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Quantitative mineralogy of sedimentary rocks with emphasis on clays and with applications to K-Ar dating

Published online by Cambridge University Press:  05 July 2018

J. Środoń
J. Środoń*
Affiliation:
Institute of Geological Sciences PAN, Senacka 1, 31-002, Cracow, Poland
*
*E-mail: ndsrodon@cyf-kr.edu.pl
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Abstract

Clays are the most complicated objects in quantitative mineral analysis of sedimentary rocks. Complex quantitative analysis of clays comprises four major steps: measuring bulk quantities, quantifying the mixed layering, determining the three-dimensional organization, and measuring the particle size. Computerization has resulted in major progress in all four areas during the last decade. X-ray diffraction remains the major tool of the quantitative studies of clays, supported by Fourier Transform Infrared Spectroscopy (bulk quantities), chemical analysis (bulk quantities) and electron microscopy (particle size). This contribution reviews recent developments in the techniques used for quantifying clays and their properties, and looks at the use of these quantification techniques in K-Ar dating of geological processes.

Keywords

clay mineralsrock analysisX-ray diffractioninfrared spectroscopymixed layeringparticle-size analysisK-Ar dating
Type
Research Article
Information
Mineralogical Magazine , Volume 66 , Issue 5 , October 2002 , pp. 677 - 687
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 2002

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References

Adam, H., Harville, D., Meer, D. and Freeman, D. (1988) Rapid mineral analysis by Fourier transform infrared spectroscopy. Society of Core Analysts Conference Paper No. 8809.Google Scholar
Batchelder, M. and Cressey, G. (1998) Rapid, accurate phase quantification of clay-bearing samples using a position-sensitive X-ray detector. Clays and Clay Minerals, 46, 183–194.CrossRefGoogle Scholar
Bertaux, J., Frohlich, F. and Ildefonse, P. (1998) Multicomponent analysis of FTIR spectra: quantification of amorphous and crystallized phases in synthetic and natural sediments. Journal of Sedimentary Research, 68, 440–447.CrossRefGoogle Scholar
Biscaye, P.E. (1965) Mineralogy and sedimentation of Recent deep-sea clay in the Atlantic Ocean and the adjacent seas and oceans. Geological Society of America Bulletin, 76, 803–832.CrossRefGoogle Scholar
Bookin, A., Drits, V.A. and Cherkashin, V. (1999) Mica polytypes – problems in quantitative analysis. Euroclay 99, Program with Abstracts, pp. 65–66.Google Scholar
Brindley, G.W. (1980 a) Quantitative analysis of clay mixtures. Pp. 411–438 in: Crystal Structures of Clay Minerals and their X-ray Identification (Brindley, G.W. and Brown, G., editors). Monograph 5, Mineralogical Society, London.Google Scholar
Brindley, G.W. (1980 b) Order-disorder in clay mineral structures. Pp. 125–195 in: Crystal Structures of Clay Minerals and their X-ray Identification (Brindley, G.W. and Brown, G., editors). Monograph 5, Mineralogical Society, London.Google Scholar
Brown, J.M. and Elliot, J.J. (1985) The quantitative analysis of complex, multicomponent mixtures by FT-IR; the analysis of minerals and interacting organic blends. Pp. 111–128 in: Chemical, Biological and Industrial Applications of Infrared Spectroscopy (During, J., editor). Wiley, Chichester, UK.Google Scholar
Calvert, C.S., Palkovsky, D.A. and Pevear, D.R. (1989) A combined X-ray powder diffraction and chemical method for the quantitative mineral analysis of geologic samples. Pp. 154–166 in: Quantitative Mineral Analysis of Clays (Pevear, D.R. and Mumpton, F.A., editors). CMS Workshop Lectures 1. Clay Minerals Society, Boulder, Colorado.Google Scholar
