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Interactions between Simulant Vitrified Nuclear Wastes and high pH solutions: A Natural Analogue Approach

Published online by Cambridge University Press:  20 January 2017

Colleen Mann ,
Clare Thorpe ,
Antoni E. Milodowski ,
Lorraine P. Field ,
Richard P. Shaw ,
Luke Boast ,
Russell Hand ,
Neil C. Hyatt ,
John L. Provis  and
Claire L. Corkhill
Colleen Mann*
Affiliation:
NucleUS Immobilisation Science Laboratory, Department of Materials Science and Engineering, The University of Sheffield, Mappin Street, Sheffield S1 3JD, UK
Clare Thorpe
Affiliation:
NucleUS Immobilisation Science Laboratory, Department of Materials Science and Engineering, The University of Sheffield, Mappin Street, Sheffield S1 3JD, UK
Antoni E. Milodowski
Affiliation:
British Geological Survey, Environmental Science Centre, Nicker Hill, Keyworth, Nottingham, NG12 5GG, UK
Lorraine P. Field
Affiliation:
British Geological Survey, Environmental Science Centre, Nicker Hill, Keyworth, Nottingham, NG12 5GG, UK
Richard P. Shaw
Affiliation:
British Geological Survey, Environmental Science Centre, Nicker Hill, Keyworth, Nottingham, NG12 5GG, UK
Luke Boast
Affiliation:
NucleUS Immobilisation Science Laboratory, Department of Materials Science and Engineering, The University of Sheffield, Mappin Street, Sheffield S1 3JD, UK
Russell Hand
Affiliation:
NucleUS Immobilisation Science Laboratory, Department of Materials Science and Engineering, The University of Sheffield, Mappin Street, Sheffield S1 3JD, UK
Neil C. Hyatt
Affiliation:
NucleUS Immobilisation Science Laboratory, Department of Materials Science and Engineering, The University of Sheffield, Mappin Street, Sheffield S1 3JD, UK
John L. Provis
Affiliation:
NucleUS Immobilisation Science Laboratory, Department of Materials Science and Engineering, The University of Sheffield, Mappin Street, Sheffield S1 3JD, UK
Claire L. Corkhill
Affiliation:
NucleUS Immobilisation Science Laboratory, Department of Materials Science and Engineering, The University of Sheffield, Mappin Street, Sheffield S1 3JD, UK
*
*(Email: cmann1@sheffield.ac.uk)
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Abstract

This study details the characterization of a glass sample exposed to hyperalkaline water and calcium-rich sediment for an extended time period (estimated as 2 - 70 years) at a lime (CaO) waste site in the UK. We introduce this site, known as Peak Dale, in reference to its use as a natural analogue for nuclear waste glass dissolution in the high pH environment of a cementitious engineered barrier of a geological disposal facility. In particular, a preliminary assessment of alteration layer chemistry and morphology is described and the initiation of a long-term durability assessment is outlined.

Keywords

waste managementwatersurface chemistry
Type
Articles
Information
MRS Advances , Volume 2 , Issue 12: Scientific Basis for Nuclear Waste Management XL , 2017 , pp. 669 - 674
Copyright
Copyright © Materials Research Society 2017 

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References

REFERENCES

NDA DECC, 2013 UK Radioactive Waste Inventory (2014).Google Scholar
Department of Energy & Climate Change, Implementing Geological Disposal, (2014)Google Scholar
Hicks, T.W., Baldwin, T.D., Hooker, P.J., Richardson, P.J., Chapmanl, N.A., McKinleyl, I.G., and Neall, F.B., Galson Services Limited Report (2008).Google Scholar
Field, L. P., Milodowski, A. E., Shaw, R. P., Stevens, L. A., Kilpatrick, A., Gunn, J. and Kemp, S. J., Min Mag. 080, 111 (2016).Google Scholar
Werme, L.O., Forsyth, R.S., SKB technical report 89-14 (1989)Google Scholar
Coumes, C.D., Cement and Concrete Research. 36, 2152–2163 (2006).Google Scholar
Berner, U.R., Waste Management. 12, 201–219 (1992).Google Scholar
Rébiscoul, D., Tormos, V., Godon, N., Mestre, J.P., Cabie, M., Amiard, G., Foy, E., Frugier, P., Gin, S., Applied Geochemistry. 58, 26–37 (2015).Google Scholar
Dillmann, P., Gin, S., Neff, D., Gentaz, L., Rebiscoul, D., Geochimica et Cosmochimica Acta. 172, 287–305 (2016).Google Scholar