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Macromolecular Templating for the Formation of Inorganic-Organic Hybrid Structures

Published online by Cambridge University Press:  31 January 2011

Takashi Kato ,
Takeshi Sakamoto  and
Tatsuya Nishimura
Takashi Kato
Affiliation:
Department of Chemistry and Biotechnology, School of Engineering, The University of Tokyo, Japan; e-mail kato@chiral.t.utokyo.ac.jp.
Takeshi Sakamoto
Affiliation:
t_saka@chemsys.t.utokyo.ac.jp.
Tatsuya Nishimura
Affiliation:
tatsuya@chembio.t.utokyo.ac.jp.
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Abstract

Biominerals such as the nacre of shells, spicules of sea urchins, teeth, and bones are inorganic-organic hybrids that have highly controlled hierarchical and complex structures. These structures are formed in mild conditions, and the processes are controlled by macromolecular templates of proteins, peptides, and polysaccharides. Materials scientists can obtain ideas from the structures, properties, and formation processes of biominerals for use in creating synthetic, biomimetic materials. This article highlights bioinspired synthetic approaches to the development of organic/CaCO3 hybrids using macromolecular templates. These hybrids have oriented, patterned, and 3D complex structures, as well as thin films with smooth surfaces. The structures are formed by templating synthetic and semisynthetic macromolecules. These materials have great potential for new functional materials.

Type
Research Article
Information
MRS Bulletin , Volume 35 , Issue 2: Lessons from Nature—Biomimetic Approaches to Minerals with Complex Structures , February 2010 , pp. 127 - 132
Copyright
Copyright © Materials Research Society 2010

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