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The distribution of trace precious metals in minerals and mineral products

The 23rd Hallimond Lecture (1991)

Published online by Cambridge University Press:  05 July 2018

Louis J. Cabri
Louis J. Cabri*
Affiliation:
Canada Centre for Mineral and Energy Technology, Ottawa, Ontario, Canada KIA 0G1
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Abstract

Data on the distribution of the precious metals (Au, Ag and the platinum=group elements Ru, Rh, Pd, Os, Ir, Pt) are rapidly accumulating as a consequence of the application of microbeam analytical techniques such as the electron microprobe, the proton microprobe, and the ion microprobe. The new data obtained with these techniques build on knowledge accumulated over the last 140 years using bulk analytical methods (e.g. spectrographic). The nature of the occurrence, the concentrations, and the variation in amount s of precious metals in minerals and mineral products are reviewed with comments as to the significance of the results with respect to industrial and environmental concerns. Future directions in mineral-specific analysis of trace precious-metal concentrations and applications outside of process mineralogy are discussed.

Keywords

precious metalsAuAgPGEmicrobeam techniqueselectron-proton- and ion microprobesprocess mineralogymineral balancesmineral processingextractive metallurgyenvironment
Type
The Hallimond Lecture
Information
Mineralogical Magazine , Volume 56 , Issue 384 , September 1992 , pp. 289 - 308
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 1992

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References

Anderson, A.J., Clark, A.H., Mas, X.-P., Palmer, G.R., MacArthur, J.D., and Roedder, E. (1989) Proton-induced X-ray and gamma-ray emission analysis of unopened fluid inclusions. Econ. Geol. 84, 924–39.CrossRefGoogle Scholar
Bérubé, M.-A., Bernard, D., and Laeat, J. (1985) Distribution minéralogique de l'argent dans les rejets de la mine Calumet, Québec. Can. Mineral. 23, 635–41.Google Scholar
Boyle, R.W. (1979) The geochemistry of gold and its deposits. Geol. Surv. Can. Bull. 280, 584.p.Google Scholar
Broadhead, M., Broadhead, R., and Hager, J.W. (1990) Laser sampling inductively coupled mass spectrometry: determination of 66 elements in geo-logical samples. Atomic Spec. 11, 205–9.Google Scholar
Bürg, G. H. (1930) Die Sichtbarmachung des feinver-teilten Goldes in goldhoffigen Erzen und ihre wirt-schaftliche Bedeutung. Metall. u. Erz. 27, 333.8Google Scholar
Bürg, G. H. (1935) Natur des in den Pyriten nicht sichtbar enthaltenen Goldes. Zeit. f prakt. Geologic, 2, 3–26.Google Scholar
Cabri, L.J. (1967) A new copper-iron sulfide. Econ. Geol. 62, 910–25.CrossRefGoogle Scholar
Cabri, L.J. (1972) The mineralogy of the platinum-group elements. Minerals Sci. Eng. 4, 3–29.Google Scholar
Cabri, L.J. (1973) New data on phase relations in the Cu-Fe-S system. Econ. GeoL 68, 443–54.CrossRefGoogle Scholar
Cabri, L.J. (1974) The significance of detailed mineralogical studies of sulfide ores. Geol. Soc. Amer. Abstr. with Program, 6, no. 7, 677.Google Scholar
Cabri, L.J. (1976) Glossary of platinum-group minerals. Econ. Geol. 71, 1476–80.CrossRefGoogle Scholar
