Hostname: page-component-848d4c4894-ttngx Total loading time: 0 Render date: 2024-04-30T19:24:50.048Z Has data issue: false hasContentIssue false

Filtered Cathodic Arc Deposited Diamond-Like Carbon: Electron Spin Resonance (ESR) and Raman Spectroscopy

Published online by Cambridge University Press:  10 February 2011

B. Druz
Affiliation:
Veeco Instruments, Inc., Terminal Drive, Plainview, NY 11803
I. Zaritskiy
Affiliation:
Veeco Instruments, Inc., Terminal Drive, Plainview, NY 11803
Y. Yevtukhov
Affiliation:
Veeco Instruments, Inc., Terminal Drive, Plainview, NY 11803
A. Konchits
Affiliation:
Institute of Semiconductor Physics, 45 Prospect Nauki, Kiev 252650, Ukraine
M. Valakh
Affiliation:
Institute of Semiconductor Physics, 45 Prospect Nauki, Kiev 252650, Ukraine
S. Kolesnik
Affiliation:
Institute of Semiconductor Physics, 45 Prospect Nauki, Kiev 252650, Ukraine
B. Shanina
Affiliation:
Institute of Semiconductor Physics, 45 Prospect Nauki, Kiev 252650, Ukraine
V. Visotski
Affiliation:
Institute of Semiconductor Physics, 45 Prospect Nauki, Kiev 252650, Ukraine
Get access

Abstract

Tetrahedral diamond like carbon (ta-C) films were deposited onto Si substrates using Filtered Cathodic Vacuum Arc (FCVA) process. Stress of deposited films was varied in the range 3.5÷8.5 GPa. The ESR (stationary and pulse) and Raman techniques were used to analyze sp2 related defects in the pseudo-gap of undoped, as deposited 20 – 100 nm thick films. The results are compared with data for direct ion beam deposited from CH4 plasma hydrogenated DLHC films and nature of paramagnetic defects in DLC is discussed.

Type
Research Article
Copyright
Copyright © Materials Research Society 2000

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

Refernces

1. Druz, B., Yevtukhov, Y., Novotny, V., Zaritskiy, I., Konarov, V., Polyakov, V., Rukavishnikov, A., Diamond Relat. Mater., XXX-000, 2000.Google Scholar
2. Druz, B., DiStefano, S., Hayes, A., Ostan, E., Williams, K., Wang, L., Surface and Coatings Technology, 86–87, 708 (1996).Google Scholar
3. Fanciulli, M., Fusco, G., Tagliaferro, A., Diamond Relat. Mater., 6, 725 (1997).Google Scholar
4. Fusko, G., Tagliaferro, A., Milne, W.I., Robertson, J., Diamond Relat. Mater., 6, 783 (1997).Google Scholar
5. Giorgis, F., Tagliaferro, A., Fanciulli, M., in Amorphous Carbon: State of the Art, edited by Silva, S.R.P., Robertson, J., Milne, W.I., Amaratunga, G.A.J. (World Scientific Publishing Co., Singapore, 1998) p. 143.Google Scholar
6. Abragam, A., Bleaney, B., Electron Paramagnetic Resonance of Transition Ions, V. 1 (Clarendon Press, Oxford, 1970).Google Scholar
7. Konchits, A., Superhard Materials, No.3, 56 (1998).Google Scholar
8. Prawer, S., Nugent, K.W., in Amorphous Carbon: State of the Art, edited by Silva, S.R.P., Robertson, J., Milne, W.I., Amaratunga, G.A.J. (World Scientific Publishing Co., Singapore, 1998) p. 199.Google Scholar