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Ultra-low Pt-decorated NiCu bimetallic alloys nanoparticles supported on reduced graphene oxide for electro-oxidation of methanol

Published online by Cambridge University Press:  26 July 2018

Ammar Bin Yousaf Open the ORCID record for Ammar Bin Yousaf [Opens in a new window] ,
Sajeda Adnan Mutlaq Alsaydeh ,
Fathima Sifani Zavahir ,
Peter Kasak  and
Syed Javaid Zaidi
Ammar Bin Yousaf*
Affiliation:
Center for Advanced Materials, Qatar University, Doha 2713, Qatar
Sajeda Adnan Mutlaq Alsaydeh
Affiliation:
Center for Advanced Materials, Qatar University, Doha 2713, Qatar
Fathima Sifani Zavahir
Affiliation:
Center for Advanced Materials, Qatar University, Doha 2713, Qatar
Peter Kasak
Affiliation:
Center for Advanced Materials, Qatar University, Doha 2713, Qatar
Syed Javaid Zaidi*
Affiliation:
Center for Advanced Materials, Qatar University, Doha 2713, Qatar
*
*Address all correspondence to Yousaf and Zaidi at ammar.chemist18@gmail.com, ammar@mail.ustc.edu.cn, muhammad.ammar@qu.edu.qa and szaidi@qu.edu.qa
*Address all correspondence to Yousaf and Zaidi at ammar.chemist18@gmail.com, ammar@mail.ustc.edu.cn, muhammad.ammar@qu.edu.qa and szaidi@qu.edu.qa
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Abstract

The selectivity of catalyst is an essential factor in direct methanol fuel cells (DMFCs) and plays an important role to improve their performance. To this end, platinum (Pt)-based low-cost trimetallic catalysts have been developed. The catalyst comprising ultra-low Pt-decorated NiCu bimetallic alloys nanoparticles fabricated on reduced graphene oxide (rGO). The series of Pt-NiCu/rGO nanocomposites were synthesized with different compositions to obtain the optimal conditioned material. The electrochemical results showed good performance for the electro-oxidation of methanol at anodic end of DMFCs. These outcomes opened up a broad avenue for developing lower cost-active catalysts with better performance for DMFCs.

Type
Research Letters
Information
MRS Communications , Volume 8 , Issue 3 , September 2018 , pp. 1050 - 1057
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Copyright
Copyright © Materials Research Society 2018 