Cabri, L.J. (1980) Determination of ideal formulae for new minerals of the platinum-group. Proceed. XI General Meeting of IMA, 1978, 10, 157–65.Google Scholar
Cabri, L.J. (1981) Platinum-Group Elements: Mineralogy, Geology, Recovery.Can. Inst. Mining Metall. Spec. Vol. 23, 267.p.Google Scholar
Cabri, L.J. (1987) The mineralogy of precious metals: new developments and metallurgical implications. Can. Mineral. 25, 1–7.Google Scholar
Cabri, L.J. (1988a) Applications of proton and nuclear micro- probes in ore deposit mineralogy and metallurgy. Nucl. Instr. Methods Phys. Res. B30, 459-55.CrossRefGoogle Scholar
Cabri, L.J. (1988b) New developments in determination of the distributution of precious metals in ore deposits. Proc. Seventh Quadrennial IAGOD Symposium, 149-54.Google Scholar
Cabri, L.J. (1991) Mineralogical balances in platinum-group element-bearing ores. Internat. Congr. Appl. Mineral., Pretoria, 1, Paper 9, 19.Google Scholar
Cabri, L.J. and Chryssoulis, S.L. (1990) Genesis of the Olympias carbonate-hosted Pb-Zn(Au,Ag) sulfide ore deposit, eastern Chalkidiki Peninsula, northern Greece—a discussion. Econ. Geol. 85, 651–2.CrossRefGoogle Scholar
Cabri, L.J. and Hall, S.R. (1972) Mooihoekite and haycock- ite, two new copper-iron sulfides, and their relationship to chalcopyrite and talnakhite. Amer. Mineral. 57, 689–708.Google Scholar
Cabri, L.J. and Harris, D.C. (1971) New compositional data on talnakhite, Culs(Fe,Ni)16S32. Econ. Geol. 66, 673–5.CrossRefGoogle Scholar
Cabri, L.J. and Laflamme J. H. G. (1976) The mineralogy of the platinum-group elements from some copper-nickel deposits of the Sudbury area, Ontario. Ibid. 71, 1159-95.CrossRefGoogle Scholar
Cabri, L.J. (1979) Mineralogy of samples from the Lac des Iles area, Ontario. CANMETRept. 79-27, 20pp.CrossRefGoogle Scholar
Cabri, L.J. (1981) Analyses of minerals containing platinum-group elements. In Platinum-Group Elements: Mineralogy, Geology, Recovery (L. J. Cabri Ed.). Can. Inst. Mining Metall. Spec. Vol. 23, 151-73.Google Scholar
Cabri, L.J. (1984) Mineralogy and distribution of platinum-group elements in mill products from Sudbury. Proceed. 2nd lnternat. Congr. Appld. Mineral. in the Minerals Industry, (Park, W. C., Hausen, D. M. & Hagni, R. D., Eds.), Metall. Soc. AIME, 911-22.Google Scholar
Cabri, L.J. and Traill, R.J. (1966) New palladium minerals from Noril'sk, western Siberia. Can. Mineral. 8, 541–50.Google Scholar
Cabri, L.J. Hall, S.R., Szymanski, J.T., and Stewart, J.M. (1973) On the transformation of cubanite. Ibid. 12, 33-8.Google Scholar
Cabri, L.J., Criddle, A.J., Laflamme, J.H.G., Bearne, G.S., and Harris, D.C. (1981) Mineralogical study of complex Pt-Fe nuggets from Ethiopia. Bull. Mindral. 104, 508–25.CrossRefGoogle Scholar
Cabri, L.J. Blank, H., El Goresy, A., Laflamme, J.H.G., Nobiling, R., Sizgoric, M.B., and Traxel, K. (1984) Quantitative trace-element anlayses of sulfides from Sudbury and StiUwater by proton microprobe. Can. Mineral. 22, 521–42.Google Scholar
Cabri, L.J. Campbell, J.L., Laflamme, J.H.G., Leigh, R.E., Maxwell, J.A., and Scott, J.D. (1985) Proton-microprobe analyses of trace elements in sulfides from some massive-sulfide deposits. Ibid. 23, 133—48.Google Scholar
