Hostname: page-component-7479d7b7d-qs9v7 Total loading time: 0 Render date: 2024-07-11T08:33:59.715Z Has data issue: false hasContentIssue false

A new occurrence of vesigniéite from the Gorob-Hope copper deposit, Namibia

Published online by Cambridge University Press:  05 July 2018

G. I. C. Schneider
Affiliation:
Geological Survey of Namibia P.O. Box 2168 Windhoek 9000, Namibia
H.-J. Lauenstein
Affiliation:
Tsumeb Corporation P.O. Box 40 Tsumeb 9000, Namibia

Abstract

An iron-rich vesigniéite, [Ba(Cu,Fe)3(VO4)2(OH)2] with Cu : Fe near 4 : 1, was identified in samples from the submarine-exhalative Gorob-Hope copper deposit, Namibia. The olive-colour mineral occurs as mammillary encrustations and vein fillings in the gossan zone of this deposit; it often has a brownish oxidation coating. The main X-ray lines are 3.21 Å (100) [204, 113], 2.72 Å (63) [313,002] and 2.94 Å (61) [020, 311]. The cell parameters are a = 10.236, b = 5.905, c = 14.253 Å and B = 103.71°. The formation of vesigniéite took place during the alteration of the ore under strongly alkaline and slightly reducing to oxidizing conditions. While copper and barium were derived from the submarine exhalative mineralisation, vanadium was leached from the countryrock, a micea schist.

Type
Research Article
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 2014

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

Evans, H. T. Jr. and Garrels, R. M. (1958) Geochim. Cosmochim. Acta, 15, 131.10.1016/0016-7037(58)90015-2CrossRefGoogle Scholar
Guillemin, C. (1955) C.R. Acad. Sci. Paris, 240, 2331.Google Scholar
Guillemin, C. (1956) Bull. Soc. Fr. Minéral. Cristallogr., 79, 219–75.Google Scholar
Hartleb, J. W. O. (1988) Ore Geology Reviews, 3, 277–87.10.1016/0169-1368(88)90022-4CrossRefGoogle Scholar
Miller, R. McG. (1983) In: R. McG. Miller, Ed., p. 431-515. Geol. Soc. South Africa Spec. Publ. 11, Johannesburg.Google Scholar
Vesigniéite Research Group (1977) Acta Geol. Sinica, 1, 67-83.Google Scholar