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PNL-Sandia HLW Package Interactions Test: Phase One

Published online by Cambridge University Press:  15 February 2011

Martin A. Molecke
Affiliation:
Sandia National Laboratories, Division 4512, Albuquerque, NM 87185
Donald J. Bradley
Affiliation:
Battelle Pacific Northwest Laboratory, Richland, WA 99352
John W. Shade
Affiliation:
Battelle Pacific Northwest Laboratory, Richland, WA 99352
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Abstract

The first phase of a complex high-level waste (HLW) package interactions test in a salt environment has been completed. The test system consisted of PNL 76–68 HLW glass (loaded with inactive fission products and 238U) surrounded by a stainless steel waste canister, a TiCode- 12 overpack, a bentonite/sand backfill, excess brine leachant, and a bedded rock salt container, all heldwithin a 19-liter autoclave. All components were physically compromised in order to force wasteform-barrier-salt interactions to occur during this 95-day, 250°C overtest. Analyses of leachant, wasteform, and all barrier surfaces were performed. Test data included the synergistic effects between barriers and confirmed previous analyses of simpler systems. The glass wasteform exhibited some surface alteration but was not dissolved to any significant degree. The TiCode-12 overpack showed minimal uniform corrosion and no localized attack. Observed mineralogical alteration of the backfill was minimal.

Type
Research Article
Copyright
Copyright © Materials Research Society 1982

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References

REFERENCES

1 Braithwaite, J. W. and Molecke, M. A., Nuclear Waste Canister Corrosion Studies Pertinent to Geologic Isolation, Nuclear and Chemical Waste Management, 1(1), 1980.Google Scholar
2 Nowak, E. J., The Backfill Barrier as a Component in a Multibarrier Nuclear Waste Isolation System, SAND79–1109, May 1980.Google Scholar
3 Shade, J. W. and Bradley, D. J., Initial Waste Package Interactions Test: Status Report, PNL–3559, December 1980.Google Scholar
4 Mendel, J. E., et al. , A State of the Art Review of Materials Properties of Nuclear Waste Forms, PNL–3082, April 1980.Google Scholar
5 Seyfried, W. E. and Bischoff, J. L., Low Temperature Basalt Alterations by Seawater: An Experimental Study at 70° and 150° C, Geochimica et Cosmochimica Acta, 43, 19371947, 1979.Google Scholar
6 Franz, J. D. and Propp, R. K., Mineral Solution Equilibria I. An Experimental Study of Complexing and Thermodynamic Properties of Aqueous MgCl2 in the System MgO-SiO2-H2O-HCl, Geochimica et Cosmochimica Acta, 43, 12231239, 1979.Google Scholar
7 Bradley, D. J., Harvey, C. O., and Turcotte, R. P., Leaching of Actinides, and Technetium from Simulated High-Level Waste Glass, PNL–3152, August 1979.Google Scholar
8 Molecke, M. A. Schaefer, D. W., Glass, R. S. and Ruppen, J. A., Sandia HLW Canister/Overpack Studies Applicable for a Salt Repository. SAND81–1585, October 1981 (to be published in Advances in Science and Technology of the Management of High-Level Nuclear Waste, Vol. I, Battelle Press).Google Scholar