Hostname: page-component-77c89778f8-vsgnj Total loading time: 0 Render date: 2024-07-18T08:21:31.200Z Has data issue: false hasContentIssue false
  • English
  • Français

Organic / Inorganic Hybrid Material for Coating on Metals

Published online by Cambridge University Press:  11 February 2011

Zhexiong Tang ,
Neil Alvarez  and
Sze Yang
Zhexiong Tang
Affiliation:
Department of Chemistry, University of Rhode Island, Kingston, RI 02879
Neil Alvarez
Affiliation:
Department of Chemistry, University of Rhode Island, Kingston, RI 02879
Sze Yang
Affiliation:
Department of Chemistry, University of Rhode Island, Kingston, RI 02879
Get access

Abstract

In this paper, we present the syntheses of nano particles of organic / inorganic hybrid for coating on metal or glass surfaces. The organic component is a π-conjugated polymer, polyaniline. The inorganic component is a metal oxide, e.g., cerium oxide. Since the organic component is a water-dispersible polymeric complex of polyaniline and poly(acrylic acid), the hybrid particles are also dispersed in water. The synthesis of the organic / inorganic composite is described. The water dispersible hybrid material was coated on aluminum and glass substrates using a molecular layer-by-layer coating process.

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 734: Symposia A/B – Defect-Mediated Phenomena in Ordered Polymers – Polymer/Metal Interfaces and Defect Mediated Phenomena in Ordered Polymers , 2002 , B9.57
Copyright
Copyright © Materials Research Society 2003

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1. Simon, P.F.W., Ulrich, R., Spiess, H.W., Wiesner, U., Chem. Mater, 13, 3464 (2001).CrossRefGoogle Scholar
2. O'Regan, B., Gratzel, M., Nature, 353, 737 (1991).Google Scholar
3. Zarur, A. J., Ying, J. Y., Nature 403, 65 (2000).CrossRefGoogle Scholar
4. Liu, J.-M. and Yang, S. C., Chem, J.. Soc., Chem. Comm., 1529 (1991).CrossRefGoogle Scholar
5. Nano cerium oxide 15 nm diameter. Purchased from Nanophase Technology, Romeoville, IL.Google Scholar
6. Stoffer, J. O., O'Keefe, T. J., Lin, X., Morris, E., Yu, P., Sitaram, S. P., US Patent 5,932,083.Google Scholar
7. Sitaram, S.P., Yu, P., O'Keefe, T. and Stoffer, J.O., Polym. Mater. Sci. Eng., 75, 354 (1996).Google Scholar
8. Racicot, R., Brown, R., Yang, S. C., Syn. Met. 85, 1263 (1997).Google Scholar
9. Racicot, R. J., Yang, S. C., Brown, R., Proceedings of Corrosion / 2000, Research Topical Symposium, Surface Conversions of Aluminum and Ferrous Alloys for Corrosion Resistance, pp 113–128 (2000)Google Scholar
10. Sun, L., Liu, H., Clark, R., Yang, S. C., Syn. Met. 85, 67 (1997).CrossRefGoogle Scholar
11. Liu, J.-M., Sun, L., Hwang, J.-H. and Yang, S. C., Mat Res Soc. Symposium Proceedings 247, 601 (1992)Google Scholar
12. McCarthy, P. A., Huang, J., Yang, S.C., Wang, H-L., Langmuir 18, 259 (2002).Google Scholar
13. Cheung, J. H., Stockton, W. B., Rubner, M.F., Macromolecules 1997, 30, 2712.Google Scholar