0.364 Render date: 2021-02-27T23:22:03.047Z Has data issue: true Feature Flags: { "shouldUseShareProductTool": true, "shouldUseHypothesis": true, "isUnsiloEnabled": true, "metricsAbstractViews": false, "figures": false, "newCiteModal": false, "newCitedByModal": true }

Structural and Magnetic Properties of La0.7Sr0.3Mn1-xNixO3 (x=0.05, 0.1, 0.2, 0.3, 0.4)

Published online by Cambridge University Press:  23 June 2011

Thomas F. Creel
Affiliation:
Department of Physics, Missouri University of Science and Technology, Rolla, MO, U.S.A.
Jinbo B. Yang
Affiliation:
State Key Laboratory for Artificial Microstructure and Mesoscopic Physics and School of Physics, Peking University, Beijing
Mehmet Kahveci
Affiliation:
Department of Physics, University of Missouri, Columbia, MO, U.S.A
Jagat Lamsal
Affiliation:
Department of Physics, University of Missouri, Columbia, MO, U.S.A
Satish K. Malik
Affiliation:
Departamento de Física Teórica e Experimental, UFRN, 59072-970 NATAL- RN, Brazil
S. Quezado
Affiliation:
Departamento de Física Teórica e Experimental, UFRN, 59072-970 NATAL- RN, Brazil
B. W. Benapfl
Affiliation:
Department of Physics, University of Notre Dame, IN, U.S.A.
H. Blackstead
Affiliation:
Department of Physics, University of Notre Dame, IN, U.S.A.
O. A. Pringle
Affiliation:
Department of Physics, Missouri University of Science and Technology, Rolla, MO, U.S.A.
William B. Yelon
Affiliation:
Center for Materials Science Research, Missouri University of Science and Technology, Rolla, MO, U.S.A.
William J. James
Affiliation:
Center for Materials Science Research, Missouri University of Science and Technology, Rolla, MO, U.S.A.
Get access

Abstract

We have studied the structural and magnetic properties of La0.7Sr0.3Mn1-xNixO3 (x=0.05, 0.10, 0.20, 0.30, and 0.40) perovskites using x-ray and neutron diffraction and magnetic measurements. To our knowledge, there exists no neutron diffraction data available for this group of perovskite compositions. Neutron (λ = 1.479Å) and x-ray (λ = 1.5481Å; Cu Kα) powder diffraction indicate that for x ≥ 0.1 all samples are two-phase with a rhombohedral perovskite structure (space group R-3c) and a small amount of NiO (space group Fm3m). Neutron diffraction data for the perovskite phase at 12K and 300K show ferromagnetic ordering for x ≤ 0.2 and antiferromagnetic ordering for x = 0.4. However, for x = 0.3, neutron diffraction data at 12K show coexisting ferromagnetic and antiferromagnetic ordering while at 300K no magnetic ordering is found. Magnetic measurements indicate that the Curie temperature decreases with increasing Ni content. The NiO phase for all samples was found to have antiferromagnetic ordering at 12K and 300K. The magnetic measurements are consistent with the neutron diffraction data and together indicate long-range magnetic ordering for samples at low temperature and transitions from ferromagnetic to paramagnetic to antiferromagnetic ordering for samples at room temperature.

Type
Research Article
Copyright
Copyright © Materials Research Society 2011

Access options

Get access to the full version of this content by using one of the access options below.

