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Sum Frequency Laser Spectroscopy during Chemical Reactions on Surfaces

Published online by Cambridge University Press:  31 January 2011

Günther Rupprechter
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Abstract

The surface specificity of vibrational sum frequency generation (VSFG) spectroscopy allows one to characterize adsorbed and reacting molecules on catalyst surfaces while the catalyst functions at high pressure and high temperature. VSFG spectroscopy can be carried out in different modes, including scanning, broadband, time-resolved, and polarization-dependent, and has been applied to various active surfaces. Single-crystal and nanoparticle model catalysts have mostly been used, which are typically prepared under ultrahigh vacuum, but applications to powder materials have been reported recently. In this article, the fundamentals and technical aspects of VSFG are summarized, and its benefits are illustrated by case studies of elementary processes of heterogeneous catalysis.

Type
Research Article
Information
MRS Bulletin , Volume 32 , Issue 12: Novel In Situ Probes for Nanocatalysis , December 2007 , pp. 1031 - 1037
Copyright
Copyright © Materials Research Society 2007

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