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Electrophysical Properties Of Polymers With Implanted Amorphous Single - Component Metals

Published online by Cambridge University Press:  11 February 2011

R. Malkhasyan
Affiliation:
Scientific – Production Enterprise “ATOM”, Yerevan, Republic of ARMENIA.
R. Krmoyan
Affiliation:
Scientific – Production Enterprise “ATOM”, Yerevan, Republic of ARMENIA.
V. Kosyan
Affiliation:
Scientific – Production Enterprise “ATOM”, Yerevan, Republic of ARMENIA.
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Abstract

For the last years, especially after the creation of conducting polymers, much prominence has been given to the works on creation and working out the new technologies of implantation of different metals and, on the whole, inorganic components into the structure of different polymers.

Of special interest are rapidly developing researches in the field of creation and application of different nanomaterials also including metals in the processes of synthesis of different polymers.

The data on electrophysical properties of polyvinyl acetate with doping amorphous molybdenum, obtained for the first time in SPE “ATOM” of Armenia, are being presented and discussed for the first time in the given paper.

It is shown, that the dopes of amorphous nanosize molybdenum and crystalline nanosize molybdenum in the process of polymerization lead to its implantation into the structure of polymer. Amorphous molybdenum practically always lowers substantially electrical resistance of composite materials.

Type
Research Article
Copyright
Copyright © Materials Research Society 2003

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References

REFERENCES

1. Whitesides, G.M.. Organic materials science. MRS Bulletin, V. 27, N 1, p. 5665, 2002.Google Scholar
2. Cerveau, and Corriu, R.J.P., Coord. Chem. Rev. 178–180 (2) (1998) p. 1051.CrossRefGoogle Scholar
3. Swager, T.M., Wosnick, J.H.. Self-amplifying semiconducting polymers for chemical sensors. MRS Bulletin, V. 27, N 6, p.446450, 2002.CrossRefGoogle Scholar
4. Giannelis, , Adv. Mater. 8 (1) (1996) p. 29. Э/CrossRefGoogle Scholar
Pinnavaia, T.J. and Beal, G.W., eds., Polymerum/ Nanocomposites (John Wiley & Sons, New York, 2001).Google Scholar
5. Erichsen, J., Zekonyte, J., Dolgner, K. and others. The surface glass transition of polymeric glasses probed by the embedding of noble metal. Material Research Society Symposium Proceedings, V. 710, p. 625627, 2001.Google Scholar
6. Loy, D.A. and Shea, K.J., Chem. Rev. 95 (5) (1995) p. 1431;CrossRefGoogle Scholar
Shea, K.J. and Loy, D.A., Polym. Prepr. (Am. Chem. Soc, Div. Polym. Chem.) 41 (1). (2000) p. 505.Google Scholar
7. Shin, K., Wang, H., Satija, S.K., Han, Ch.C.. Gold nanoparticles in polymeric matrix: Evolution, diffusion, and interactions. Material Research Society Symposium Proceedings, V. 710, p. 682685, 2001.Google Scholar
8. Malkhasyan, R.T., Agababyan, E.B., Karachanyan, R.K. Production of new class of amorphous metals. Chem. Phys. Reports V15. N10, 1996., p.14091417 Google Scholar
9. Malkhasyan, R.T. A Method of Amorphous Materials Obtainment. PCT/AM 01/00010 04.09.2001.Google Scholar
10. Malkhasyan, R.T., New, Grigoryan S.L. mechanism and kinetics of nanoamorphous metals syntesis process. Ceramic Transactions Vol. 94, 1999., p.455 Google Scholar
11. Gharibyan, T. A., Malkhasyan, R.T., Minasyan, V., Vartikyan, L., Grigoryan, S.L Grigoryan, R.R. Influencing an amorphism and size of fragments of catalyzers on transformations of methanol. Kinetics and catalysis. 2002. (it is accepted for printing)Google Scholar
12. Malkhasyan, R.T., Gharibyan, T. A., Minasyan, V., Vartikyan, L. Grigoryan, S.L Grigoryan, R.R. Role nanosize, Mo in dehydrogenation of cyclohexane in benzol. Kinetics and catalysis. 2002. Ru. (it is accepted for printing).Google Scholar
13. Malkhassian, R.T. Production and technical characteristics of amorphous metals of new class. Proceedings of the 1995 Material Research Society Fall Meeting V 400 p. 7886.Google Scholar