Hostname: page-component-848d4c4894-x24gv Total loading time: 0 Render date: 2024-04-30T18:22:19.508Z Has data issue: false hasContentIssue false
  • English
  • Français

Synthesis and Characterization of 2D-Graphene Oxide-Metal Hybrid Systems with Increased Solubility

Published online by Cambridge University Press:  10 June 2019

Hadi Kelani ,
Shelby Weatherbee ,
Stephen Blama  and
Mary Sajini Devadas Open the ORCID record for Mary Sajini Devadas [Opens in a new window]
Hadi Kelani
Affiliation:
Department of Chemistry, Towson University 8000 York Road, Towson, MD21252, U.S.A.
Shelby Weatherbee
Affiliation:
Department of Chemistry, Towson University 8000 York Road, Towson, MD21252, U.S.A.
Stephen Blama
Affiliation:
Department of Chemistry, Towson University 8000 York Road, Towson, MD21252, U.S.A.
Mary Sajini Devadas*
Affiliation:
Department of Chemistry, Towson University 8000 York Road, Towson, MD21252, U.S.A.
*
*Corresponding Author Email: mdevadas@towson.edu
Get access

Abstract

Graphene oxide serves as a precursor to various technologies, which include batteries, biosensors, solar cells, and supercapacitors. Gold nanoparticles exhibit excellent electrochemical and photophysical properties, allowing for electronic absorption and the ability to absorb light energy at the plasmonic wavelength. Palladium nanoparticles are highly sensitive and functional in room temperature, making it an ideal metal for catalytic applications. We report the synthesis of functional graphene oxide from graphite flakes followed by the insertion of gold and palladium nanoparticles through an oleylamine ligand. In this report, the fermi level of graphene oxide (GOx), gold-graphene oxide (Au-GOx), and palladium-graphene oxide (Pd-GOx) was shown to be effectively controlled. Additionally, each system showed complete solubility in ethanol and in the case of Au-GOx, enhanced solubility was seen in tetrahydrofuran as well.

Keywords

2D materialsnanoscalegrapheneplasmonic
Type
Articles
Information
MRS Advances , Volume 4 , Issue 38-39: Quantum and Nanomaterials , 2019 , pp. 2119 - 2126
Copyright
Copyright © Materials Research Society 2019 

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

REFERENCES

Lightcap, I.V., Kosel, T.H., Kamat, P.V., Nano Letters, 10, 577-583 (2010).CrossRefGoogle Scholar
Neklyudov, V.V., Khafizov, N.R., Sedov, I.A., Dimiev, A.M., Physical Chemistry Chemical Physics, 19, 17000-17008 (2017).CrossRefGoogle Scholar
Huang, X., El-Sayed, M.A., Journal of Advanced Research, 1, 13-28 (2010).CrossRefGoogle Scholar
Eustis, S., El-Sayed, M.A., Chemical Society Reviews, 35, 209-217 (2006).CrossRefGoogle Scholar
Shao, L., Huang, X., Teschner, D., Zhang, W., ACS Catalysis, 4, 2369-2373 (2014).CrossRefGoogle Scholar
Olkhov, R.V., Shaw, A.M., RSC Advances, 4, 31678-31684 (2014).CrossRefGoogle Scholar
Turcheniuk, K., Boukherroub, R., Szunerits, S., Journal of Materials Chemistry B, 3 (2015) 4301-4324.CrossRefGoogle Scholar
Chen, X., Wu, G., Chen, J., Chen, X., Xie, Z., Wang, X., Journal of the American Chemical Society, 133, 3693-3695 (2011).CrossRefGoogle Scholar
Sanger, A., Jain, P.K., Mishra, Y.K., Chandra, R., Sensors and Actuators B: Chemical, 242, 694-699 (2017).CrossRefGoogle Scholar
Erami, R.S., Díaz-García, D., Prashar, S., Rodríguez-Diéguez, A., Fajardo, M., Amirnasr, M., Gómez-Ruiz, S., Catalysts, 7, 76 (2017).CrossRefGoogle Scholar
Liu, Y., Stradins, P., Wei, S.- H., Science Advances, 2 , e1600069 (2016).Google Scholar
Marcano, D.C., Kosynkin, D.V., Berlin, J.M., Sinitskii, A., Sun, Z., Slesarev, A., Alemany, L.B., Lu, W., Tour, J.M., ACS Nano, 4, 4806-4814 (2010).CrossRefGoogle Scholar
Hussain, N.G., , A.; Sarma, R. K.; Sharma, P.; Barras, A.; Boukherroub, R.; Saikia, R.; Sengupta, P.; Das, M.R., ChemPlusChem, 79, 1774-1784 (2014).Google Scholar
Devadas, M.S., Kwak, K., Park, J.-W., Choi, J.-H., Jun, C.-H., Sinn, E., Ramakrishna, G., Lee, D., The Journal of Physical Chemistry Letters, 1, 1497-1503 (2010).CrossRefGoogle Scholar
Katoh, R.S., , K.; Furube, A.; Kotani, M.; Tokumaru, K., J. Phys. Chem. C, 113 (2009) 2961-2965.CrossRefGoogle Scholar
Radich, J.G., Kamat, P.V., ACS Nano, 7, 5546-5557 (2013).CrossRefGoogle Scholar
Lian, P., Zhu, X., Liang, S., Li, Z., Yang, W., Wang, H., Electrochimica Acta, 55, 3909-3914 (2010).CrossRefGoogle Scholar
Nguyen, K.C., Advances in Natural Sciences: Nanoscience and Nanotechnology, 3 , 045008 (2012).Google Scholar