Cabri, L.J. Craigen, W.J.S. Pouskouleli, G., and Stemerowicz, A.E. (1988) Platinum metals recovery. CANMET Div. Rept. MSL 88-148 (IR).Google Scholar
Cabri, L.J., Chryssoulis, S.L., de Villiers, J.P.R., Laflamme, J.H.G., and Buseck, P.R. (1989) The nature of ‘invisible’ gold in arsenopyrite. Can. Mineral. 27, 353-52.Google Scholar
Cabri, L.J. Campbell, J.L., and Teesdale, W.J. (1991) Comparison of in-situ gold analyses in arsenian pyrite. Appl. Geochem. 6, 225–30.CrossRefGoogle Scholar
Cabri, L.J. Laflamme, J.H.G., and Lastra, R. (1991) Process mineralogy of samples from the Wellgreen Cu-Ni-Pt-Pd deposit, Yukon. CANMET Division Report MSL 91-8 (CR), 37pp.Google Scholar
Campbell, J.L., Cabri, L.J., Rogers, P.S.Z., Traxel, K., and Benjamin, T.M. (1987) Calibratrion of micro-PIXE analysis of sulfide minerals. Nucl. Instr. Meth. Phys. Res. B22, 437-41.CrossRefGoogle Scholar
Campbell, J.L., Teesdale, W.J., Halden, N.M., Anderson, A.J., and Guha, J. (1991) The scanning proton micro-probe: a new tool for image analysis in geology. Ann. Mtg. Geol. Assoc. Can.-Mineral. Assoc. Can. with Soc. Econ. Geol. Prog. with Abstracts, 16, A19.Google Scholar
Chen, T.T., and Dutrizac, J.E. (1990) Mineralogical reactions of gold and silver during the electrorefining of copper anodes. Proceed. Copper ‘90, Refining, Fabrication, Markets, Inst. Metals, 180-8.Google Scholar
Chen, T.T., and Dutrizac, J.E. (1991) The behaviour of gold and silver during copper electrorefining. Proceed. 14th Precious Metal Inst. (in press).Google Scholar
Chen, T.T., and Dutrizac, J.E. and Petruk, W. (1980) Mineralogy and characteristics that affect recoveries of metals and trace elements from the ore at Heath Steel mines, New Brunswick. Can. Inst. Mining Metall. Bull. 73, 167–79.Google Scholar
Chryssoulis, S.L. (1989) Ion probe microanalysis of good in common sulphide minerals and implications of enhanced recovery from refractory gold ores. CANMET Contract Rep. 79037-01-SS, 380pp.Google Scholar
Chryssoulis, S.L. (1990) Detection and quantification of ‘invisible’ gold by microprobe techniques. In Gold 90 (Eds. D. M. Hausen et al.), AIME, 323-32.Google Scholar
Chryssoulis, S.L. (1991) Determination of submicroscopic precious metals dispersed within common ore minerals. Implications for ore genesis and mineralogical balances. Mineral. Soc. Winter Conf. Abstr. 15.Google Scholar
Chryssoulis, S.L. and Cabri, L.J. (1990) Significance of gold mineralogical balances in mineral processing. Trans. Inst. Mining Metall. 99, C1-C10.Google Scholar
Chryssoulis, S.L. (1991) Quantitative microanalysis of PGE in sulphide and oxide minerals. 6th Internat. Platinum Symp., Prog. and Abstr., Perth, 15.Google Scholar
Chryssoulis, S.L. and Surges, L.J. (1988) Behaviour of tctrahedrite in mill circuits of Brunswick Mining and Smelting Corporation, Ltd. In Silver-Exploration, Mining & Treatment. Inst. Mining Metall., 205-16.Google Scholar
Chryssoulis, S.L. Chauvin, W.J., and Surges, L.J. (1986) Trace element analysis by secondary ion mass spectrometry with particular reference to silver in the Brunswick sphalerite. Can. Metall. Quart. 25, 233–9.CrossRefGoogle Scholar
Chryssoulis, S.L. Cabri, L.J. and Salter, R.S. (1987) Direct determination of invisible gold in refractory sulphide ores. In Proceed. lnternat. Symp. on Gold Metallurgy, Winnipeg (R. S. Salter, D. M. Wyslouzil, and G. W. McDonald, Eds.) Pergamon Press, Toronto, 235-44.Google Scholar
