Hostname: page-component-7479d7b7d-k7p5g Total loading time: 0 Render date: 2024-07-11T13:35:44.890Z Has data issue: false hasContentIssue false
  • English
  • Français

Surface and Interface Modification of Polymers

Published online by Cambridge University Press:  29 November 2013

Jeffrey T. Koberstein
Get access

Extract

The properties of polymeric surfaces and interfaces are ubiquitous in their myriad commercial applications: paints and coatings, adhesives, lubrication, biocompatible materials, flocculation and steric stabilization of colloids, membranes and separation media, immiscible polymer blends, and filled composites. Some of these applications require low-energy surfaces that are chemically inert and are not easily wet with other materials. Other applications require high adhesion and strong interactions between the polymer and substrate. This article discusses fundamental principles governing the behavior of polymer surfaces and interfaces, then illustrates various means available for polymer-interface modification.

Type
Polymer Surfaces and Interfaces
Information
MRS Bulletin , Volume 21 , Issue 1 , January 1996 , pp. 19 - 23
Copyright
Copyright © Materials Research Society 1996

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

1.Koberstein, J.T., in Encyclopedia of Polymer Science and Engineering, vol. 8, 2nd ed. (John Wiley & Sons, Inc., 1987) p. 237.Google Scholar
2.Macleod, D.B., Trans. Faraday Soc. 19 (1923) p. 38.CrossRefGoogle Scholar
3.Wu, S., Polymer Interface and Adhesion (Marcel Dekker, New York, 1982).Google Scholar
4.Wu, S., in Polymer Blends, vol. 1, edited by Paul, D.R. and Newman, S. (Academic Press, New York, 1978).Google Scholar
5.Anastasiadis, S.H., Chen, J.K., Koberstein, J.T., Siegel, A.F., Sohn, J.E., and Emerson, J.A., J. Colloid I. Sci. 199 (1987) p. 55.CrossRefGoogle Scholar
6.Anastasiadis, S.H., Gancarz, I., and Koberstein, J.T., Macromoleculcs 21 (1988) p. 2980.CrossRefGoogle Scholar
7.Sauer, B.B. and Dee, G.T., Macromoleculcs 24 (1991) p. 2124.CrossRefGoogle Scholar
8.Jalbert, C.J., Koberstein, J.T., Yilgor, I., Gallagher, P., and Krukonis, V., Macromolecules 26 (1993) p. 3069.CrossRefGoogle Scholar
9.Fleischer, C.A., Koberstein, J.T., Krukonis, V., and Wetmore, P., Macromolecules 26 (1993) p. 4172.CrossRefGoogle Scholar
10.Fox, H.W. and Zisman, W.A., J. Colloid Sci. 5 (1950) p. 514.CrossRefGoogle Scholar
11.Dupre, A., Theorie Mecanique de la Chaleur (Paris, 1869).Google Scholar
12. See, for example, Kinloch, A.J., Adhesion and Adhesives (Chapman and Hall, London, 1987).CrossRefGoogle Scholar
13.Pan, D.H. and Prest, W.M. Jr., J. Appl. Phys. 8 (1985) p. 15.Google Scholar
14.Bhatia, Q.S., Pan, D.H., and Koberstein, J.T., Macromolecules 21 (1988) p. 2166.CrossRefGoogle Scholar
15.Jones, R.A.L., Kramer, E.J., Rafailovich, M.H., Sokolov, J., and Schwarz, S.A., Phys. Rev. Lett. 62 (3) (1989) p. 280.CrossRefGoogle Scholar
16.Stamm, M., Reiter, G., and Kunz, K., Physica B 173 (1991) p. 35.CrossRefGoogle Scholar
17. For a review, see Binder, K., Adv. Polym. Sci. 112 (1994) p. 181.CrossRefGoogle Scholar
18.Kumar, S.K., Tang, H., and Szleifer, I., Mol. Phys. 81 (1994) p. 867.CrossRefGoogle Scholar
19. For a review, see Dwight, D.W., McGrath, J.E., Smith, S.D., and York, G.A., J. Electron Spectrosc. Relat. Phenom. 52 (1990) p. 457.CrossRefGoogle Scholar
20.Jalbert, C.J., Balaji, R., Bhatia, Q., Koberstein, J.T., Salvati, L. Jr., and Yilgor, I., Macromolecules 27 (1994) p. 2409.CrossRefGoogle Scholar
21.Elman, J., Johs, B., Long, T., and Koberstein, J.T., Macromolecules 27 (1994) p. 5341.CrossRefGoogle Scholar
