Hostname: page-component-8448b6f56d-gtxcr Total loading time: 0 Render date: 2024-04-18T12:17:32.174Z Has data issue: false hasContentIssue false
  • English
  • Français

Gobbinsite, a new zeolite mineral from Co. Antrim, N. Ireland

Published online by Cambridge University Press:  05 July 2018

Rab Nawaz  and
John F. Malone
Rab Nawaz
Affiliation:
Department of Geology, Ulster Museum, Belfast
John F. Malone
Affiliation:
Department of Chemistry, Queen's University, Belfast
Get access Rights & Permissions [Opens in a new window]

Abstract

A chalky white, fibrous mineral, in the amygdales of Tertiary basalts from the Gobbins area, Co. Antrim, has been discovered to be a new mineral. It consists of fibrous dusters of lath-shaped crystals showing straight extinction with negative elongation. Its refractive index is ɛ 1.489, ω 1.494 (both ± 0.003) and specific gravity is 2.194 (meas.), 2.147 (calc.). The mineral is tetragonal with ɛ = c (elongation); a = 10.145, c = 9.788 Å. The strongest powder lines (in Å, intensity in brackets) are: 7.10, 4.10, 3.19(100); 3.10, 2.69(80); 5.07(50); 2.64(40). A spectrographic analysis shows major Si, Al, minor Ca, Na, Cu, and trace Fe. Two chemical and one probe analysis give the ideal formula Na4(Ca,Mg,K2)Al6Si10 O32.12H2O. The name gobbinsite (approved by the IMA Commission on New Mineral Names) is suggested after the locality. The type specimen (I7881) is preserved in the Ulster Museum.

Rotation and Weissenberg photographs of gobbinsite and garronite show doubled reflections, which are explained on the basis of submicroscopic twinning on (101). Relationship between gobbinsite and garronite is discussed and evidence is presented for the occurrence of minute amounts of a merlinoite-type mineral that forms regular intergrowths with gobbinsite and garronite.

Type
Research Article
Information
Mineralogical Magazine , Volume 46 , Issue 340 , September 1982 , pp. 365 - 369
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 1982

Access options

Get access to the full version of this content by using one of the access options below. (Log in options will check for institutional or personal access. Content may require purchase if you do not have access.)

References

Barrer, R. M., and Baynham, J. W. (1956) The hydro-thermal chemistry of the silicates. Part VII. Synthetic potassium aluminosilicates. J. Chem. Soc. 2882-91 [M.A. 13-449].CrossRefGoogle Scholar
Barrer, R. M., and Baynham, J. W., Bultitude, R. W., and Meier, W. M. (1959a) Hydrothermal chemistry of silicates. Part VIII. Low-temp, crystal growth of aluminosilicates, and of some gallium and germanium analogues. Ibid. 196-208.CrossRefGoogle Scholar
Barrer, R. M., Bultitude, F. W., and Kerr, I. S. (1959b) Some properties of, and structural scheme for, the Harmotome zeolites. Ibid. 1521-8.Google Scholar
Gottardi, G., and Alberti, A. (1974) Domain structure in garronite: a hypothesis. Mineral. Ma#. 39, 898–9.CrossRefGoogle Scholar
Mandarino, J. A. (1963) Garronite abstract, New Mineral Names (by Fleischer, M.) Am. Mineral. 48, 711–12.Google Scholar
Pabst, A. (1971) Natrolite from the Green River Formation, Colorado, showing an intergrowth akin to twinning. Ibid. 56, 560–9.Google Scholar
Passaglia, E., Pongiluppi, D., and Rinaldi, R. (1977) Merlinoite, a new mineral of the zeolite group. Neues Jahrb. Mineral., Monatsh. 355-64.Google Scholar
Taylor, A. M., and Rustum Roy (1964) Zeolite studies IV. Na-P zeolites and the ion-exchanged derivatives of tetragonal Na-P. Am. Mineral. 49, 656–82.Google Scholar
Walker, G. P. L. (1962) Garronite, a new zeolite, from Ireland and Iceland. Mineral. Mag. 33, 173–86.Google Scholar