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Long-Term Corrosion of Zircaloy Hull Waste under Geological Disposal Conditions: Corrosion Correlations, Factors Influencing Corrosion, Corrosion Test Data, and Preliminary Evaluation

Published online by Cambridge University Press:  30 June 2014

Hiromi Tanabe ,
Tomofumi Sakuragi ,
Hideaki Miyakawa  and
Ryota Takahashi
Hiromi Tanabe*
Affiliation:
Radioactive Waste Management Funding and Research Center (RWMC), Pacific Marks Tsukishima, 1-15-7Tsukishima, Chuo-ku, Tokyo, 104-0052, Japan
Tomofumi Sakuragi
Affiliation:
Radioactive Waste Management Funding and Research Center (RWMC), Pacific Marks Tsukishima, 1-15-7Tsukishima, Chuo-ku, Tokyo, 104-0052, Japan
Hideaki Miyakawa
Affiliation:
Radioactive Waste Management Funding and Research Center (RWMC), Pacific Marks Tsukishima, 1-15-7Tsukishima, Chuo-ku, Tokyo, 104-0052, Japan
Ryota Takahashi
Affiliation:
Radioactive Waste Management Funding and Research Center (RWMC), Pacific Marks Tsukishima, 1-15-7Tsukishima, Chuo-ku, Tokyo, 104-0052, Japan
*
*Tel.: 81-3-3534-4533; E-mail: tanabe.hiromi@rwmc.or.jp
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Abstract

The carbon-14 generated in Zircaloy (Zry) hull waste is considered an important radionuclide in the TRU waste geological disposal concept in Japan. Given that the metal Zry is highly corrosion-resistant in the anaerobic and low-temperature conditions of the repository, and that the C-14 release rate is assumed to be controlled by the corrosion rate, a variety of corrosion and leaching tests have been performed. However, since the Zry corrosion rate is extremely slow, it is not possible to predict long-term corrosion behavior through low-temperature corrosion tests conducted in a reasonable time period. A vast amount of testing has been conducted in the higher-temperature range of 523 to 633 K, and corrosion correlations have been obtained from these tests. Corrosion correlations have been used to predict the corrosion rate of Zry in a tuff repository. Long-term Zry autoclave corrosion data have been analyzed to develop new corrosion correlations. Extrapolating these correlations to a lower temperature range requires verification that the mechanisms do not change over the range of testing and extrapolation. Factors that influence corrosion rates under geological disposal conditions, such as material and environmental factors, should also be examined. Corrosion correlations, factors influencing corrosion rates, the results of corrosion and leaching tests, and a preliminary evaluation are discussed.

Keywords

corrosionZrgeologic
Type
Articles
Information
MRS Online Proceedings Library (OPL) , Volume 1665: Symposium NW – Scientific Basis for Nuclear Waste Management XXXVII , 2014 , pp. 203 - 214
Copyright
Copyright © Materials Research Society 2014 

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References

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