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Peo-Based Polymer Electrolytes Containing Divalent Cations

Published online by Cambridge University Press:  21 February 2011

Gregory C. Farrington ,
Hong Yang  and
Rokeya Hug
Gregory C. Farrington
Affiliation:
Department of Materials Science and Engineering University of Pennsylvania 3231 Walnut Street Philadelphia, PA 19104, USA
Hong Yang
Affiliation:
Department of Materials Science and Engineering University of Pennsylvania 3231 Walnut Street Philadelphia, PA 19104, USA
Rokeya Hug
Affiliation:
Department of Materials Science and Engineering University of Pennsylvania 3231 Walnut Street Philadelphia, PA 19104, USA
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Abstract

Poly(ethylene oxide) is a non-aqueous solvent which can dissolve high concentrations of a wide variety of monovalent and divalent cation salts. The resulting solutions are generally heterogeneous mixtures of crystalline and amorphous regions. The amorphous components have relatively high ionic conductivities, and PEO ‘quasi-solid’ electrolytes and related polymer materials are arguably a new class of electrolyte, with properties in between those of true solids and true liquids. This paper briefly discusses the preparation and properties of PEO electrolytes containing Mg(II), Zn(II), and Pb(II) salts.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 135: Symposium M – Solid State Ionics I , 1988 , 319
Copyright
Copyright © Materials Research Society 1989

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References

1. Armand, M.B., Solid State Ionics. 9&10 (1983), 745 CrossRefGoogle Scholar
2. Yang, L.L, McGhie, A.R. and Farrington, G.C., J. Electrochem.Soc., M3 (1986) 1380.CrossRefGoogle Scholar
3. Huq, R., Chiodelli, G., Ferloni, P., Magistris, A., and Farrington, G.C., J. Electrochem. Soc., 134 (1987) 364 CrossRefGoogle Scholar
4. Yang, L.L., Huq, R., and Farrington, G.C., Solid State Ionics, 18/19 (1986)CrossRefGoogle Scholar
5. Huq, R. and Farrington, G.C., J. Electrochem. Soc., 135 (1988) 524.CrossRefGoogle Scholar
6. Huq, R. and Farrington, G.C., The Electrochemical Society, 170th Meeting, San Diego, October 1986, Abstract No. 765Google Scholar
7. Patrick, A., Glasse, M., Latham, R., and Unford, R., Solid State Ionics, 18/19 (1986) 1063 CrossRefGoogle Scholar
8. Abrantes, T.M.A., Alcacer, L.T. and Sequeira, C.A.C., Solid State Ionics, 18/19 (1986) 315 CrossRefGoogle Scholar
9. Patrick, A., Glasse, M., Latham, R., and Linford, R., Solid State Ionics, 18&12 (1986) 1063 CrossRefGoogle Scholar
10. Andrews, K.C., Cole, M., Latham, R.J., R.G. Linford, Williams, M.M., and Dobson, B.R., 6th International Conference on Solid State Ionics, GarmischPartenkirchen, Germany, 1987, Paper A2-3Google Scholar
11. Yang, H. and Farrington, G.C., unpublished results, University of PennsylvaniaGoogle Scholar
12. Huq, R. and Farrington, G.C., 6th International Conference on Solid State Ionics, Garmisch-Partenkirchen, Germany, 1987, Paper P1-33Google Scholar
13. Bruce, P.G., Krok, F., and Vincent, C.A., Solid State Ionics, 27 (1988) 81 CrossRefGoogle Scholar
14. Huq, R. and Farrington, G.C., unpublished results, University of PennsylvaniaGoogle Scholar
15. Pantaloni, S., Passerini, S., and Scrosati, B., J. Electrochem. Soc., 135 (1988) 1961 Google Scholar
16. Yang, H., Farrington, G.C., and McGhie, A.R., Proceedings of the 15th NATAS Conference, Cincinnati, OH (1986) p. 447 Google Scholar