Chryssoulis, S.L. Alcock, R.A., Sizgoric, M.B. and Cabri, L.J. (1989a) Quantitative trace PGE analysis of pyrrho-rite, pentlandite and millerite. Geol. Soc. Finland Bull. No. 61, Abstr., 56.Google Scholar
Chryssoulis, S.L. Cabri, L.J., and Lennard, W. (1989b) Calibration of the ion microprobe for quantitative trace precious metal analyses of ore minerals. Econ. Geol. 84, 1684–9.CrossRefGoogle Scholar
Chryssoulis, S.L. Distler, V.V., Evstigneeva, T.L., Filimonova, A.A., Genkin, A.D., and Weisener, C.G. (1991a) Platinum-group elements in the sulphides of Noril'sk copper-nickel ores. 6th Internat. Platinum Symp., Prog. with Abstr., Perth, 16.Google Scholar
Chryssoulis, S.L. Reich, F., and Cabri, L. J. (1991b) Characterization of surface composition of minerals by laser ionization mass spectrometry (LIMS). Ann. Mtg. Geol. Assoc. Can.—Mineral. Assoc. Can. with Soc. Econ. Geol., Prog. with Abstracts, 16, A23.Google Scholar
Colvine, A.C., Fyon, J.A., Heather, K.B., Marmont, S., Smith, P.M., and Troop, D.G. (1988) Archean lode gold deposits in Ontario. Ont. Geol. Surv. Miscel. Paper, 139, 136.p.Google Scholar
Cook, N.J. and Chryssoulis, S.L. (1990) Concen-trations of ‘invisible gold’ in the common sulfides. Can. Mineral. 28, 1–16.Google Scholar
Czamanske, G.K., Cabri, L.J., Zientek, M.L., Likhachev, A.P., Calk, L.C., and Oscarson, R.L. (1991) Proton microprobe analyses of dominant phases in the Cu-Fe-Ni-S system, Oktyabr'sky mine, Noril'sk-Talnakh district, U.S.S.R. Ann. Mtg. Geol. Assoc. Can.—Mineral. Assoc. Can. with Soc. Econ. Geol., Prog. with Abstracts, 16, A27.Google Scholar
Czamanske, G.K. Kulinov, V.E., Likhachev, A.P., Zientek, M.L., Cabri, L.J., Calk, L.C., and Oscarson, R.L. (1992) A proton microprobe study of sulfide ores from the Noril'sk-Talnakh district, Siberia. Can. Mineral. 30, 249–87.Google Scholar
Demopoulos, G.P. and Papangelakis, V.G. (1989) Recent advances in refractory gold processing. Can. Inst. Mining Metall. Bull. 82, 85–91.Google Scholar
Distler, V.V. and Laputina, I.L. (1979) Nickel and cobalt sulpharsenides containing platinum metals. Dokl. Acad. Nauk. SSSR, E.S.S. 24B, 718-21.Google Scholar
Dunn, J.G., Graham, J., Just, J., Nguyen, G., and Avraamides, J. (1989) The roasting and leaching of refractory sulphides. Mineralogy-Petrology Symposium Sydney, The AuslMM Sydney Branch, 97-9.Google Scholar
Dutrizac, J.E. and Chen, T.T. (1990) A chemical and mineralogical study of silver, lead and cadmium in Kidd Creek concentrates and roaster products. Proceed. Lead-Zinc ‘90. The Minerals, Metals & Materials Soc. (T. S. Mackey and R. D. Prengaman, Eds.), 161-91.Google Scholar
Elphiek, S.C., Graham, C.M., Walker, F.D.L., and Holmes, M.B. (1991) The application of SIMS ion imaging techniques in the experimental study of fluid-mineral interactions. Mineral. Mag. 55, 347–56.CrossRefGoogle Scholar
Fleischer, M. (1955) Minor elements in some sulfide minerals. Econ. Geol. Fiftieth Annivers. Vol. Part II, 970-1024.Google Scholar
Foord, E.E. and Shawe, D.R. (1989) The Pb-Bi-Ag-Cu-(Hg) chemistry of galena and some associated sulfosalts: a review and some new data from Colorado, California and Pennsylvania. Can. Mineral. 27, 363–82.Google Scholar
