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Organic-Inorganic Crystals for Optical Devices

Published online by Cambridge University Press:  10 February 2011


A. Ibanez
Affiliation:
Laboratoire de Cristallographie, CNRS, associé à 1'Université Joseph Fourier, BP 166, 38042 Grenoble Cedex 09, France
J. Zaccaro
Affiliation:
Laboratoire de Cristallographie, CNRS, associé à 1'Université Joseph Fourier, BP 166, 38042 Grenoble Cedex 09, France
P. L. Baldeck
Affiliation:
Laboratoire de Spectrométrie Physique, Université Joseph Fourier, BP 87, 38402 Saint Martin d'Hères Cedex, France
R. Masse
Affiliation:
Laboratoire de Cristallographie, CNRS, associé à 1'Université Joseph Fourier, BP 166, 38042 Grenoble Cedex 09, France

Abstract

Two routes of crystal engineering and elaboration of optical materials are described. The former applied to the design of organic-inorganic crystals for quadratic nonlinear optics is supported by a strategy of deliberately engineered noncentrosymmetric structures built-up from herringbone motifs of 2-amino-5-nitropyridinium chromophore. The original crystal growth of a solid solution of a member of this family is presented and discussed. The latter is a simple and generic elaboration of stable organic nanocrystals embedded in sol-gel matrices. Several molecules and characterization techniques have been involved to demonstrate the validity of this preparation.


Type
Research Article
Copyright
Copyright © Materials Research Society 1998

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References

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