Chung, F.H. (1974) Quantitative interpretation of X-ray diffraction patterns of mixtures. I. Matrix flushing method for quantitative multicomponent analysis. Journal of Applied Crystallography, 7, 519–525.CrossRefGoogle Scholar
Clauer, N., Środoń, J., Francu, J. and Šucha, V. (1997) K-Ar dating of illite fundamental particles separated from illite/smectite. Clay Minerals, 32, 181–196.CrossRefGoogle Scholar
Cradwick, P.D. (1975) On the calculation of one-dimensional X-ray scattering from interstratified material. Clay Minerals, 10, 347–356.CrossRefGoogle Scholar
Drits, V.A. and Sakharov, B.A. (1976) X-ray Structural Analysis of Mixed-Layer Minerals. Nauka, Moscow (in Russian).Google Scholar
Drits, A.V. and Tchoubar, C. (1990) X-ray Diffraction by Disordered Lamellar Structures: Theory and Applications to Microdivided Silicates and Carbons. Springer-Verlag, New York, Berlin, Heidelberg.CrossRefGoogle Scholar
Drits, V.A., Plançon, A., Sakharov, B.A., Besson, G., Tsipursky, S.I. and Tchoubar, C. (1984) Diffraction effects calculated for structural models of K-saturated montmorillonite containing different types of defects. Clay Minerals, 19, 541–562.Google Scholar
Drits, V.A., Weber, F., Salyn, A.L. and Tsipursky, S. (1993) X-ray identification of one-layer illite varieties: Application to the study of illites around uranium deposits of Canada. Clays and Clay Minerals, 41, 389–398.CrossRefGoogle Scholar
Drits, V.A., Varaxina, T.V., Sakharov, B.A. and Plançon, A. (1994) A simple technique for identification of one-dimensional powder X-ray diffraction patterns for mixed-layer illite-smectites and other minerals. Clays and Clay Minerals, 42, 383–390.CrossRefGoogle Scholar
Drits, V.A., Salyn, A.L. and Šucha, V. (1996) Structural transformations of interstratified illite-smectites from Dolna Ves hydrothermal deposits: dynamics and mechanisms. Clays and Clay Minerals, 44, 181–190.CrossRefGoogle Scholar
Drits, V.A., Środoń, J. and Eberl, D.D. (1997) XRD measurement of mean crystal thickness of illite and illite/smectite: reappraisal of the Kübler index and the Scherrer equation. Clays and Clay Minerals, 45, 461–475.CrossRefGoogle Scholar
Drits, V.A., Eberl, D.D. and Środoń, J. (1998) XRD measurement of mean thickness, thickness distribution and strain for illite and illite/smectite crystallites by the Bertaut-Warren-Averbach technique. Clays and Clay Minerals, 46, 38–50.CrossRefGoogle Scholar
Dudek, T. and Środoń, J. (1996) Identification of illite/smectite by X-ray powder diffraction taking into account the lognormal distribution of crystal thickness. Geologica Carpathica-Series Clays, 5, 21–32.Google Scholar
Dudek, T., Środoń, J., Eberl, D.D., Elsass, F. and Uhlik, P. (2002) Thickness distribution of illite crystals in shales. 1: XRD vs. HRTEM measurements. Clays and Clay Minerals (in press).Google Scholar
Eberl, D.D., Nuesch, R., Šucha, V. and Tsipursky, S. (1998) Measurement of fundamental particle thicknesses by X-ray diffraction using PVP-10 intercalation. Clays and Clay Minerals, 46, 89–97.CrossRefGoogle Scholar
Elsass, F., Środoń, J. and Robert, M. (1997) Illite-smectite alteration and accompanying reactions in a Pennsylvanian underclay studied by TEM. Clays and Clay Minerals, 45, 390–403.CrossRefGoogle Scholar
Estep-Barnes, P.A. (1977) Infrared spectroscopy. Pp. 529–603 in: Physical Methods in Determinative Mineralogy (Zussman, J., editor). Academic Press, London.Google Scholar