Foord, E.E. and Shawe, D.R. and Conklin, N.M. (1988) Coexisting galena, Pbss and sulfosalts: evidence of multiple episodes of mineralization in the Round Mountain and Manhattan gold districts, Nevada. Ibid. 26, 355-76.Google Scholar
Gasparrini, C. (1984) The mineralogy of silver and its significance in metal extraction. Can. Inst. Mining Metall. Bull. 77, 99–110.Google Scholar
Gavelin, S. and Gabrielson, O. (1947) Spectrochemical investigation of sulfide minerals from ores of the Skellefte district. The significance of minor constituents for certain practical and theoretical problems of economic geology. Sver. Geol. Undersökn, Ser. C, no. 491, 3-45.Google Scholar
Genkin, A.D. (1959) Conditions of occurrence and features of the composition of minerals of the platinum group in ores of the Noril'sk deposits. Geol. Rud. Mestoroz. no. 6, 74-84 (in Russian).Google Scholar
Genkin, A.D. (1968) Minerals of the Platinum Metals and theirAssociations in the Copper-Nickel Ores of the Noril'sk Deposits. Nauka, Moscow (in Russian).Google Scholar
Genkin, A.D. (1991) Mode of occurrence of platinum group elements in copper-nickel sulphide ores. Mineral. Soc. Winter Conf. Abstr. 20.Google Scholar
Genkin, A.D. Laputina, I.L., and Muravitskaya, G.N. (1974) Ruthenium- and rhodium-containing pentlandite— an indicator of hydrothermal mobilization of platinum metals. Geol. Rudnkyh. Mestoroz. No. 106.Google Scholar
Griffin, W.L., Ryan, C.G., Cousins, D.R., Sic, S.H., and Suter, G.F. (1990) Application of the proton microprobe to diamond exploration and genesis. Nucl. Instr. Meth. Phys. Res. B49, 318-22.CrossRefGoogle Scholar
Halden, N.M., Hawthorne, F.C., Campbell, J.L.,and Teesdale, W.J. (1991) Chemical characterization of oscillatory zoning and overgrowths in zircon using low-energy ∼t-PIXE. Ann. Mtg. Geol. Assoc. Can. — Mineral. Assoc. Can. with Soc. Econ. Geol., Prog, with Abstracts, 16, A49.Google Scholar
Hall, W.E. and Czamanske, G.K. (1972) Mineralogy and trace element content of the Wood River lead-silver deposits, Blaine county, Idaho. Econ. Geol. 67, 350–61.CrossRefGoogle Scholar
Hallimond, A.F. (1956) Manual of the Polarizing Microscope. Cooke, Troughton, and Simms; York.Google Scholar
Harris, D.C. (1990a) Electron microprobe analysis. In Advanced Microscopic Studies of Ore Minerals (J. L. Jambor and D. J. Vaughan, Eds.), Mineral. Assoc. Can. Short Course, 17, 319-39.Google Scholar
Harris, D.C. (1990b) The mineralogy of gold and its relevance to gold recoveries. Mineral. Deposita 25, 13–17.CrossRefGoogle Scholar
Harris, D.C. and Cabri, L.J. (1991) Nomenclature of platinum- group-element alloys: review and revision. Can. Mineral. 29, 231–7.Google Scholar
Harris, D.C. Cabri, L.J. and Nobiling, R. (1984) Silver-bearing chalcopyritc, a principal source of silver in the Izok Lake massive-sulfide deposit: confirmation of electron- and proton-microprobe analyses. Can. Mineral. 22, 493–98.Google Scholar
Haycock, M.H. (1937) The role of the microscope in the study of gold ores. Can. Inst. Mining Metall. 40, 405–14.Google Scholar
Healy, R.E. and Petruk, W. (1990) Petrology of Au-Ag-Hg alloy and ‘invisible’ gold in the Trout Lake massive sulfide deposit, Flin FIon, Manitoba, Can. Mineral. 28, 189–206.Google Scholar
