Skip to main content Accessibility help
×
Home

Preparation and Intercalation of Fluorescein in a Reconstructed Zinc/Aluminum Layer Double Hydroxide (LDH)

  • Jose F Ramirez-Rodriguez (a1), Ivan Bustamante-Hernandez (a1) and Tomas Viveros-Garcia (a1)

Abstract

A Zn/Al LDH with fluorescein intercalated as counterion with fluorescent properties was prepared. Fluorescein was prepared by the reaction between resorcinol and phthalic anhydride using the mixed oxide obtained after the thermal treatment of the LDH as catalyst. The material thus obtained, i.e. fluorescein adsorbed onto the mixed oxide from the calcined LDH, was treated with a mixture of water and pentanol in order to reconstitute the LDH and intercalate the fluorescein in the material. Three mixtures of water/pentanol with volume percent ratios of 100/0, 50/50, 20/80, were used to obtain the LDH with fluorescein intercalated. The best treatment could be determined according to the degree reconstruction and fluorescein intercalated into the LDH.

Copyright

Corresponding author

References

Hide All
1. Charles, W. Y. C., Jin, R. and Mirkin, C. A.: Nanoparticles with Raman spectroscopic fingerprints for DNA and RNA detection., Science, 297, 1536, (2002).
2. Walkup, G. K., Burdette, S. C., Lippard, S. J. and Tsien, R. Y.:, A New Cell-Permeable Fluorescent Probe for Zn. J. Am. Chem. Soc., 122, 5644, (2000).
3. Birks, J. B.: Photophysics of Aromatic Molecules, (Wiley-Interscience, London, 1970), pp 704.
4. Levitus, M., Schmieder, K., Ricks, H., Shimizu, K. D., Bunz, U. H. F. and Garcia-Garibay, M. A.: Steps to Demarcate the Effects of Chromophore Aggregation and Planarization in Poly(phenyleneethynylene)s. 1. Rotationally Interrupted Conjugation in the Excited States of 1,4-Bis(phenylethynyl)benzene J. Am. Chem. Soc., 123, 4259, (2001)
5. Shi, Wenying, Wei, Min, Evans, David G. and Duan, Xue: Tunable photoluminescence properties of fluorescein in a layered double hydroxide matrix and its application in sensors. J.Mater.Chem, 20, 3901, (2010)
6. Wypych, F. and Satyanarayana, K. G.: Clay Surfaces: Fundamentals and Applications, (Elsevier, London, UK, 2004), pp 546
7. Miyata, S., Anion-Exchange Properties of Hydrotalcite-Like Compounds Clays and Clay Miner., 31, 305, (1983).
8. Erickson, K.L., Bostrom, T.E., and Frost, R.L.: A study of structural memory effects in synthetic hydrotalcites using environmental SEM Materials Letters, 59(2-3), 226, (2005).
9. Wang, Liping, Wang, Fan and Xu, Linxiao: Layered double hydroxides based on different cations as catalysts for synthesis of poly(1, 5-pentadiol) carbonate diols Indian Journal of Chemistry, 54A, 607, (2015).
10. Bezen, Manuela C.I., Breitkopf, Cornelia, Lercher, Johannes A.: On the acid–base properties of Zn–Mg–Al mixed oxides. Appl. Cat. A 399, 93, (2011)
11. Hyeon Lee, Jong, Jung, Duk-Young, Kim, Eunchul, and Ahn, Tae Kyu: Fluorescein dye intercalated layered double hydroxides for chemically stabilized photoluminescent indicators on inorganic surfaces. DaltonTrans., 43, 8543, (2014)
12. Kooli, E, Depege, I C: Rehydration of Zn-Al layered double hydroxides Clays and Clay Miner. 45, 9298, (1997)
13. Adachi-Pagano, Mariko, Forano, Claude and Besse, Jean-Pierre: Delamination of layered double hydroxides by use of surfactants. Chem. Commun., 91, (2000)
14. Cavani, F., Trifiro, F., and Vaccari, A: Hydrotalcite-type anionic clays: Preparation, properties and applications. Catal. Today, 11, 173, (1991)
15. Lili Wang, A. Roitberg, C. Meuse, A.K. Gaigalas, : Raman and FTIR spectroscopies of fluorescein in solutions. Spectrochimica Acta Part A 57, 1781, (2001)
16. Lozano, Rafael, Rossi, Carlos and Matessanz, Emilio: Zaccagnaite-3R, a new Zn-Al hydrotalcite polytype from El Soplao cave (Cantabria, Spain) American Mineralogist, 97, 513, (2012)

Keywords

Related content

Powered by UNSILO

Preparation and Intercalation of Fluorescein in a Reconstructed Zinc/Aluminum Layer Double Hydroxide (LDH)

  • Jose F Ramirez-Rodriguez (a1), Ivan Bustamante-Hernandez (a1) and Tomas Viveros-Garcia (a1)

Metrics

Full text views

Total number of HTML views: 0
Total number of PDF views: 0 *
Loading metrics...

Abstract views

Total abstract views: 0 *
Loading metrics...

* Views captured on Cambridge Core between <date>. This data will be updated every 24 hours.

Usage data cannot currently be displayed.