Garrels, R.M. and Mackenzie, F.T. (1971) Evolution of Sedimentary Rocks. Norton, New York.Google Scholar
Grathoff, G.H., Moore, D.M., Hay, R.L. and Wemmer, K. (1998) Illite polytype quantification and K/Ar dating of Paleozoic shales: a technique to quantify diagenetic and detrital illite. Pp. 161–175 in: Shales and Mudstones II (Schiebler, J., Zimmerle, W. and Sethii, P., editors). E. Schweizerbart'sche Verlagsbuchhandlung, Stuttgart, Germany.Google Scholar
Herron, S.L. and Herron, M.M. (1996) Quantitative lithology: an application for open and cased hole spectroscopy. Transactions of the SPWLA 37th Annual Logging Symposium, Paper E, New Orleans, Louisiana, USA.Google Scholar
Herron, M.M., Matteson, A. and Gustavson, G. (1997) Dual-range FT-IR mineralogy and the analysis of sedimentary formations. Society of Core Analysts Intern ational Symposium, Calgary, Canada. Proceedings Paper No. SCA-9729, 1–12.Google Scholar
Hillier, S. (1999) Use of an air-brush to spray-dry samples for X-ray powder diffract ion. Clay Minerals, 34, 127–135.CrossRefGoogle Scholar
Hillier, S. (2000) Accurate quantitative analysis of clay and other minerals in sandstones by XRD: comparison of a Rietveld and a reference intensity ratio (RIR) method and the importance of sample preparation. Clay Minerals, 35, 291–302.CrossRefGoogle Scholar
Hubbard, C.R. and Snyder, R.L. (1988) RIR – measurement and use in quantitative XRD. Powder Diffraction, 3, 74–77.CrossRefGoogle Scholar
Jonas, E.C. and Kuykendall, J.R. (1965) Preparation of montmorillonites for random powder diffraction. Clay Minerals, 6, 232–235.CrossRefGoogle Scholar
Kakinoki, J. and Komura, Y. (1965) Diffraction by a one-dimensionally disordered crystal. I. The intensity equation. Acta Crystallographica, 19, 137–147.CrossRefGoogle Scholar
Kish, H.J. (1987) Correlation between indicators of very low-grade metamorphism. Pp. 227–299 in: Low Temperature Metamorphism (Frey, M., editor). Blackie, Glasgow, Scotland.Google Scholar
Kister, J., Guiliano, M., Reymond, H., Mille, G. and Dou, H. (1985) Analyse quantitative par spectroscopie infrarouge a transformee de Fourier de la partie minerale de charbons. Mise au point et application de la technique. International Journal of Environmental and Analytical Chemistry, 22, 297–318 (in French).CrossRefGoogle Scholar
Kotarba, M. and Środoń, J. (2000) Diagenetic evolution of crystallite thickness distribution of illitic material in Carpathian flysh shales studied by Bertaut-Warren-Averbach XRD method (MudMaster computer program). Clay Minerals, 35, 387–395.CrossRefGoogle Scholar
MacEwan, D.M.C. (1956) Fourier transform methods. I. A direct method of analysing interstratified mixtures. Kolloidzeitschrift, 149, 96–108.Google Scholar
MacEwan, D.M.C. (1958) Fourier transform methods. II. Calculation of diffraction effects for different types of interstratification. Kolloidzeitschrift, 156, 61–67.Google Scholar
Matulis, C.E. and Taylor, J.C. (1993) A theoretical model for the correction of intensity aberrations in Bragg-Brentano X-ray diffractometers – detailed description of the algorithm. Journal of Applied Crystallography, 26, 351–356.CrossRefGoogle Scholar
Matteson, A. and Herron, M.M. (1993) Quantitative mineral analysis by Fourier transform infrared spectroscopy. Society of Core Analysts Conference Paper No. 9308, pp. 1–15.Google Scholar
McCarty, D.K. and Reynolds, R.C. Jr. (1995) Rotationally disordered illite/smectite in Paleozoic K-bentonites. Clays and Clay Minerals, 43, 271–284.CrossRefGoogle Scholar
McCarty, D.K. and Reynolds, R.C. Jr. (2001) Three-dimensional crystal structures of illite-smectite minerals in Paleozoic K-bentonit es from the Appalachian Basin. Clays and Clay Minerals, 49, 24–35.CrossRefGoogle Scholar
