Skip to main content Accessibility help
×
Home
Hostname: page-component-7ccbd9845f-dxj8b Total loading time: 0.3 Render date: 2023-01-28T12:34:59.794Z Has data issue: true Feature Flags: { "useRatesEcommerce": false } hasContentIssue true

Hypervalent Siliconate Materials. Synthesis and Characterization of Novel Ladder and Network Ionomers

Published online by Cambridge University Press:  25 February 2011

Kenneth J. Shea
Affiliation:
Department of Chemistry, University of California, Irvine, California 92717
Douglas A. Loy
Affiliation:
Sandia National Laboratories, Albuquerque, New Mexico 87185
James H. Small
Affiliation:
Department of Chemistry, University of California, Irvine, California 92717
Get access

Abstract

The first representatives of novel materials that contain five- and six-coordinate anionie silicon are reported. Linear (or cyclic) ionomers incorporating pentacovalent siliconate were synthesized by condensation of 1,2,4,5-tetrahydroxybenzene (THB) with alkyl and aryl trialkoxysilylanes. Network ionomers that incorporate pentacovalent siliconates were formed from THB and alkyl and aryl bistrialkoxysilanes. In addition, network ionomers with hexacoordinate silicon result from condensation of TEOS and THB. Spectroscopie evidence is presented to verify the identity of the novel structural features of these materials.

Type
Research Article
Copyright
Copyright © Materials Research Society 1992

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

1. Holmes, R. R. Chem. Rev. 1990, 90, 17.CrossRefGoogle Scholar
2. Corriu, R. J. P.; Guerin, C. Adv. Organomet. Chem. 1982, 20, 265.CrossRefGoogle Scholar
3. (a) Corriu, R. J. P.; Guerin, C.; Moreau, J. J. E. The Chemistry of Organic Silicon Compounds; Patai, S.; Rappoport, Z., Eds., Wiley, New York, 1989, Part 1, pp. 305370.CrossRefGoogle Scholar
(b) Corriu, R. J. P.; Young, , The Chemistry of Organic Silicon Compounds; Patai, S.; Rappoport, Z., Eds., Wiley, New York, 1989, Part 2, pp. 12411288.CrossRefGoogle Scholar
4. Fleming, I. in Comprehensive Organic Chemistry, Barton, D. H. R.; Ollis, D. W., Eds., Pergamon Press, Oxford, 1979, Vol. 3, p. 555.Google Scholar
5. (a) Corriu, R. J. P.; Guerin, C.; Moreau, J. J. E. Topics in Stereochemistry 1984, 15, 43.Google Scholar
(b) Johnson, S. E.; Day, R. O.; Holmes, R. R., Inorg. Chem. 1989, 28, 3182.CrossRefGoogle Scholar
(c) Johnson, S. E.; Payne, J. S.; Day, R. O.; Holmes, J. M.; Holmes, R. R. Inorg. Chem, 1989, 28, 3190.CrossRefGoogle Scholar
(d) Damraver, R.; O'Connell, B.; Denahey, S. E.; Simon, R. Organometallics 1989, 8, 1167.CrossRefGoogle Scholar
6. Shklover, V. E.; Struchkov, Yu. T.; Voronkov, M. G. Russian Chemical Reviews 1989, 58, 211.CrossRefGoogle Scholar
7. Johnson, S. E.; Deiters, J. A.; Day, R. O.; Holmes, R. R. J. Am. Chem. Soc. 1989, 211, 320.Google Scholar
8. Sakurai, H. Selectivities in Lewis Acid Promoted Reactions; Schinzer, D., Ed., Kluwer, 1989, p. 203.CrossRefGoogle Scholar
9. Tandura, S. N.; Voronkov, M. G.; Alekseev, N. V. Top Stereochem, 1986, 131, 99.Google Scholar
10. (a) Thomas, J. M.; Gonzales-Calbert, J. M.; Fyfe, C. A.; Gobbi, G. C.; Nicol, M. Geophysical Research Letters 1983, 10, 91.CrossRefGoogle Scholar
(b) Edge, R. A.; Taylor, H. F. W. Nature 1969, 224, 363.CrossRefGoogle Scholar
11. Edge, R. A.; Talor, H. F. W. Nature 1969, 224, 363.CrossRefGoogle Scholar
12. Shea, K. J.; Loy, D.; Webster, O. Chemistry of Materials 1989, 1, 572.CrossRefGoogle Scholar
13. Shea, K. J.; Webster, O. W.; Loy, D. A. Better Ceramics Through Chemistry IV, MRS Symposium Proceedings, 1990, 180, 975.Google Scholar
14. Shea, K. J.; Loy, D. A.; Webster, O. J. Am. Chem. Soc. 1992, 114, 0000.Google Scholar
15. Rosenheim, A.; Baibmann, B.; Schendel, G. Z. Anorg. All. Chem. 1931, 196, 160.CrossRefGoogle Scholar
16. Frye, C. L. J. Am. Chem. Soc. 1964, 86, 3170.CrossRefGoogle Scholar
17. Cella, J. A.; Cargiol, J. D.; Williams, E. A. J. Organomet, Chem. 1980, 186, 13.CrossRefGoogle Scholar

Save article to Kindle

To save this article to your Kindle, first ensure coreplatform@cambridge.org is added to your Approved Personal Document E-mail List under your Personal Document Settings on the Manage Your Content and Devices page of your Amazon account. Then enter the ‘name’ part of your Kindle email address below. Find out more about saving to your Kindle.

Note you can select to save to either the @free.kindle.com or @kindle.com variations. ‘@free.kindle.com’ emails are free but can only be saved to your device when it is connected to wi-fi. ‘@kindle.com’ emails can be delivered even when you are not connected to wi-fi, but note that service fees apply.

Find out more about the Kindle Personal Document Service.

Hypervalent Siliconate Materials. Synthesis and Characterization of Novel Ladder and Network Ionomers
Available formats
×

Save article to Dropbox

To save this article to your Dropbox account, please select one or more formats and confirm that you agree to abide by our usage policies. If this is the first time you used this feature, you will be asked to authorise Cambridge Core to connect with your Dropbox account. Find out more about saving content to Dropbox.

Hypervalent Siliconate Materials. Synthesis and Characterization of Novel Ladder and Network Ionomers
Available formats
×

Save article to Google Drive

To save this article to your Google Drive account, please select one or more formats and confirm that you agree to abide by our usage policies. If this is the first time you used this feature, you will be asked to authorise Cambridge Core to connect with your Google Drive account. Find out more about saving content to Google Drive.

Hypervalent Siliconate Materials. Synthesis and Characterization of Novel Ladder and Network Ionomers
Available formats
×
×

Reply to: Submit a response

Please enter your response.

Your details

Please enter a valid email address.

Conflicting interests

Do you have any conflicting interests? *