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IV.—A Defence of Turner's method of Detecting Boracic Acid

Published online by Cambridge University Press:  14 March 2018

Extract

A defence of Turner’s method seems at first sight to be quite unnecessary, for his test has been used over and over again, for upwards of fifty years, and, as far as I am aware, its usefulness has never been questioned till quite lately. Great was my surprise a few days ago to read a paragraph “On the uselessness of Turner’s flux as applied to the detection of boracic acid.” Professor Chapman speaking of Turner’s method, says:— “This test is much quoted in blowpipe books, and works on chemical analysis generally; but it is altogether superfluous. With borate of soda it fails entirely, or yields very unsatisfactory results ; and although it answers for most other borates, and for borosilicates, it is uselessly applied to them, because these bodies colour the flame equally well per se.” He quotes from Buzengeiger (Annales des Mines, 1829, tome v.p. 36), in support of these statements.

Type
Research Article
Copyright
Copyright © The Mineralogical Society of Great Britain and Ireland 1877

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References

page 77 note * It consists in heating on Pt. wire before the blowpipe the powdered mineral mixed with a flux made of 4 1/2 parts of bisulphate of potash, and 1 part of finely powdered fluor spar. If boric acid is present the flame is colored green.

page 77 note † On some blowpipe-reactions, by Prof. E. J. Chapmam. Canadian Journal, October, 1876.

page 79 note * Plattner's Probirkunst-mit dem Löthrohre, 4re Auflage 1865, p. 466.

page 80 note * Translated from Berzelius' Anwendung des Löhrohrs Nürnberg 1821, p. 79.