McCarty, D.K., Środoń, J. and Drits, V.A. (1999) The heterogeneity of clays in shales. Euroclay 99, Program with Abstracts, pp. 110–111.Google Scholar
McManus, D.A. (1991) Suggestions for authors whose manuscripts include quantitative clay mineral analysis by X-ray diffraction. Marine Geology, 98, 1–5.CrossRefGoogle Scholar
Moore, D.M. and Reynolds, R.C. Jr. (1997) X-ray Diffraction and the Identification and Analysis of Clay Minerals. Oxford University Press, Oxford, UK and New York.Google Scholar
Morton, J.P. (1985) Rb-Sr evidence for punctuated illite/smectite diagenesis in the Oligocene Frio Formation. Geological Society of America Bulletin, 96, 114–122.2.0.CO;2>CrossRefGoogle Scholar
Mystkowski, K., Środoń, J. and Elsass, F. (2000) Mean thickness and thickness distribution of smectite crystallites. Clay Minerals, 35, 545–557.CrossRefGoogle Scholar
Nadeau, P.H., Wilson, M.J., McHardy, W.J. and Tait, J.M. (1984) Interstratified clays as fundamental particles. Science, 225, 923–935.CrossRefGoogle ScholarPubMed
O'Connor, B.H. and Chang, W.J. (1986) The amorphous character and particle size distribution of powders produced with the micronizing mill for quantitative X-ray powder diffractometry. X-ray Spectrometry, 15, 267–270.CrossRefGoogle Scholar
Painter, P.C., Coleman, M.M., Jenkins, R.G., Whang, P.W. and Walker, P.L. Jr. (1978) Fourier Transform Infrared study of mineral matter in coal. A novel method for quantitative mineralogical analysis. Fuel, 57, 337–344.CrossRefGoogle Scholar
Painter, P.C., Rimmer, S.M., Snyder, R.W. and Davis, A. (1981) A Fourier transform infrared study of mineral matter in coal: the application of a least squares curve-fitting program. Applied Spectroscopy, 35, 102–106.CrossRefGoogle Scholar
Pawloski, G.A. (1985) Quantitative determination of mineral content of geological samples by X-ray diffraction. American Mineralogist, 70, 663–667.Google Scholar
Pearson, M.J. (1978) Quantitative clay mineralogical analyses from the bulk chemistry of sedimentary rocks. Clays and Clay Minerals, 26, 423–433.CrossRefGoogle Scholar
Pevear, D.R. (1992) Illite age analysis, a new tool for basin thermal history analysis. Pp. 1251–1254 in: Proceedings of the 7th International. Symposium on. Water-Rock Interactions (Kharaka, Y.K. and Maest, A.S., editors). Park City, Utah.Google Scholar
Pevear, D.R. and Schuette, C.M. (1993) Inverting the NEWMOD X-ray diffraction forward model for clay minerals using genetic algorithms. Pp. 20–41 in: Computer Applications to X-ray Diffraction Methods (Reynolds, R.C. and Walker, J.R., editors). CMS Workshop Lectures 5. Clay Minerals Society, Boulder, Colorado.Google Scholar
Plançon, A. and Tchoubar, C. (1975) Etudes des fautes d'empilement dans les kaolinites partiellement desordonnees. I. Modele d'empilement ne comportant que des fautes de translation. Journal of Applied Crystallography, 8, 582–588.CrossRefGoogle Scholar
Plançon, A., Giese, R.F., Snyder, R., Drits, V.A., and Bookin, A.S. (1989) Stacking faults in the kaolin-group minerals: Defect structures of kaolinite. Clays and Clay Minerals, 37, 203–210.CrossRefGoogle Scholar
Reynolds, R.C. Jr. (1967) Interstratified clay systems: calculation of the total one-dimensional diffraction function. American Mineralogist, 52, 661–672.Google Scholar
Reynolds, R.C. Jr. (1980) Interstratified clay minerals. Pp. 249–303 in: Crystal Structures of Clay Minerals and their X-ray Identification (Brindley, G.W. and Brown, G., editors). Monograph 5, Mineral Society, London.Google Scholar