Hodges, G.J., Roset, G.K., Matousek, J.W., and Marcantonio, P.J. (1991) The Stillwater Mining Company's precious metals smelter: from pilot to production. Preprint SME Ann. Mtg., Denver, 10pp.Google Scholar
Iwasaki, I., Weiblen, P.W., Reid, K.J., Ryan, P.J., Nakazawa, H., and Malicsi, A.S. (1983) Platinum group and arsenide minerals in copper-nickel sulfide bearing Duluth gabbro and their flotation recoveries. Trans. Soc. Mining Eng. AIME, 280, 6.p.Google Scholar
Jackson, S.E. Fryer, B.J., Gosse, W., Healey, D.C., Longerich, H.P., and Strong, D.F. (1990) Determination of precious metals in geological materials by inductively coupled plasma mass spectrometry with nickel sulphide fire-assay collections and tellurium coprecipitation. Chem. Geol. 83, 119–32.CrossRefGoogle Scholar
Jambor, J.L. and Laflamme, J.H.G. (1978) The mineral sources of silver and their distribution in the Caribou massive sulphide deposit, Bathurst area, New Brunswick. CANMET Report 78-14, 26 pp.Google Scholar
Johan, Z. (1988) Indium and germanium in the structure of sphalerite: an example of coupled substitution with copper. Mineral. and Petrol. 39, 211–29.CrossRefGoogle Scholar
Johan, Z. Marcoux, E., and Bonnemaison, M. (1989) Arsénopyrite aurifbre: mode de substitution de Au dans la structure de FeAsS. C.R. Acad. Sci. Paris, 308, sdr. II, 185-91.Google Scholar
Kalogeropoulos, S.I., Kilias, S.P., Bitzios, D.C., Nicolaou, M., and Both, R.A. (1989) Genesis of the Olympias carbonate-hosted Pb-Zn(Au,Ag) sulfide ore deposit, eastern Chalkidiki Peninsula, northern Greece. Econ. Geol. 84, 1210–34.CrossRefGoogle Scholar
Kerr, A.N. and Kipkie, W.B. (1985) Recent process developments at INCO's Copper Cliff milling complex. In Complex Sulfides Processing of Ores, Concentrates and By-Products, Proceed. Metall. Soc. AIME and Can. Inst. Mining Metall. (Zunkel, A. D., Boorman, R. S., Morris, A. E., and Wesely, R. J., Eds.), 525-48.Google Scholar
Kinloch, E.D. (1982) Regional trends in the platinum-group mineralogy of the Critical Zone of the Bush-veld Complex, South Africa. Econ. Geol. 77, 1328-47.CrossRefGoogle Scholar
Kinloch, E.D. and Peyerl, W. (1990) Platinum-group minerals in various rock types of the Merensky reef: genetic implications. Ibid. 85, 537-55.CrossRefGoogle Scholar
Knights, J.G. and Patterson, D.J. (1988) Process mineralogy of silver in lead-zinc-silver ores at Mount Isa, Australia. In Silver-Exploration, Mining and Treatment. Inst. Mining Metall., 101-10.Google Scholar
Kucha, H. (1991) EPMA, microPIXE, synchrotron microprobe and TEM study of visible and invisible accumulations of Au and PGEs in black shale and organic matrix, Kupferschiefer, Poland. Mineral. Soc. Winter Conf. Abstr. 19.Google Scholar
Laflamme, J.H.G. and Cabri, L.J. (1986a) Silver and bismuth contents of galena from the Brunswick No. 12 mine. CANMET MSL Div. Rept. 86-91(IR), 16pp.Google Scholar
Laflamme, J.H.G. and Cabri, L.J. (1986b) Silver and antimony contents of galena from the Brunswick No. 12 mine. Ibid. 86-13g(IR), 16 pp.Google Scholar
Leta, D.P. and Morrison, G.H. (1980) Ion implan-tation for in-situ quantitative ion microprobe analy-sis. Anal. Chem. 52, 277–80.CrossRefGoogle Scholar
