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 This work was supported in part by US DOE Grant No. DE-FG02-03ER46057. This research is also part of the Chemical Imaging & Signature Discovery Initiatives conducted under the LDRD Program at Pacific Northwest National Laboratory (PNNL) and used EMSL, a national scientific user facility sponsored by the DOE Office of Bio & Env. Research at PNNL. PNNL is a multi-program national lab operated by Battelle Memorial Institute under Contract DE-AC05-76RL01830 for the US DOE.