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Mass Flow and Stability of Nanoscale Features on AU(111)

Published online by Cambridge University Press:  25 February 2011

B. H. Cooper
Affiliation:
Laboratory of Atomic and Solid State Physics, Cornell University, Ithaca, NY 14853
D. R. Peale
Affiliation:
Laboratory of Atomic and Solid State Physics, Cornell University, Ithaca, NY 14853 current address: IBM T.J. Watson Research Center, Yorktown Heights, NY 10598
J. G. Mclean
Affiliation:
Laboratory of Atomic and Solid State Physics, Cornell University, Ithaca, NY 14853
R. Phillips
Affiliation:
Laboratory of Atomic and Solid State Physics, Cornell University, Ithaca, NY 14853
E. Chason
Affiliation:
Sandia National Laboratories, Albuquerque, NM 87185
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Abstract

We present the use of an STM to make quantitative observations of time-dependent mass flow associated with the decay of two-dimensional clusters on the Au(111) surface. When formed and observed in air, layered islands with well-defined edges located on larger terraces are generally found to decay in such a way that their areas decrease linearly in time over periods ranging from minutes to several hours depending on the island size. This is in contrast to the behavior of similar features formed and observed under ultra high vacuum conditions, which do not appear to decay over experimental periods of several days. The linear decay is consistent with models that have been used previously to describe growth of 2-dimensional clusters on surfaces. We discuss possible decay mechanisms, and the role that adsorbates may play in influencing the decay.

Type
Research Article
Copyright
Copyright © Materials Research Society 1993

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References

REFERENCES

[1] Peale, D.R. and Cooper, B.H., J. Vac. Sci. Technol., A10, 2210 (1992).Google Scholar
[2] Peale, D.R., McLean, J.G., and Cooper, B.H., in preparation.Google Scholar
[3] Michely, T. and Comsa, G., Surf. Sci. 256, 217 (1991).Google Scholar
[4] Michely, T., Besocke, K.H., and Comsa, G., Surf. Sci. Lett. 230, L135 (1990).Google Scholar
[5] Chambliss, D.D., private communication.Google Scholar
[6] Peale, D.R. and Cooper, B.H., J. Vac. Sci. Technol. A8, 345 (1990).Google Scholar
[7] Mamin, H.J., Guthner, P.H., and Rugar, D., Phys. Rev. Lett. 65, 2418 (1990).Google Scholar
[8] Li, Y.Z., Vazquez, L., Piner, R., Andres, R.P., and Reifenberger, R., Appl. Phys. Lett. 54, 1424 (1989).Google Scholar
[9] Lifshitz, L.M. and Slyozov, V.V., Phys, J.. Chem. Sol. 19, 35 (1961).Google Scholar
[10] Wagner, C., Z. Electrochem. 65, 581 (1961).Google Scholar
[11] Chakraverty, B.K., J. Phys. Chem. Sol. 28, 2401 (1967).Google Scholar
[12] Wynblatt, P. and Gjostein, N.A., in Progress in Solid State Chemistry, ed. McCaldin, J.O. and Somorjai, G. (Pergamon, Oxford, 1975), vol. 9, p. 21.Google Scholar
[13] Note that a parallel theory can be developed if in place of adatoms we consider single atom vacancies in the surface. In this case the “clusters” are monolayer deep pits. Due to the different diffusion barriers for adatoms and vacancies, the two cases may not be in the same limit of the theory. Data we have obtained suggests that nonetheless pits follow the same linear decay behavior. Whether the linear decay is caused by the outward diffusion of vacancies to straight step edges or the interface transfer of adatoms over the pit edges has not yet been determined.Google Scholar
[14] Trevor, D.J. and Chidsey, C.E.D., J. Vac. Sci. Technol. B 9, 964 (1991).Google Scholar
[15] Chason, E. and Dodson, B., J. Vac. Sci. Technol. A9, 1545 (1991).Google Scholar
[16] Dubson, , et al., to be published.Google Scholar