Hostname: page-component-8448b6f56d-xtgtn Total loading time: 0 Render date: 2024-04-23T17:27:50.941Z Has data issue: false hasContentIssue false
  • English
  • Français

One-Step Fabrication of Fe-Si-O/Carbon Nanotube Composite Anode Material with Excellent High-Rate Long-Term Cycling Stability

Published online by Cambridge University Press:  26 January 2017

Yun-Kai Sun ,
Xue Bai ,
Tao Li ,
Gui-Xia Lu ,
Yong-Xin Qi ,
Ning Lun ,
Yun Tian  and
Yu-Jun Bai
Yun-Kai Sun*
Affiliation:
Key Laboratory for Liquid−Solid Structural Evolution and Processing of Materials (Ministry of Education), Shandong University, Jinan 250061, PR China
Xue Bai*
Affiliation:
Key Laboratory for Liquid−Solid Structural Evolution and Processing of Materials (Ministry of Education), Shandong University, Jinan 250061, PR China
Tao Li
Affiliation:
Key Laboratory for Liquid−Solid Structural Evolution and Processing of Materials (Ministry of Education), Shandong University, Jinan 250061, PR China
Gui-Xia Lu
Affiliation:
Key Laboratory for Liquid−Solid Structural Evolution and Processing of Materials (Ministry of Education), Shandong University, Jinan 250061, PR China
Yong-Xin Qi
Affiliation:
Key Laboratory for Liquid−Solid Structural Evolution and Processing of Materials (Ministry of Education), Shandong University, Jinan 250061, PR China
Ning Lun
Affiliation:
Key Laboratory for Liquid−Solid Structural Evolution and Processing of Materials (Ministry of Education), Shandong University, Jinan 250061, PR China
Yun Tian*
Affiliation:
Key Laboratory for Liquid−Solid Structural Evolution and Processing of Materials (Ministry of Education), Shandong University, Jinan 250061, PR China
Yu-Jun Bai*
Affiliation:
Key Laboratory for Liquid−Solid Structural Evolution and Processing of Materials (Ministry of Education), Shandong University, Jinan 250061, PR China
*
† Presenter E-mail: yksun_1994@126.com (Y.-K. Sun)
*E-mail: byj97@126.com (Y.-J. Bai), ytian@sdu.edu.cn (Y. Tian)
*E-mail: byj97@126.com (Y.-J. Bai), ytian@sdu.edu.cn (Y. Tian)
Get access

Abstract

The composite Li-ion battery anode material of Fe2SiO4, Fe3O4, Fe3C (Fe-Si-O) and carbon nanotubes was prepared by a simple one-step reaction between ferrocene and tetraethyl orthosilicate. When cycled at 100 mA g-1, this material exhibited ever-increasing capacities and reached 588 mAh g-1 at the 280th cycle. At 500 mA g-1, a reversible capacity of 350 mAh g-1 was retained for 600 cycles. Compared with Fe3O4 materials, the Fe-Si-O/CNT exhibited superior long-term high-rate performance, which could mainly result from its enhanced stability and conductivities by introducing silicates and CNTs during the one-step synthesis.

Keywords

energy storageoxideLi
Type
Articles
Information
MRS Advances , Volume 2 , Issue 21-22: Energy and Sustainability , 2017 , pp. 1157 - 1163
Copyright
Copyright © Materials Research Society 2017 

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

Armand, M. and Tarascon, J.-M., Nature, 451 (2008) 652–657.Google Scholar
Yang, L., Hu, J., Dong, A. and Yang, D., 2014.. Electrochimica Acta, 144, pp.235–242.Google Scholar
Gao, G., Zhang, Q., Cheng, X. B., Qiu, P., Sun, R., Yin, T. and Cui, D., ACS Appl. Mater. Interfaces, 7 (2014) 340–350.Google Scholar
He, Y., Huang, L., Cai, J. S., Zheng, X. M. and Sun, S.G., Electrochim. Acta, 55 (2010) 1140–1144.Google Scholar
Keller, T.M., Laskoski, M. and Qadri, S.B., J. Phys. Chem. C, 111 (2007) 2514–2519.Google Scholar
Kim, K.-E., Kim, K.-J., Jung, W.S., Bae, S.Y., Park, J., Choi, J. and Choo, J., Chem. Phys. Lett., 401 (2005) 459–464.Google Scholar
Zhang, Q., Ge, S., Xue, H., Wang, X., Sun, H. and Li, A., RSC Adv., 4 (2014) 58260–58264.CrossRefGoogle Scholar
Chen, W., Lan, M., Zhu, D., Ji, C., Feng, X., Yang, C., Zhang, J. and Mi, L., J. Mater. Chem. A, 1 (2013) 10912–10917.Google Scholar
Cheng, W., Rechberger, F., Ilari, G., Ma, H., Lin, W. I. and Niederberger, M., Chem. Sci, 6 (2015) 6908–6915.Google Scholar
Wang, Y.-Y., Li, T., Qi, Y.-X., Bai, R.-L., Yin, L.-W., Li, H., Lun, N. and Bai, Y.-J.. Electrochim. Acta, 186 (2015) 572–578.Google Scholar
Li, T., Wang, Y.-Y., Tang, R., Qi, Y.-X., Lun, N., Bai, Y.-J. and Fan, R.-H., ACS Appl. Mater. Interfaces, 5 (2013) 9470–9477.CrossRefGoogle Scholar
Latorre-Sanchez, M., Primo, A. and Garcia, H., J. Mater. Chem., 22 (2012) 21373–21375.CrossRefGoogle Scholar
Adams, S. and Rao, R.P., Phys. Chem. Chem. Phys., 11 (2009) 3210–3216.CrossRefGoogle Scholar
Raistrick, I., Ho, C. and Huggins, R.A., J. Electrochem. Soc, 123 (1976) 1469–1476.Google Scholar
Wang, W., Kumta, P.N., Acs Nano, 4 (2010) 2233–2241.Google Scholar
Zhao, X., Xia, D., Yue, J. and Liu, S., Electrochim. Acta, 116 (2014) 292–299.CrossRefGoogle Scholar
Sun, Y.-K., Bai, X., Li, T., Lu, G.-X., Qi, Y.-X., Lun., N., Tian, Y. and Bai, Y.-J., J. Alloys Compd., 686 (2016) 318–325 CrossRefGoogle Scholar