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Understanding Actinides through the Role of 5f Electrons

Published online by Cambridge University Press:  31 January 2011

T. Gouder ,
F. Wastin ,
J. Rebizant  and
G.H. Lander
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Extract

Studies of the actinide elements and compounds were (and are) motivated by the need to characterize their structural and thermodynamic properties for the development of nuclear fuels and the treatment of waste, whether it be for long-term storage or ideas involving transmutation in high-powered accelerators. For the most part, tables giving these data exist, although the data for transuranium compounds are rather sparse. A much more difficult task is to understand the data and develop theories that have predictive power in this part of the periodic table. In doing this, however, we are confronted with the extremely complicated electronic structure of the 5f shell and the great paucity of high-quality data on materials containing transuranium isotopes.

Type
Research Article
Information
MRS Bulletin , Volume 26 , Issue 9: Challenges in Plutonium and Actinide Materials Science , September 2001 , pp. 684 - 688
Copyright
Copyright © Materials Research Society 2001

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References

1.Spirlet, J.C. and Vogt, O., in Handbook on the Physics and Chemistry of the Actinides, Vol. 1, edited by Freeman, A.J. and Lander, G.H. (Elsevier, Amsterdam, 1984) p.79.Google Scholar
2.Ichas, V., Griveau, J.C., Rebizant, J., and Spirlet, J.C., Phys. Rev. B 63 045109 (2001).Google Scholar
3.Wachter, P., Marabelli, F., and Bucher, B., Phys. Rev. B 43 (1991) p.11136.CrossRefGoogle Scholar
4.Oppeneer, P.M., Kraft, T., and Brooks, M.S.S., Phys. Rev. B 61 (2000) p.12825.CrossRefGoogle Scholar
5.Dabos-Seignon, S., Benedict, U., Heathman, S., and Spirlet, J.C., J. Less-Common Met. 160 (1990) p.35.CrossRefGoogle Scholar
6.Johansson, B. and Brooks, M.S.S., in Handbook on the Physics and Chemistry of the Rare Earths, Vol. 17, edited by Gschneidner, K.A., Eyring, L., Lander, G.H., and Choppin, G. (Elsevier, Amsterdam, 1993) p.149.Google Scholar
7.Benedict, U. and Holtzapfel, W.B., in Handbook on the Physics and Chemistry of the Rare Earths, Vol. 17, edited by Gschneidner, K.A., Eyring, L., Lander, G.H., and Choppin, G. (Elsevier, Amsterdam, 1993) p.245.Google Scholar
8.Heathman, S., Haire, R.G., Bihan, T. Le, Lindbaum, A., Litfin, K., Meresse, Y., and Libotte, H., Phys. Rev. Lett. 85 (2000) p.2961.CrossRefGoogle Scholar
9.Soderlind, P., Ahuja, R., Eriksson, O., Johans-son, B., and Wills, J.M., Phys. Rev. B 61 (2000) p.8119.CrossRefGoogle Scholar
10.Gouder, T., Wastin, F., Rebizant, J., and Havela, L., Phys. Rev. Lett. 84 (2000) p.3378.CrossRefGoogle Scholar
11.Gouder, T., Wastin, F., Rebizant, J., and Havela, L., Europhys. Lett. (2001) in press.Google Scholar
12.Eriksson, O., Cox, L.E., Cooper, B.R., Wills, J.M., Fernando, G.W., Hao, Y.G., and Boring, A.M., Phys. Rev. B 46 (1992) p.13576.CrossRefGoogle Scholar
13.Haschke, J.M., Allen, T.H., and Morales, L.A., Science 287 (2000) p.285.CrossRefGoogle Scholar
14.Brooks, M.S.S. and Kelly, P.J., Phys. Rev. Lett. 51 (1983) p.1708.CrossRefGoogle Scholar
15.Fournier, J.M. and Troc, R., in Handbook on the Physics and Chemistry of the Actinides, Vol. 2, edited by Freeman, A.J. and Lander, G.H. (Elsevier, Amsterdam, 1985) p.29.Google Scholar
16.Potzel, W., Kalvius, G.M., and Gal, J., in Handbook on the Physics and Chemistry of the Rare Earths, Vol. 17, edited by Gschneidner, K.A., Eyring, L., Lander, G.H., and Choppin, G. (Elsevier, Amsterdam, 1993) p.539.Google Scholar
17.Lander, G.H. and Burlet, P., Physica B 215 (1995) p.7.CrossRefGoogle Scholar
18.Yamagami, H., Phys. Rev. B 61 (2000) p.6246; K. Knöpfle and L.M. Sandratskii, Phys. Rev. B 63 014411 (2001).CrossRefGoogle Scholar
19.Normile, P. (unpublished manuscript).Google Scholar