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Layered oxides as positive electrode materials for Na-ion batteries

Published online by Cambridge University Press:  09 May 2014

Kei Kubota ,
Naoaki Yabuuchi ,
Hiroaki Yoshida ,
Mouad Dahbi  and
Shinichi Komaba
Kei Kubota
Affiliation:
Research Institute for Science and Technology, Tokyo University of Science, Japan; Unit of ESICB, Kyoto University, Japan; keikubota@rs.tus.ac.jp
Naoaki Yabuuchi
Affiliation:
Research Institute for Science and Technology, Tokyo University of Science, Japan; Unit of ESICB, Kyoto University, Japan; yabuuchi@rs.kagu.tus.ac.jp
Hiroaki Yoshida
Affiliation:
Department of Chemical Sciences and Technology, Tokyo University of Science, Japan; jb112899@ed.tus.ac.jp
Mouad Dahbi
Affiliation:
Department of Applied Chemistry, Tokyo University of Science, Japan; Unit of ESICB, Kyoto University, Japan; mouad.dahbi@rs.tus.ac.jp
Shinichi Komaba
Affiliation:
Department of Applied Chemistry, Tokyo University of Science, Japan; Unit of ESICB, Kyoto University, Japan; komaba@rs.kagu.tus.ac.jp
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Abstract

Considering the need for designing better batteries to meet the rapidly growing demand for large-scale energy storage applications, an aspect of primary importance for battery materials is elemental abundance. To achieve sustainable energy development, we must reconsider the feasibility of a sustainable lithium supply, which is essential for lithium(-ion) batteries. Lithium is widely distributed in the Earth, but is not regarded as an abundant element. Therefore, widespread use of large-scale lithium batteries would be inevitably restricted. Sodium(-ion) batteries are thus promising candidates for large-scale applications because sodium is the most advantageous next to lithium considering its atomic weight, standard potential, and natural abundance. Rechargeable sodium-ion batteries consist of two different sodium insertion materials similar to Li-ion batteries. Sodium insertion materials, especially layered oxides, have been studied since the early 1980s, but not extensively for energy storage devices due to the expanded interest in lithium insertion materials in the 1990s. In recent years, materials researchers have again been extensively exploring new sodium insertion materials to enhance battery performance. This article reviews recent advancements and trends in layered sodium transition metal oxides as positive electrode materials for Na-ion batteries.

Keywords

energy storageNaintercalationlayeredceramic
Type
Research Article
Information
MRS Bulletin , Volume 39 , Issue 5: Lithium Batteries and Beyond , May 2014 , pp. 416 - 422
Copyright
Copyright © Materials Research Society 2014 

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