Lindsay, N.M. (1988) The Processing and Recovery of the Platinum-Group Elements. Unpub. Ph.D. thesis Univ. Witwatersrand, Fac. Eng., 322pp.Google Scholar
Lindsay, N.M. and Sellschop, J.P.F. (1988) Routine SIMS microanalysis: trace Au and Pt in sulphides. Nucl. Instr. Meth. Phys. Res. B35, 358-63.CrossRefGoogle Scholar
MacLean, W.H., Cabri, L.J., and Gill, J.E. (1972) Exsolution products in heated chalcopyrite. Can. J. Earth Sci. 9, 1305–7.CrossRefGoogle Scholar
Mao, S.H. (1991) Occurrence and distribution of invisible gold in a Carlin-type gold deposit in China. Amer. Mineral. 76, 1964–72.Google Scholar
Marion, P., Holliger, P., Boiron, M.C., Cathelineau, M., and Wagner, F.E. (1991a) New improvements in the characterization of refractory gold in pyrites: an electron microprobe, M6ssbauer spectrometry and ion microprobe study. In Proceed. Brazil Gold ‘91 (E. A. Ladeira, Ed.) Balkema, Rotterdam, 38-95.Google Scholar
Marion, P., Holliger, P., Boiron, M.C., Cathelineau, M., and Wagner, F.E. Monroy, M., Holliger, P., Boiron, M.C., Cathelineau, M., Wagner, F.E., and Friedl, J. (1991b) Gold-bearing pyrites: a combined ion microprobe and M6ssbauer spectrometry approach. In Proceed. Source, Transport and Deposition of Metals (Pagel and Lercy, Eds.) Balkema, Rotterdam, 677-80.Google Scholar
McIntyre, N.S., Cabri, L.J., Chauvin, W.J., and Laflamme, J.H.G. (1984) Secondary ion mass spectrometric study of dissolved silver and indium in sulfide minerals. Scanning Elect. Micros., 1139-46.Google Scholar
Newman, S.C. (1973) Platinum. Trans. Inst. Mining Metall. Sect. A, 82, A54-A68.Google Scholar
Nickel, E.H. and Nichols, M.C. (1991) Mineral Reference Manual. Van Nostrand Reinhold, 250 pp.CrossRefGoogle Scholar
Orberger, B. and Traxel, K. (1991) Proton-microprobe analyses of palladium and selenium in Ni-Cu-sulfides. Nucl. Inst. Meth. Phys. Res. B54, 304-11.CrossRefGoogle Scholar
Paktunc, A.D., Hulbert, L.J., and Harris, D.C. (1990) Partitioning of the platinum-group and other trace elements in sulfides from the Bushveld complex and Canadian occurrences of nickel-copper ores. Can. Mineral. 28, 475–88.Google Scholar
Pearson, M.F., Clark, K.F., and Gonzilez, O. (1988) Ore mineralogy and silver distribution at Real de Angeles, Zacatecas, Mexico. In Silver-Exploration, Mining and Treatment. Inst. Mining Metall., 73-99.Google Scholar
Peyerl, W. (1983) The metallurgical implications of the mode of occurrence of platinum-group metals in the Merensky reef and UG-2 chromitite of the Bushveld complex. Spec. Publ. GeoL Soc. S. Afr. 7, 295–300.Google Scholar
Picot, P. and Marcoux, E. (1987) Nouvelles données sur la métallogénie de l'or. C. R. Acad. Sci. Paris, 304, s6r. II, 221-6.Google Scholar
Prendergast, M.D. (1990) Platinum-group minerals and hydrosilicate ‘alteration’ in Wedza-Mimosa platinum deposit, Great Dyke, Zimbabwe—genetic and metallurgical implications. Trans. Inst. Mining Metall. 99, B91-B105.Google Scholar
Przybylowicz, W., Kucha, H., Piestrzynski, A., Traxel, K., and Bajt, S. (1990) Micro-PIXE analyses of trace elements in black shales from the lower Zechstein copper deposits, Poland. Nucl. Instr. Methods Phys. Res. BS0, 231-7.CrossRefGoogle Scholar
Remond, G., Cesbron, F., Traxel, K., Campbell, J.L., and Cabri, L.J. (1987) Electron microprobe analysis and proton induced X-ray spectrometry applied to trace element analysis in sulfides: problems and prospects. Scanning Microsc. 1, 1017–37.Google Scholar