Reynolds, R.C. Jr. (1989) Principles and techniques of quantitative analysis of clay minerals by X-ray powder diffraction. Pp. 4–36 in: Quantitative Mineral Analysis of Clays (Pevear, D.R. and Mumpton, F.A., editors). CMS Workshop Lectures 1. Clay Minerals Society, Boulder, Colorado.Google Scholar
Reynolds, R.C. Jr. (1993) Three-dimensional powder X-ray diffraction from disordered illite: Simulation and interpretation of the diffraction patterns. Pp. 44–78 in: Computer Applications to X-ray Diffraction Methods (Reynolds, R.C. and Walker, J.R., editors). CMS Workshop Lectures 5. Clay Minerals Society, Boulder, Colorado.Google Scholar
Russel, J.D. and Fraser, A.R. (1994) Infrared methods. Pp. 11–67 in: Clay Mineralogy: Spectroscopic and Chemical Determinative Methods (Wilson, M.J., editor). Chapman & Hall, London.CrossRefGoogle Scholar
Sakharov, B.A., Naumov, A.S. and Drits, V.A. (1983) Scattering of X-rays by imperfect layered structures. Soviet Physical Crystallography, 28, 5, 564–568.Google Scholar
Sakharov, B.A., Besson, G., Drits, V.A., Kameneva, M.Y., Salyn, A.L. and Smoliar, B.B. (1990) X-ray study of the nature of stacking faults in the structure of glauconites. Clay Minerals, 25, 419–435.CrossRefGoogle Scholar
Sakharov, B.A., Lindgreen, H., Salyn, A.L. and Drits, V.A. (1999) Determination of illite-smectite structures using multispecimen X-ray diffraction profile fitting. Clays and Clay Minerals, 47, 555–566.CrossRefGoogle Scholar
Sato, M. (1969) Interstratified structures. Zeitschrift für Kristallographie, 129, 388–395.CrossRefGoogle Scholar
Sato, M. (1987) Interstratified (mixed-layer) structures and their theoretical X-ray powder patterns I. theoretical aspects. Clay Science, 7, 41–48.Google Scholar
Schultz, L.G. (1964) Quantitative interpretation of mineralogical composition from X-ray and chemical data for the Pierre Shale. USGS Professional Paper, 391-C.CrossRefGoogle Scholar
Slaughter, M. (1989) Quantitative determination of clays and other minerals in rocks. Pp. 120–151 in: Quantitative Mineral Analysis of Clays (Pevear, D.R. and Mumpton, F.A., editors). CMS Workshop Lectures 1. Clay Minerals Society, Boulder, Colorado.Google Scholar
Smith, S.T., Snyder, S.L. and Brownell, W.E. (1979) Quantitative phase analysis of Devonian shales by computer controlled X-ray diffraction of spray dried samples. Advances in X-ray Analysis, 22, 181–191.CrossRefGoogle Scholar
Smith, D.K. and Johnson, G.G. (1989) Chemical constraints in quantitative X-ray powder diffraction for mineral analysis of the sand/silt fractions of sedimentary rocks. Advances in X-ray Analysis, 38, 489–496.CrossRefGoogle Scholar
Smith, D.K., Johnson, G.G. Jr. and Jenkins, R. (1995) A full-trace database for the analysis of clay minerals. Advances in X-ray Analysis, 38, 117–125.CrossRefGoogle Scholar
Smith, D.K., Johnson, G.G. Jr., Scheible, W., Wims, A.M., Johnson, J.L. and Ullmann, G. (1987) Quantitative X-ray powder diffraction method using the full diffraction pattern. Powder Diffraction, 2, 73–77.CrossRefGoogle Scholar
Snyder, R.L. and Bish, D.L. (1989) Quantitative analysis. Pp. 101–144 in: Modern Powder Diffraction (Bish, D.J. and Post, J.E., editors). Reviews in Mineralogy, 20. Mineralogical Society of America, Washington, D.C.CrossRefGoogle Scholar
Środoń, J. (1980) Precise identification of illite/smectite interstratifications by X-ray powder diffraction. Clays and Clay Minerals, 28, 401–411.CrossRefGoogle Scholar
Środoń, J. (1984) X-ray powder diffraction identification of illitic materials. Clays and Clay Minerals, 32, 337–349.CrossRefGoogle Scholar