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References

1.Winjobi, O., Zhang, Z., Liang, C., and Li, W.: Carbon nanotube supported platinum–palladium nanoparticles for formic acid oxidation. Electrochim. Acta 55, 4217 (2010).Google Scholar
2.Antolini, E. and Gonzalez, E.R.: Alkaline direct alcohol fuel cells. J. Power Sources 195, 3431 (2010).Google Scholar
3.Yousaf, A.B., Imran, M., Uwitonze, N., Zeb, A., Zaidi, S.J., Ansari, T.M., Yasmeen, G., and Manzoor, S.: Enhanced electrocatalytic performance of Pt3Pd1 alloys supported on CeO2/C for methanol oxidation and oxygen reduction reactions. J. Phys. Chem. C 121, 2069 (2017).Google Scholar
4.Debe, M.K.: Electrocatalyst approaches and challenges for automotive fuel cells. Nature 486, 43 (2012).Google Scholar
5.Zaidi, S.J., Bello, M., Al-Ahmed, A., Yousaf, A.B., and Imran, M.: Mesoporous carbon supported Pt/MO2 (M=Ce, Pr, Nd, Sm) heteronanostructure: promising non-Ru methanol oxidation reaction catalysts for direct methanol fuel cell application. J. Electroanal. Chem. 794, 86 (2017).Google Scholar
6.Wu, J. and Yang, H.: Platinum-based oxygen reduction electrocatalysts. Acc. Chem. Res. 46, 1848 (2013).Google Scholar
7.Huang, Y., Huang, H., Gao, Q., Gan, C., Liu, Y., and Fang, Y.: Electroless synthesis of two-dimensional sandwich-like Pt/Mn3O4/reduced-graphene-oxide nanocomposites with enhanced electrochemical performance for methanol oxidation. Electrochim. Acta 149, 34 (2014).Google Scholar
8.Liu, J., Liu, Z., Barrow, C.J., and Yang, W.: Molecularly engineered graphene surfaces for sensing applications: a review. Anal. Chim. Acta 859, 1 (2015).Google Scholar
9.Ojani, R., Raoof, J.-B., Fathi, S., and Alami-Valikchali, S.: Electrochemical behavior of Ni (II) incorporated in zeolite Y-modified carbon electrode: application for electrocatalytic oxidation of methanol in alkaline solution. J. Solid State Electrochem. 15, 1935 (2011).Google Scholar
10.Risbud, M., Baxter, S., and Skyllas-Kazacos, M.: Preparation of nickel modified carbon fibre electrodes and their application for methanol oxidation. Open Energy Fuels J. 5, 9 (2012).Google Scholar
11.Zhao, Y., Yang, X., Tian, J., Wang, F., and Zhan, L.: Methanol electro-oxidation on Ni@ Pd core-shell nanoparticles supported on multi-walled carbon nanotubes in alkaline media. Int. J. Hydrogen Energy 35, 3249 (2010).Google Scholar
12.Amin, R., Hameed, R.A., El-Khatib, K., and Youssef, M.E.: Electrocatalytic activity of nanostructured Ni and Pd–Ni on Vulcan XC-72R carbon black for methanol oxidation in alkaline medium. Int. J. Hydrogen Energy 39, 2026 (2014).Google Scholar
13.Danaee, I., Jafarian, M., Forouzandeh, F., Gobal, F., and Mahjani, M.: Electrocatalytic oxidation of methanol on Ni and NiCu alloy modified glassy carbon electrode. Int. J. Hydrogen Energy 33, 4367 (2008).Google Scholar
14.Tammam, R., Fekry, A., and Saleh, M.: Electrocatalytic oxidation of methanol on ordered binary catalyst of manganese and nickel oxide nanoparticles. Int. J. Hydrogen Energy 40, 275 (2015).Google Scholar
15.Katsounaros, I., Meier, J.C., and Mayrhofer, K.J.J.: The impact of chloride ions and the catalyst loading on the reduction of H2O2 on high surface area platinum catalysts. Electrochim. Acta 110, 790–795 (2013).Google Scholar
16.Lee, J.Y., Kwak, D.H., Lee, Y.W., Lee, S., and Park, K.W., Synthesis of cubic PtPd alloy nanoparticles as anode electrocatalysts for methanol and formic acid oxidation reactions. Phys. Chem. Chem. Phys. 17, 8642 (2015).Google Scholar
17.Keeley, G.P., Cherevko, S., and Mayrhofer, K.J.J., The stability challenge on the pathway to low and ultra-low platinum loading for oxygen reduction reaction in fuel cells. ChemElectroChem 3, 51 (2016).Google Scholar
18.Yousaf, A.B., Imran, M., Zeb, A., Wen, T., Xie, X., Jiang, Y.F., Yuan, C.Z., and Xu, A.W.: Single phase PtAg bimetallic alloy nanoparticles highly dispersed on reduced graphene oxide for electrocatalytic application of methanol oxidation reaction. Electrochim. Acta 197, 117 (2016).Google Scholar
19.Casella, I.G., Guascito, M.R., and Sannazzaro, M.G.: Voltammetric and XPS investigations of nickel hydroxide electrochemically dispersed on gold surface electrodes. J. Electroanal. Chem. 462, 202 (1999).Google Scholar
20.Li, D., Lv, P., Zhu, J., Lu, Y., Chen, C., Zhang, X., and Wei, Q., NiCu alloys nanoparticles-loaded carbon nanofibers for phenolic biosensor applications. Sensors 15, 29419 (2015).Google Scholar
21.Zhao, B., Shao, G., Fan, B., Zhao, W., and Zhang, R., Preparation and electromagnetic waves absorption properties of novel dendrite-like NiCu alloys composite. RSC Adv. 5, 42587 (2015).Google Scholar
22.Prabhuram, J., Zhao, T., Tang, Z., Chen, R., and Liang, Z.: Multiwalled carbon nanotube supported PtRu for the anode of direct methanol fuel cells. J. Phys. Chem. B 110, 5245 (2006).Google Scholar
23.Guo, G., Qin, F., Yang, D., Wang, C., Xu, H., and Yang, S.: Synthesis of platinum nanoparticles supported on poly (acrylic acid) grafted MWNTs and their hydrogenation of citral. Chem. Mater. 20, 2291 (2008).Google Scholar
24.Temiz, S., Mutlu, Z., Shahrezaei, S., Ozkan, M., and Ozkan, C.S.: Effect of intermittent oxygen exposure on chemical vapor deposition of graphene. MRS Commun. 7, 826 (2017).Google Scholar
25.Hsieh, H.H., Chang, Y.K., Pong, W.F., Pieh, J.Y., Tseng, P.K., Sham, T.K., Coulthard, I., Naftel, S.J., Lee, J.F., Chung, S.C., and Tsang, K.L.: The electronic structure of Ni-Cu alloys: d-electron charge distribution. Phys. Rev. B 57, 15204 (1998).Google Scholar
26.Guo, Q., Liu, D., Zhang, X., Li, L., Hou, H., Niwa, O., and You, T.: Pd–Ni alloy nanoparticle/carbon nanofiber composites: preparation, structure, and superior electrocatalytic properties for sugar analysis. Anal. Chem. 86, 5898 (2014).Google Scholar
27.Jafarian, M., Moghaddam, R., Mahjani, M., and Gobal, F.: Electro-catalytic oxidation of methanol on a Ni–Cu alloy in alkaline medium. J. Appl. Electrochem. 36, 913 (2006).Google Scholar
28.Lu, L.F., Chen, S., Thota, S., Wang, X.D., Wang, Y.C., Zou, S.H., Fan, J., and Zhao, J.: Composition controllable synthesis of PtCu nanodendrites with efficient electrocatalytic activity for methanol oxidation induced by high index surface and electronic interaction. J. Phys. Chem. C 121, 19796 (2017).Google Scholar
29.Sharma, S., Ganguly, A., Papakonstantinou, P., Miao, X., Li, M., Hutchison, J.L., Delichatsios, M., and Ukleja, S.: Rapid microwave synthesis of CO tolerant reduced graphene oxide-supported platinum electrocatalysts for oxidation of methanol. J. Phys. Chem. C 114, 19459 (2010).Google Scholar
30.Bavand, R., Wei, Q., Zhang, G., Sun, S., Yelon, A., and Sacher, E., PtRu alloy nanoparticles. 2. Chemical and electrochemical surface characterization for methanol oxidation. J. Phys. Chem. C 121, 23120 (2017).Google Scholar
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