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Crystallization Kinetics In A Ni24Zr76 Amorphous Alloy

Published online by Cambridge University Press:  15 February 2011

G. Ghosh
Affiliation:
Dept of Materials Science and Engineering, Northwestern University, Evanston, IL 60208–3108
F.-R. Chen
Affiliation:
Materials Science Center, National Tsing Hua University, Kuang Fu Road, Hsinchu, Taiwan
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Abstract

Isothermal crystallization kinetics of Ni24Zr76 amorphous alloy has been studied by differential scanning calorimetry (DSC). Theoretically estimated transient times are found to be consistent with the experimentally observed incubation periods. The crystallization kinetics has been analyzed in terms of Kolmogorov-Johnson-Mehl-Avrami (KJMA) Model and significant departure from the linear KJMA behavior was observed. Such non-linearity is due to the surface-induced crystallization, anisotropie growth of the crystals, impingement effects and variation of the nucleation rate during crystallization etc. By applying high-resolution electron Microscopy (HREM), it has been shown that the nucleation and growth of the crystals do not take place at a constant state of disorder.

Type
Research Article
Copyright
Copyright © Materials Research Society 1994

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References

REFERENCES

[1] Buschow, H. H. J. and Beekmans, N. M., Phys. Rev. B, 19, 3847 (1979).Google Scholar
[2] Dong, Y. D., Gregan, G. and Scott, M. G., J. Non-Crstalline Solids, 43, 403 (1981).Google Scholar
[3] Altounian, Z., Guo-Hua, Tu and StöM-Olsen, J. O., J. Appl. Phys., 54, 3111 (1983).Google Scholar
[4] Dey, G. K., Baburaj, E. G. and Banerjee, S., Mat. Sci. Engg., 21, 117 (1986).Google Scholar
[5] Kolb-Telieps, A., Int. J.Rapid Solidification, 3, 109 (1987).Google Scholar
[6] Ghosh, G., Chandrasekaran, M. and Delaey, L., Acta Metall. Mater., 39, 925 (1991).Google Scholar
[7] Kolgomorov, A. E., Akad. Nauk. SSSR. IZV.Ser. Mat, 1, 355 (1937).Google Scholar
[8] Johnson, W. A. and Mehl, R. F., Trans. AIME, 135, 416 (1939).Google Scholar
[9] Avrami, M., J.Chem Phys., 7, 103 (1939).Google Scholar
[10] Christian, J. W., The Theory of Transformation in metals and Alloys, Pergamon, Oxford, 2nd. Edn., 1975.Google Scholar
[11] Chen, H. S., Appl. Phys. Letters, 29, 12 (1976).Google Scholar
[12] Kelton, K. F., Greer, A. L. and Thompson, C.V., J.Chem.Phys., 79, 6261 (1983).Google Scholar
[13] Kashchiev, D., Surface Science, 14, 209 (1969).Google Scholar
[14] Ghosh, G., to appear in J. Mater. Res. (1994).Google Scholar
[15] Calka, A. and Radlinski, A. P., J. Mater. Res., 3, 59 (1987).Google Scholar
[16] Köster, U, in Proc. Phase Transformations, Cambridge, Lorimer, G. W., Ed., The Institute of Metals, London, pp.597 (1986).Google Scholar
[17] Price, C.W., Acta Metall., 35, 1377 (1987).Google Scholar