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A New Polymer Cathode-Conducting Polymer Interconnected With Sulfur-Sulfur Bonds: Poly(2,2'-Dithiodianiline)

Published online by Cambridge University Press:  10 February 2011

Katsuhiko Naoi ,
Ken-ichi Kawase ,
Mitsubiro Mori  and
Michiko Komiyama
Katsuhiko Naoi
Affiliation:
Cooperative Research Center, Tokyo University of Agriculture & TechnologyKoganei, Tokyo 184, Japan
Ken-ichi Kawase
Affiliation:
Cooperative Research Center, Tokyo University of Agriculture & TechnologyKoganei, Tokyo 184, Japan
Mitsubiro Mori
Affiliation:
Cooperative Research Center, Tokyo University of Agriculture & TechnologyKoganei, Tokyo 184, Japan
Michiko Komiyama
Affiliation:
Cooperative Research Center, Tokyo University of Agriculture & TechnologyKoganei, Tokyo 184, Japan
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Abstract

Poly(2, 2'-Dithiodianiline)(Poly(DTDA)), a conducting polymer having disulfide bond in it, has been proposed as a new class of high energy storage material. DTDA has one S-S bond interconnected between two moieties of anilines. The structure of the poly(DTDA) was similar to that of polyaniline in addition that the S-S bond is preserved after electropolymerization of DTDA. The poly(DTDA) has some advantages because of its high theoretical energy density, faster kinetics and higher electrical conductivity than other organosulfur cathodes

Type
Research Article
Information
MRS Online Proceedings Library (OPL) , Volume 496: Symposium Y – Materials For Electrochemical Energy Storage & Conversion II… , 1997 , 309
Copyright
Copyright © Materials Research Society 1998

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References

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