Rucklidge, J. and Gasparrini, E.L. (1969) Electron microprobe analytical data reduction. EMPADR VII. Univ. Toronto, Toronto.Google Scholar
Ryan, C.G., Cousens, D.R., Sie, S.H., Griffin, W.L. and Suter, G.F. (1990) Quantitative PIXE micro-analysis of geological material using the CSIRO proton microprobe. Nucl. Instr. Methods Phys. Res. B47, 55-71.CrossRefGoogle Scholar
Sharp, T.G. and Buseck, P.R. (1989) Distribution of silver in galena: a high spatial resolution study. Geol. Soc. Amer. Abstr. with Programs, 21-6, A248.Google Scholar
Sharp, T.G. and Buseck, P.R. (1992) The distribution of Ag and Sb in galena: inclusions versus solid solution. Amer. Mineral. 77 (in press).Google Scholar
Sharp, T.G. and Buseck, P.R. Zheng, N.J., Tsong, I.S.T. and Museck, P.R. (1990) Scanning tunnelling microscopy of defects in Ag- and Sb-bearing galena. Ibid. 75, 1438-42.Google Scholar
Sie, S.H., Ryan, C.G., Cousens, D.R., and Griffin, W.L. (1989) Application of the proton microprobe in mineral exploration and processing. Nucl. Instr. Methods Phys. Res. B41, 690-7.CrossRefGoogle Scholar
Sie, S.H., Ryan, C.G., Cousens, D.R., and Griffin, W.L. (1990) IBA in minerals research: progress and prospects. Ibid. B45, 6049.CrossRefGoogle Scholar
Swash, P.M. (1988) A mineralogical investigation of refractory gold ores and their beneficiation, with special reference to arsenical ores. J. S. Afr. Inst. Mining Metall. 88, 173–80.Google Scholar
Swash, P.M. and Ellis, P. (1986) The roasting of arsenical gold ores: a mineralogical perspective. In Gold 100. Proceed. Internat. Conf. on Gold: Extractive Metallurgy of Gold, S. Afr. Inst. Mining Metall. 2, 235-57.Google Scholar
Temple, D.A. (1985) Zinc—from mine to market: some views on the industry. Proceed. Zinc ‘85, (K. Tozawa, Ed.) Mining Metall. Inst. Japan, 3—18.Google Scholar
Thorpe, R.I., Pringle, G.J., and Plant, A.G. (1976) Occurrence of selenide and sulphide minerals in bornite ore of the Kidd Creek massive sulphide deposit, Timmins, Ontario. Geol. Surv. Can. Paper, 76-1A, 311-7.Google Scholar
Todd, S.G., Keith, D.W., Le Roy, L. W., Schissel, D.J., Mann, E.L. and Irvine, T.N. (1982) The J-M platinum-palladium reef of the Still water Complex, Montana: I. Stratigraphy and petrology. Econ. Geol. 77, 1454–80.CrossRefGoogle Scholar
Wagner, F.E., Marion, P. and Regnard, J.-R. (1986) Mrssbauer study of the chemical state of gold in gold ores. In Gold 100. Proceed. Internat. Conf. on Gold: Extractive Metallurgy of Gold, S. Afr. Inst. Mining Metall. 2, 435-43.Google Scholar
Wagner, F.E., Marion, P. and Regnard, J.-R. (1988) 197Au Mrssbauer study of gold ores, mattes, roaster products, and gold minerals. Hyperfine Interactions, 41, 851–4.CrossRefGoogle Scholar
Wilson, G.C., Rucklidge, J.C. and Kilius, L. (1990) Sulfide gold content of skarn mineralization at Rossland, British Columbia. Econ. Geol. 85, 1252–9.CrossRefGoogle Scholar
Wright, T.L. and Fleischer, M. (1965) Geochemistry of the Platinum Metals. U.S. Geol. Surv. Bull. 1214-A.Google Scholar
Wu, X. and Delbove, F. (1989) Hydrothermal synthesis of gold-bearing arsenopyrite. Econ. Geol. 84, 2029–32.CrossRefGoogle Scholar