Środoń, J. (1999 a) Nature of mixed-layer clays and mechanisms of their formation and alteration. Annual Review of Earth and Planetary Sciences, 27, 19–53.CrossRefGoogle Scholar
Środoń, J. (1999 b) Extracting K-Ar ages from shales: a theoretical test. Clay Minerals, 33, 375–378.CrossRefGoogle Scholar
Środoń, J. (2000) Reply to discussion of ‘Extracting KAr ages from shales: a theoretical test’. Clay Minerals, 35, 605–608.CrossRefGoogle Scholar
Środoń, J. and Clauer, N. (2001) Diagenetic history of Lower Paleozoic sediments in Pomerania (northern Poland) traced across the Teisseyre-Tornquist tectonic zone using mixed-layer illite-smectite. Clay Minerals, 36, 15–27.CrossRefGoogle Scholar
Środoń, J., Andreoli, C., Elsass, F. and Robert, M. (1990) Direct high-resolution transmission electron microscopic measurement of expandability of mixed-layer illite/smectite in bentonite rock. Clays and Clay Minerals, 38, 373–379.CrossRefGoogle Scholar
Środoń, J., Eberl, D.D. and Drits, V.A. (2000) Evolution of fundamental particle-size during illitization of smectite and implications for reaction mechanism. Clays and Clay Minerals, 48, 446–458.CrossRefGoogle Scholar
Środoń, J., Drits, V.A., McCarty, D.K., Hsieh, J.C.C. and Eberl, D.D. (2001) Quantitative XRD analysis of clay-rich rocks from random preparations. Clays and Clay Minerals, 49, 514–528.CrossRefGoogle Scholar
Środoń, J., Clauer, N. and Eberl, D.D. (in press) Interpretation of K-Ar dates of illitic clays from sedimentary rocks aided by modelling. American Mineralogist.Google Scholar
Šucha, V., Środoń, J., Elsass, F. and McHardy, W.J. (1996) Particle shape versus coherent scattering domain of illite/smectite: evidence from HRTEM of Dolna Ves clays. Clays and Clay Minerals, 44, 665–671.CrossRefGoogle Scholar
Takahashi, H. (1982) Electronic computer's program for calculation of diffracted intensity by close-packed structure with stacking faults. Bulletin of Faculty of Education, Kagoshima University, 34, 1–14 (in Japanese).Google Scholar
Taylor, J.C. (1991) Computer programs for standardless quantitative analysis of minerals using the full powder diffraction profile. Powder Diffraction, 6, 2–9.CrossRefGoogle Scholar
Taylor, J.C. and Matulis, C.E. (1994) A new method for Rietveld clay analysis. Part I. Use of a universal measured standard profile for Rietveld quantification of montmorillonites. Powder Diffraction, 9, 119–123.CrossRefGoogle Scholar
Tomita, K. and Takahashi, H. (1985) Curves for the quantification of mica/smectite and chlorite/smectite interstratifications by X-ray powder diffraction. Clays and Clay Minerals, 33, 379–390.CrossRefGoogle Scholar
Tomita, K. and Takahashi, H. (1986) Quantification curves for the X-ray powder diffraction analysis of mixed-layer kaolinite/smectite. Clays and Clay Minerals, 34, 323–329.CrossRefGoogle Scholar
Uhlik, P., Šucha, V., Elsass, F. and Caplovicova, M. (2000) High-resolution transmission electron microscopy of mixed-layer clays dispersed in PVP-10: A new technique to distinguish detrital and authigenic illitic material. Clay Minerals, 35, 781–789.CrossRefGoogle Scholar
van der Marel, H.W. and Beutelspacher, H. (1976) Atlas of Infrared Spectroscopy of Clay Minerals and their Admixtures. Elsevier, Amsterdam.Google Scholar
Watanabe, T. (1981) Identification of illite/smectite interstratification by X-ray powder diffraction. Journal of Mineralogical Society of Japan, Spec. Issue 15, 32–41 (in Japanese).CrossRefGoogle Scholar
Ylagan, R.F., Pevear, D.R. and Vrolijk, P.J. (2000) Discussion of ‘Extracting K-Ar ages from shales: a theoretical test’. Clay Minerals, 35, 599–604.CrossRefGoogle Scholar