22.Jalbert, C.J., PhD dissertation, University of Connecticut, 1993.Google Scholar
23.Jalbert, C.J., Koberstein, J.T., Hariharhan, A., and Kumar, S., “Lattice Calculations of Surface Tension in End-Functional Polymers” (unpublished manuscript).Google Scholar
24.Fredrickson, G., Macromolecules 20 (1987) p. 2535.CrossRefGoogle Scholar
25.Russell, T.P., Anastasiadis, S.H., Satija, S.K., and Majkrzak, C., Mat. Sci. Res. Soc. Symp. Proc. 166 (1990) p. 145.CrossRefGoogle Scholar
26.Gaines, G.L. Jr. and Bender, G.W., Macromolecules 5 (1972) p. 82.CrossRefGoogle Scholar
27.Kendrick, T.C., Kingston, B.M., Lloyd, N.C., and Owen, M.J., J. Colloid I. Sci. 24 (1967) p. 141.Google Scholar
28.Hunt, M.O. Jr., Belu, A.M., Linton, R.W., and DeSimone, J.M., Macromolecules 26 (1993) p. 4854.CrossRefGoogle Scholar
29.Affrossmann, S., Hartshorne, M., Kiff, T., Pethrick, R.A., and Richards, R.W., Macromolecules 27 (1994) p. 1588.CrossRefGoogle Scholar
30.Helfand, E. and Tagami, Y., J. Polym. Sci. B9 (1971) p. 741.Google Scholar
31.Paul, D.R., in Polymer Blends, vol. 2, edited by Paul, D.R. and Newman, S. (Academic Press, New York, 1978) p. 35.CrossRefGoogle Scholar
32.Sundararaj, U. and Mocosko, C.W., Macromolecules 28 (1995) p. 2647.CrossRefGoogle Scholar
33.Anastasiadis, S.H., Gancarz, I., and Koberstein, J.T., Macromolecules 22 (1989) p. 1449.CrossRefGoogle Scholar
34.Hu, W., Koberstein, J.T., Lingelser, J.P., and Gallot, Y., Macromolecules 28 (1995) p. 5209.CrossRefGoogle Scholar
35.Noolandi, J. and Hong, K.M., Macromolecules 15 (1982) p. 482.CrossRefGoogle Scholar
36.Leibler, L., Makromol. Chem., Makromol. Symp. 16 (1988) p. 1.CrossRefGoogle Scholar
37.Meier, D.J., in Thermoplastic Elastomers, edited by Legge, N.R., Holden, G., and Schroeder, H.E. (Hanser, NY, 1987).Google Scholar
38.Washiyama, J., Kramer, E.L., Cretan, C.F., and Hui, C. Y., Macromolecules 27 (1994) p. 2019.CrossRefGoogle Scholar
39.Cretan, C., Brown, H.R., and Schull, K., Macromolecules 27 (1994) p. 3174.CrossRefGoogle Scholar
40.Fleischer, C.A., Koberstein, J.T., Krukonis, V., and Wetmore, P., Macromolecules 26 (1993) p. 4172.CrossRefGoogle Scholar
41.Fleischer, C.A., Morales, A.R., and Koberstein, J.T., “The Effect of End Groups on Thermodynamics of Immiscible Polymer Blends: Two Cloud Point Curves” (unpublished manuscript).Google Scholar
42.Brown, S.B. and Orlando, C.M., in Encyclopedia of Polymer Science and Engineering, vol. 14 (1988).Google Scholar
43.Fleischer, C.A., Morales, A.R., and Koberstein, J.T., Macromolecules 27 (1994) p. 379.CrossRefGoogle Scholar
44.Clarke, C.J., Jones, R.A.L., Edwards, J.L., Schull, K.R., and Penfold, J., Macromolecules 28 (1995) p. 2042.CrossRefGoogle Scholar
45.Norton, L.J., Smigolova, V., Pralle, M.U., Hubenko, A., Dai, K.H., Kramer, E.J., Hahn, S., Berglund, C., and DeKoven, B., Macromolecules 28 (1995) p. 1999.CrossRefGoogle Scholar
46.Hu, W., Brown, H.R., Koberstein, J.T., Lingelser, J.P., and Gallot, Y., “Adhesion Enhancement of a Polystyrene/Poly(dimethyl siloxane) Interface by End-Functional Diblock Copolymers” (unpublished manuscript).Google Scholar
47.Hu, W., PhD dissertation, University of Connecticut, 1993.Google Scholar
48.Duch, D., MS thesis, University of Connecticut, 1995.Google Scholar
49.Duch, D., Lenk, T., Koberstein, J.T., Lingelser, J.P., and Gallot, Y., “Smart Polymer Surfaces: End-Functional Block Copolymers as Surface-Active, Selective Adhesion Promoters” (unpublished manuscript).Google Scholar
50.Koberstein, J.T., Lenk, T., Duch, D., Hu, W., and Brown, H., presented at the 1994 MRS Fall Meeting, Boston (unpublished).Google Scholar