References

1. Jonker, G. H. and Van Santen, J. H., Physica, vol. 16, 337349, (1950).CrossRefGoogle Scholar
2. Wollan, E. O., Koehler, W. C., Phys. Rev., vol. 100, 545563, (1955)CrossRefGoogle Scholar
3. Goodenough, J. B., Magnetism and the Chemical Bond. (Huntington: Krieger, 1976.)Google Scholar
4. Brorovskikh, L., Mazo, G., Kemnitz, E., Solid State Sci, 5, 409417 (2003)CrossRefGoogle Scholar
5. Voorhoeve, R.J.H., Johnson, D.W., Remeika, J.P., Gallagher, P.K., Science 195, 827833 (1977)CrossRefGoogle ScholarPubMed
6. Vaughey, J.T., Mawdsley, J.R., Krause, T.R., Mater Res Bul, 42, 19631968 (2007)CrossRefGoogle Scholar
7. Millis, A. J., Littlewood, P. B., and Shraiman, B. I., Phys. Rev. Lett., v. 74, (25) 5144 (1995)CrossRefGoogle Scholar
8. Millis, A.J., Phys Rev. B 53, 8434 (1996)CrossRefGoogle Scholar
9. Archiald, W., Zhou, J.-S., Goodenough, J.B., Phys. Rev. B 53, 14445 (1996)CrossRefGoogle Scholar
10. Zener, C., Phys. Rev., vol. 82, 403405 (1951)CrossRefGoogle Scholar
11. Martin, M., Shirane, G., Endoh, Y., Hirota, K., Moritomo, Y., Tokura, , Phys. Rev., 53 (21) 1428514290 (1996)CrossRefGoogle Scholar
12. Zhao, T.-S., Xianyu, W.X., Li, B.H., Qian, Z.N., J of Alloys and Comp., 459, 2934 (2008)CrossRefGoogle Scholar
13. Rubinstein, M., Gillespie, D.J., Snyder, J.e., Tritt, T.M., Phys. Rev. B 56, 5412 (1997)CrossRefGoogle Scholar
14. Wang, Z. H., Cai, J.W., Shen, B.G., Chen, X., Zhan, W.S., J. Phys.:Condens. Matter 12, 601 (2000)Google Scholar
15. Pal, S., Sose, E., Chaudhuri, B.K., Yang, H.D., Neeleshwar, S., Chen, Y.Y., J. Magn. Magn. Mater, 293, 872 (2005)CrossRefGoogle Scholar
16. Toulemonde, O., Suder, F., Barnabe, A., Maignan, A., Martin, C., Raveau, B., Eur. Phys. J. B, 4, 159 (1998)CrossRefGoogle Scholar
17. Wold, , Arnott, R. J., and Goodenough, J. B., J. Appl. Phys, 29, 387389 (1958)CrossRefGoogle Scholar
18. Rodriguez-Carvajal, J., FULLPROF 2K, Version 3.00, Laboratoire Leon Brillouin-JRC, 2004 Google Scholar
19. Shull, C. G., Strauser, W. A., Wollan, E. O, Phys. Rev., 83 (2) 333 (1951)CrossRefGoogle Scholar
20. Creel, T. F., Yang, J.B., Kahveci, M., Lamsal, J., Malik, S. K., Quezado, S., Pringle, O. A., Yelon, W. B., James, W. J., Mag, IEEE Trans, 46 (12) 4113 (2010)CrossRefGoogle Scholar
21. Kuharuangrong, Sutin, Ceramics International, 30, 273 (2004)CrossRefGoogle Scholar
22. Sun, Y., Tong, W., Xu, X, and Zhang, Y., Appl. Phys. Lett, 78 (5) 643645 (2001)CrossRefGoogle Scholar
23. Kanamori, L., J. Phys. Chem. Solids 10, 87 (1959)CrossRefGoogle Scholar
24. Goodenough, J.B., Wold, A., Arnott, R., Menyuk, N., Phys. Rev. 124, 373 (1961)CrossRefGoogle Scholar
25. Kramers, H. A., Physica 1, 182 (1934)CrossRefGoogle Scholar
26. Sanchez, M.C., Garcia, J., Blasco, J., Subias, G., Perez-Cacho, J., Phys. Rev. B 65, 144409 (2002)CrossRefGoogle Scholar
27. Hu, Jifan, Ji, Chengjie, Qin, Hongwei, Chen, Juan, Hao, Yanming, Li, Yangxian, J. of Mag. And Mag. Mat. 241, 271 (2002)CrossRefGoogle Scholar

Full text views

Full text views reflects PDF downloads, PDFs sent to Google Drive, Dropbox and Kindle and HTML full text views.

Total number of HTML views: 0
Total number of PDF views: 10 *
View data table for this chart

* Views captured on Cambridge Core between September 2016 - 27th February 2021. This data will be updated every 24 hours.

Send article to Kindle

To send this article to your Kindle, first ensure no-reply@cambridge.org is added to your Approved Personal Document E-mail List under your Personal Document Settings on the Manage Your Content and Devices page of your Amazon account. Then enter the ‘name’ part of your Kindle email address below. Find out more about sending to your Kindle. Find out more about sending to your Kindle.

Note you can select to send to either the @free.kindle.com or @kindle.com variations. ‘@free.kindle.com’ emails are free but can only be sent to your device when it is connected to wi-fi. ‘@kindle.com’ emails can be delivered even when you are not connected to wi-fi, but note that service fees apply.

Find out more about the Kindle Personal Document Service.

Structural and Magnetic Properties of La0.7Sr0.3Mn1-xNixO3 (x=0.05, 0.1, 0.2, 0.3, 0.4)
Available formats
×

Send article to Dropbox

To send this article to your Dropbox account, please select one or more formats and confirm that you agree to abide by our usage policies. If this is the first time you use this feature, you will be asked to authorise Cambridge Core to connect with your <service> account. Find out more about sending content to Dropbox.

Structural and Magnetic Properties of La0.7Sr0.3Mn1-xNixO3 (x=0.05, 0.1, 0.2, 0.3, 0.4)
Available formats
×

Send article to Google Drive

To send this article to your Google Drive account, please select one or more formats and confirm that you agree to abide by our usage policies. If this is the first time you use this feature, you will be asked to authorise Cambridge Core to connect with your <service> account. Find out more about sending content to Google Drive.

Structural and Magnetic Properties of La0.7Sr0.3Mn1-xNixO3 (x=0.05, 0.1, 0.2, 0.3, 0.4)
Available formats
×
×

Reply to: Submit a response


Your details


Conflicting interests

Do you have any conflicting interests? *